Interface and Defect Engineering in 3D Co3O4-Ov/TiO2 to Boost Simultaneous Removal of BPA and Cr(VI) upon Photoelectrocatalytic/Peroxymonosulfate (PEC/PMS) System
{"title":"Interface and Defect Engineering in 3D Co3O4-Ov/TiO2 to Boost Simultaneous Removal of BPA and Cr(VI) upon Photoelectrocatalytic/Peroxymonosulfate (PEC/PMS) System","authors":"Yu Hu, Yuzhou Jin, Yuqing Gao, Mingfang Li, Xuejiang Wang, Haiying Ma, Ya-nan Zhang","doi":"10.1002/adfm.202414350","DOIUrl":null,"url":null,"abstract":"The combination of photoelectrocatalytic (PEC) and peroxymonosulfate (PMS) is an innovative strategy for environmental treatment. And fabricating a highly efficient photoelectrode is the most pivotal factor in PEC reactions. This study designs an advanced Co<sub>3</sub>O<sub>4-Ov</sub>/TiO<sub>2</sub> photoelectrode by a dual-modification strategy encompassing interface engineering and defect engineering. The photoelectric characterization validates the synergy of oxygen vacancies and dual heterojunctions. Simulated electron density distribution and Kelvin probe force microscopy (KPFM) elucidate the charge transfer pathway between Co<sub>3</sub>O<sub>4-Ov</sub> and TiO<sub>2</sub>. <sup>1</sup>O<sub>2</sub> and SO<sub>4</sub> <sup>.−</sup> are confirmed to be primarily responsible for the BPA oxidation in PEC/PMS system by radical scavenger experiments and the EPR technique. And the attack sites of BPA are precisely identified based on the Fukui index. Furthermore, density functional theory (DFT) calculations testify that Co<sub>3</sub>O<sub>4-Ov</sub> can improve the adsorption capacity of PMS and reduce the energy barrier of the reaction process, while XPS analysis showed Co<sup>3+</sup>/Co<sup>2+</sup> redox couple can accelerate PMS activation. Enhanced anode oxidation can effectively promote cathode reduction and consequently Co<sub>3</sub>O<sub>4-Ov</sub>/TiO<sub>2</sub>-PMS/PEC system presents a superior removal of both pollutants within only 15 min with fast kinetics (0.15 min<sup>−1</sup> for BPA, 0.29 min<sup>−1</sup> for Cr(VI)). This work provides unique insight into designing a highly efficient PMS/PEC system for simultaneous pollutant treatment.","PeriodicalId":112,"journal":{"name":"Advanced Functional Materials","volume":null,"pages":null},"PeriodicalIF":18.5000,"publicationDate":"2024-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Functional Materials","FirstCategoryId":"88","ListUrlMain":"https://doi.org/10.1002/adfm.202414350","RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
The combination of photoelectrocatalytic (PEC) and peroxymonosulfate (PMS) is an innovative strategy for environmental treatment. And fabricating a highly efficient photoelectrode is the most pivotal factor in PEC reactions. This study designs an advanced Co3O4-Ov/TiO2 photoelectrode by a dual-modification strategy encompassing interface engineering and defect engineering. The photoelectric characterization validates the synergy of oxygen vacancies and dual heterojunctions. Simulated electron density distribution and Kelvin probe force microscopy (KPFM) elucidate the charge transfer pathway between Co3O4-Ov and TiO2. 1O2 and SO4.− are confirmed to be primarily responsible for the BPA oxidation in PEC/PMS system by radical scavenger experiments and the EPR technique. And the attack sites of BPA are precisely identified based on the Fukui index. Furthermore, density functional theory (DFT) calculations testify that Co3O4-Ov can improve the adsorption capacity of PMS and reduce the energy barrier of the reaction process, while XPS analysis showed Co3+/Co2+ redox couple can accelerate PMS activation. Enhanced anode oxidation can effectively promote cathode reduction and consequently Co3O4-Ov/TiO2-PMS/PEC system presents a superior removal of both pollutants within only 15 min with fast kinetics (0.15 min−1 for BPA, 0.29 min−1 for Cr(VI)). This work provides unique insight into designing a highly efficient PMS/PEC system for simultaneous pollutant treatment.
期刊介绍:
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