Microstructural characterization of InP films on SOI (001) substrates grown by selective lateral metal-Organic vapor-Phase epitaxy

IF 1.7 4区 材料科学 Q3 CRYSTALLOGRAPHY Journal of Crystal Growth Pub Date : 2024-09-24 DOI:10.1016/j.jcrysgro.2024.127903
Hiroya Homma, Hiroki Sugiyama, Tatsurou Hiraki, Tomonari Sato, Shinji Matsuo
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Abstract

To achieve monolithic integration of Si-waveguide-coupled III-V laser diodes, it is important to establish a method of growing high-quality III-V materials on large Si wafers without a thick buffer layer. Here, the lateral aspect ratio trapping (LART) method has recently been attracting attention because of its potential for integrating large-area and high-quality III-V films on (001)-oriented silicon-on-insulator (SOI) substrates. In this paper, we report a detailed microstructural analysis of InP films that were fabricated on (001) SOI substrates by using metal–organic vapor-phase epitaxy and the LART method. The obtained films had an area of around 50 x 4 μm2, which is large enough for them to be used as templates in photonics device fabrication. Transmission electron microscopy revealed that propagation of threading dislocations in the Si/InP interface region was suppressed. However, the films tended to contain other planar defects, such as stacking faults, rotational twin boundaries, and anti- phase boundaries. We discuss the mechanisms underlying the generation of these defects and approaches to suppressing their formation.
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通过选择性横向金属有机气相外延技术在 SOI (001) 衬底上生长的 InP 薄膜的微观结构特征
要实现 Si- 波导耦合 III-V 激光二极管的单片集成,必须建立一种无需厚缓冲层即可在大型硅晶片上生长高质量 III-V 材料的方法。最近,横向纵横比捕获(LART)方法因其在面向(001)绝缘体上硅(SOI)衬底上集成大面积和高质量 III-V 薄膜的潜力而备受关注。本文报告了利用金属有机物气相外延和 LART 方法在 (001) SOI 基底上制备 InP 薄膜的详细微观结构分析。获得的薄膜面积约为 50 x 4 μm2,足够大,可用作光子器件制造的模板。透射电子显微镜显示,Si/InP 界面区域的穿线位错传播受到抑制。然而,薄膜往往含有其他平面缺陷,如堆叠断层、旋转孪晶边界和反相边界。我们讨论了这些缺陷的产生机制以及抑制其形成的方法。
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来源期刊
Journal of Crystal Growth
Journal of Crystal Growth 化学-晶体学
CiteScore
3.60
自引率
11.10%
发文量
373
审稿时长
65 days
期刊介绍: The journal offers a common reference and publication source for workers engaged in research on the experimental and theoretical aspects of crystal growth and its applications, e.g. in devices. Experimental and theoretical contributions are published in the following fields: theory of nucleation and growth, molecular kinetics and transport phenomena, crystallization in viscous media such as polymers and glasses; crystal growth of metals, minerals, semiconductors, superconductors, magnetics, inorganic, organic and biological substances in bulk or as thin films; molecular beam epitaxy, chemical vapor deposition, growth of III-V and II-VI and other semiconductors; characterization of single crystals by physical and chemical methods; apparatus, instrumentation and techniques for crystal growth, and purification methods; multilayer heterostructures and their characterisation with an emphasis on crystal growth and epitaxial aspects of electronic materials. A special feature of the journal is the periodic inclusion of proceedings of symposia and conferences on relevant aspects of crystal growth.
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