RenXi Ye, Teles C. Furlani, Andrew P. Folkerson, Scott A. Mabury, Trevor C. VandenBoer and Cora J. Young*,
{"title":"A Method to Measure Total Gaseous Fluorine","authors":"RenXi Ye, Teles C. Furlani, Andrew P. Folkerson, Scott A. Mabury, Trevor C. VandenBoer and Cora J. Young*, ","doi":"10.1021/acs.estlett.4c0055310.1021/acs.estlett.4c00553","DOIUrl":null,"url":null,"abstract":"<p >Total fluorine (TF) analysis is a powerful tool for the characterization of organofluorine contaminants in the environment. Organofluorine compounds are known primarily with respect to the notorious poly- and perfluoroalkyl substances (PFAS) and as potent greenhouse gases that can impact the climate. The use of targeted methods for every organofluorine compound in the environment is not feasible. While methods are available for TF analysis of condensed phase samples, no technique exists for gas phase TF measurements (TF<sub>g</sub>). Herein we demonstrate an in situ instrumental method for TF<sub>g</sub> via platinum catalyzed thermolysis at 1000 °C in the presence of propane. TF<sub>g</sub> is fully converted into HF and subsequently quantified by an ion selective electrode or ion chromatography for F<sup>–</sup>. The method was validated using nine organofluorine compounds with differing functional groups. We characterized TF<sub>g</sub> and compared it to common speciated measurements in the headspace of four commercial fluorosurfactants and outdoor air. Most TF<sub>g</sub> (65.0–99.8% or 1.5–10.2 ppmv F) in the fluorosurfactant headspace was unknown. In outdoor air, >50% of TF<sub>g</sub> (7.2–24.2 ppmv F) was unknown. These high quantities of unknown organofluorine indicate a measurement gap in the gas phase, which could have important implications for atmospheric sources and the burdens of PFAS and fluorinated greenhouse gases.</p>","PeriodicalId":37,"journal":{"name":"Environmental Science & Technology Letters Environ.","volume":null,"pages":null},"PeriodicalIF":8.9000,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Environmental Science & Technology Letters Environ.","FirstCategoryId":"1","ListUrlMain":"https://pubs.acs.org/doi/10.1021/acs.estlett.4c00553","RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, ENVIRONMENTAL","Score":null,"Total":0}
引用次数: 0
Abstract
Total fluorine (TF) analysis is a powerful tool for the characterization of organofluorine contaminants in the environment. Organofluorine compounds are known primarily with respect to the notorious poly- and perfluoroalkyl substances (PFAS) and as potent greenhouse gases that can impact the climate. The use of targeted methods for every organofluorine compound in the environment is not feasible. While methods are available for TF analysis of condensed phase samples, no technique exists for gas phase TF measurements (TFg). Herein we demonstrate an in situ instrumental method for TFg via platinum catalyzed thermolysis at 1000 °C in the presence of propane. TFg is fully converted into HF and subsequently quantified by an ion selective electrode or ion chromatography for F–. The method was validated using nine organofluorine compounds with differing functional groups. We characterized TFg and compared it to common speciated measurements in the headspace of four commercial fluorosurfactants and outdoor air. Most TFg (65.0–99.8% or 1.5–10.2 ppmv F) in the fluorosurfactant headspace was unknown. In outdoor air, >50% of TFg (7.2–24.2 ppmv F) was unknown. These high quantities of unknown organofluorine indicate a measurement gap in the gas phase, which could have important implications for atmospheric sources and the burdens of PFAS and fluorinated greenhouse gases.
期刊介绍:
Environmental Science & Technology Letters serves as an international forum for brief communications on experimental or theoretical results of exceptional timeliness in all aspects of environmental science, both pure and applied. Published as soon as accepted, these communications are summarized in monthly issues. Additionally, the journal features short reviews on emerging topics in environmental science and technology.