In-situ activation of persulfate by emplaced magnetite nanoparticles for degradation of 1,2-dichloroethane in porous media

Abstract

In this study, column experiments were conducted to explore on the method of emplacement of magnetite nanoparticles (MNPs) for in situ activation of persulfate (PS) in sand porous media to degrade 1,2-dichloroethane (DCA), a typical recalcitrant chlorinated compound. Different molar ratios between PS and DCA (0:1, 2:1, 5:1 and 20:1) and mass contents of MNPs in the sand (0%, 1.9% and 5.4%) were tested. In the absence of MNPs, degradation of DCA was negligible for a hydraulic retention time of 7 h. Presence of MNPs at the content of 1.9% enhanced degradation of DCA and the highest removal efficiency (34.2%) was observed at the PS-to-DCA molar ratio of 5:1. At the MNPs content of 5.4%, increase of the PS-to-DCA molar ratio from 2:1 to 20:1 lead to not only increase in DCA removal efficiency but also substantial enhancement in chloride production, indicating that high PS concentration could cause significant degradation of the Cl-containing intermediates. In contrast to MNPs, Fe₃O₄ solids with much larger size (∼1 μm) were much less effective in activating PS for DCA removal even at a significantly higher content in the medium. The transport data could be well fitted by the one-site chemical nonequilibrium model, which showed kinetic DCA sorption to the MNPs as a key process for the transport. In the long-term injection experiment, a stable and significant removal of DCA (∼50%) was observed for 254 days at the MNP content of 1.9 %. The results of this study show the potential of MNPs as a sustainable PS activator in injection-based in situ chemical oxidation for groundwater remediation.