Unifying methods for optimal control in non-Markovian quantum systems via process tensors.

IF 3.1 2区 化学 Q3 CHEMISTRY, PHYSICAL Journal of Chemical Physics Pub Date : 2024-09-28 DOI:10.1063/5.0226031
Carlos Ortega-Taberner, Eoin O'Neill, Eoin Butler, Gerald E Fux, P R Eastham
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Abstract

The large dimensionality of environments is the limiting factor in applying optimal control to open quantum systems beyond the Markovian approximation. Various methods exist to simulate non-Markovian systems, which effectively reduce the environment to a number of active degrees of freedom. Here, we show that several of these methods can be expressed in terms of a process tensor in the form of a matrix-product-operator, which serves as a unifying framework to show how they can be used in optimal control and to compare their performance. The matrix-product-operator form provides a general scheme for computing gradients using back propagation and allows the efficiency of the different methods to be compared via the bond dimensions of their respective process tensors.

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通过过程张量实现非马尔可夫量子系统最优控制的统一方法。
在马尔可夫近似之外的开放量子系统中应用最优控制时,环境的大维度是限制因素。目前有多种模拟非马尔可夫系统的方法,它们能有效地将环境缩小为若干个活动自由度。在这里,我们展示了其中几种方法可以用矩阵-乘积-算子形式的过程张量来表示,这可以作为一个统一的框架,展示如何将它们用于优化控制,并比较它们的性能。矩阵-乘积-算子形式为使用反向传播计算梯度提供了一个通用方案,并允许通过各自过程张量的结合维度来比较不同方法的效率。
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来源期刊
Journal of Chemical Physics
Journal of Chemical Physics 物理-物理:原子、分子和化学物理
CiteScore
7.40
自引率
15.90%
发文量
1615
审稿时长
2 months
期刊介绍: The Journal of Chemical Physics publishes quantitative and rigorous science of long-lasting value in methods and applications of chemical physics. The Journal also publishes brief Communications of significant new findings, Perspectives on the latest advances in the field, and Special Topic issues. The Journal focuses on innovative research in experimental and theoretical areas of chemical physics, including spectroscopy, dynamics, kinetics, statistical mechanics, and quantum mechanics. In addition, topical areas such as polymers, soft matter, materials, surfaces/interfaces, and systems of biological relevance are of increasing importance. Topical coverage includes: Theoretical Methods and Algorithms Advanced Experimental Techniques Atoms, Molecules, and Clusters Liquids, Glasses, and Crystals Surfaces, Interfaces, and Materials Polymers and Soft Matter Biological Molecules and Networks.
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