A novel low shrinkage dimethacrylate monomer as an alternative to BisGMA for adhesive and resin-based composite applications.

IF 1.5 4区 医学 Q3 DENTISTRY, ORAL SURGERY & MEDICINE Brazilian oral research Pub Date : 2024-09-30 eCollection Date: 2024-01-01 DOI:10.1590/1807-3107bor-2024.vol38.0097
Fernanda Sandes de Lucena, Matthew Logan, Steven Lewis, Neil Deatherage, Adilson Yoshio Furuse, Carmem Silvia Pfeifer
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Abstract

The aim of this study was to develop a mixture of dimethacrylate isomers (PG6EMA) as a potential monomer for dental adhesives and composites. PG6EMA was synthesized de novo and characterized in the presence of ethanol (3%, 6% or 9%). BisGMA/TEGDMA (BTEG, 50/50 wt.%) was used as the resin control. Composites were formulated with 60 wt.% of either PG6EMA or BisGMA (40 wt.% TEGDMA and 70 wt.% filler). DMPA (0.2 wt.%) and DPI-PF6 (0.4 wt.%) were added as photoinitiators, irradiated with a mercury arc lamp (320-500 nm, 500 mW/cm2; Acticure). All materials were tested for polymerization kinetics (near-infrared), viscosity (η) and storage modulus (G', oscillatory rheometry). The composites were further characterized for water sorption/solubility, wet/dry flexural strength/modulus and polymerization stress. Data were analyzed with one-way ANOVA/Tukey's test (α = 0.05). The PG6EMA resins showed lower rates of polymerization compared with BTEG (p = 0.001) but high degrees of conversion (p = 0.002). Solvent concentration did not affect RPMAX but the 6% and 9% mixtures showed higher final DC, likely due to reduced viscosity. PG6EMA had much higher viscosity than BTEG (p <0.001) and lower G' (p = 0.003). Composites modified with PG6EMA have slower polymerization rates (p = 0.001) but higher final DC (p = 0.04) than the control. PG6EMA/TEGDMA showed lower dry/wet flexural strength and comparable dry modulus. The PG6EMA/TEGDMA composite showed a 18.4% polymerization stress reduction compared to the BTEG composite. Both base monomers had similar WS/SL and G'. Within its limitations, this study demonstrated that the newly synthesized PG6EMA was a viable alternative to BisGMA in dental composites.

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一种新型低收缩二甲基丙烯酸酯单体,可替代 BisGMA 用于粘合剂和树脂基复合材料应用。
本研究旨在开发一种二甲基丙烯酸酯异构体混合物(PG6EMA),作为牙科粘合剂和复合材料的潜在单体。PG6EMA 是在乙醇(3%、6% 或 9%)存在下从头合成的,并对其进行了表征。双GMA/TEGDMA(BTEG,50/50 wt.%)用作树脂对照。复合材料由 60 wt.% 的 PG6EMA 或 BisGMA(40 wt.% 的 TEGDMA 和 70 wt.% 的填料)配制而成。添加 DMPA(0.2 wt.%)和 DPI-PF6(0.4 wt.%)作为光引发剂,用汞弧灯(320-500 纳米,500 mW/cm2;Acticure)照射。对所有材料进行了聚合动力学(近红外)、粘度(η)和储存模量(G',振荡流变仪)测试。对复合材料的吸水性/溶解性、干/湿挠曲强度/模量和聚合应力进行了进一步表征。数据采用单因素方差分析/Tukey 检验(α = 0.05)进行分析。与 BTEG 相比,PG6EMA 树脂的聚合速率较低(p = 0.001),但转化率较高(p = 0.002)。溶剂浓度对 RPMAX 没有影响,但 6% 和 9% 的混合物显示出更高的最终 DC,这可能是由于粘度降低所致。PG6EMA 的粘度比 BTEG 高得多(p = 0.002)。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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来源期刊
CiteScore
3.70
自引率
4.00%
发文量
107
审稿时长
12 weeks
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