Rhitwika Chowdhury, Irshad Ahmad Bhat, Sharad Kumar Sachan and Ganapathi Anantharaman
{"title":"Not so inert mer-tris-chelate cobalt(iii) complex of a hydroxy-pyridine functionalized NHC ligand for cyclic carbonate synthesis†‡","authors":"Rhitwika Chowdhury, Irshad Ahmad Bhat, Sharad Kumar Sachan and Ganapathi Anantharaman","doi":"10.1039/D4DT02767A","DOIUrl":null,"url":null,"abstract":"<p >The homoleptic hydroxy-pyridine functionalized Co(<small>III</small>)–NHC complex (<strong>2</strong>) demonstrates extraordinary catalytic activity towards the CO<small><sub>2</sub></small> cycloaddition under mild conditions. Using this catalyst and TBAB, the highest TON (666 667) and TOF (52 713 h<small><sup>−1</sup></small>) were achieved compared to previously reported cobalt catalysts.</p>","PeriodicalId":71,"journal":{"name":"Dalton Transactions","volume":" 42","pages":" 17157-17161"},"PeriodicalIF":3.5000,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dalton Transactions","FirstCategoryId":"92","ListUrlMain":"https://pubs.rsc.org/en/content/articlelanding/2024/dt/d4dt02767a","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The homoleptic hydroxy-pyridine functionalized Co(III)–NHC complex (2) demonstrates extraordinary catalytic activity towards the CO2 cycloaddition under mild conditions. Using this catalyst and TBAB, the highest TON (666 667) and TOF (52 713 h−1) were achieved compared to previously reported cobalt catalysts.
期刊介绍：
Dalton Transactions is a journal for all areas of inorganic chemistry, which encompasses the organometallic, bioinorganic and materials chemistry of the elements, with applications including synthesis, catalysis, energy conversion/storage, electrical devices and medicine. Dalton Transactions welcomes high-quality, original submissions in all of these areas and more, where the advancement of knowledge in inorganic chemistry is significant.
京公网安备 11010802042870号
京ICP备2023020795号-1
分享
求助内容：
应助结果提醒方式：
扫码关注我们
