Arylative difunctionalization of olefins using easily accessed organobismuth (V) reagents

IF 19.1 1区 化学 Q1 CHEMISTRY, MULTIDISCIPLINARY Chem Pub Date : 2024-10-10 DOI:10.1016/j.chempr.2024.09.014
Nicholas D. Chiappini
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引用次数: 0

Abstract

In this issue of Chem, Li and Rawal present an exciting new application of Ar3BiCl2 as convenient reagents for arylative difunctionalization of alkenes using visible or near-visible light. Unburdened by air and moisture sensitivity, the method affords rapid and facile azido-, cyano-, and chloro-arylation of a bevy of functionalized alkenes.
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使用易于获取的有机铋 (V) 试剂对烯烃进行芳基化反官能度处理
在本期《化学》杂志上,Li 和 Rawal 介绍了 Ar3BiCl2 作为方便的试剂在利用可见光或近视光对烯烃进行芳基二官能化时的一种令人兴奋的新应用。该方法不受空气和湿度的影响,能快速、简便地对多种官能化烯进行叠氮、氰和氯芳基化反应。
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来源期刊
Chem
Chem Environmental Science-Environmental Chemistry
CiteScore
32.40
自引率
1.30%
发文量
281
期刊介绍: Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.
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