Light δD apatites reveal deep origin water in North China Craton intracontinental granites and basalts

IF 14.7 1区 综合性期刊 Q1 MULTIDISCIPLINARY SCIENCES Nature Communications Pub Date : 2024-10-09 DOI:10.1038/s41467-024-53133-4
Chuan-Mao Yang, Yi-Gang Xu, Xiao-Ping Xia, Jin-Hui Yang, Xiao-Long Huang, Christopher J. Spencer, Jin-Feng Sun, Qing Yang
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Abstract

Water is essential to the formation of intracontinental granites, but its origin remains elusive. Here we address this scientific problem by analyzing D/H isotopes of apatites, hydrous minerals in Jurassic and Early Cretaceous granites and basalts from eastern North China Craton, where water was previously interpreted as derived from subducting slab. Results reveal extremely low δD values in pristine Early Cretaceous granitic (−203‰ to −127‰) and basaltic (−197‰ to −107‰) apatites, contrasting with relatively high δD values (−137‰ to −47‰) in Jurassic granites. Given the depth-dependent D/H isotopic fractionation during slab dehydration and high-water contents in coeval primitive mafic magmas, the Early Cretaceous magma water is attributed to the stagnant slab within the mantle transition zone. Secular change in the depth of water aligns with steepening of subducting Paleo-Pacific plate from Jurassic to Early Cretaceous, demonstrating the potential of apatite H isotopes in tracing water origin in granites and basalts.

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轻δD磷灰石揭示华北克拉通大陆内花岗岩和玄武岩中的深源水
水对大陆内部花岗岩的形成至关重要,但水的来源仍然难以捉摸。在这里,我们通过分析华北克拉通东部侏罗纪和早白垩世花岗岩和玄武岩中的磷灰石、含水矿物的 D/H 同位素来解决这一科学问题。结果显示,原始早白垩世花岗岩(-203‰至-127‰)和玄武岩(-197‰至-107‰)磷灰石中的δD值极低,而侏罗纪花岗岩中的δD值相对较高(-137‰至-47‰)。鉴于板块脱水过程中与深度相关的 D/H 同位素分馏以及共生原始岩浆中的高含水量,早白垩世岩浆水被归因于地幔过渡带内的停滞板块。从侏罗纪到早白垩世,水深的周期性变化与俯冲的古太平洋板块的陡峭化一致,证明了磷灰石H同位素在追踪花岗岩和玄武岩中水的来源方面的潜力。
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来源期刊
Nature Communications
Nature Communications Biological Science Disciplines-
CiteScore
24.90
自引率
2.40%
发文量
6928
审稿时长
3.7 months
期刊介绍: Nature Communications, an open-access journal, publishes high-quality research spanning all areas of the natural sciences. Papers featured in the journal showcase significant advances relevant to specialists in each respective field. With a 2-year impact factor of 16.6 (2022) and a median time of 8 days from submission to the first editorial decision, Nature Communications is committed to rapid dissemination of research findings. As a multidisciplinary journal, it welcomes contributions from biological, health, physical, chemical, Earth, social, mathematical, applied, and engineering sciences, aiming to highlight important breakthroughs within each domain.
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