1,4-cineole: a bio-derived solvent for highly stable graphene nanoplatelet suspensions and well-dispersed UHMWPE nanocomposite fibers

IF 23.2 2区 材料科学 Q1 MATERIALS SCIENCE, COMPOSITES Advanced Composites and Hybrid Materials Pub Date : 2024-10-01 DOI:10.1007/s42114-024-00977-5
Kenneth R. Brown, ZhiJing Xue, Ryan Cordier, Cole Love-Baker, Erin R. Crater, Andriy Sushchenko, Eli Knight, Alexander Scherschel, Morgan Price, Robert B. Moore, Xiaodong Li
{"title":"1,4-cineole: a bio-derived solvent for highly stable graphene nanoplatelet suspensions and well-dispersed UHMWPE nanocomposite fibers","authors":"Kenneth R. Brown,&nbsp;ZhiJing Xue,&nbsp;Ryan Cordier,&nbsp;Cole Love-Baker,&nbsp;Erin R. Crater,&nbsp;Andriy Sushchenko,&nbsp;Eli Knight,&nbsp;Alexander Scherschel,&nbsp;Morgan Price,&nbsp;Robert B. Moore,&nbsp;Xiaodong Li","doi":"10.1007/s42114-024-00977-5","DOIUrl":null,"url":null,"abstract":"<div><p>The exceptional properties of carbon nanoparticles, such as graphene, promise to expand the performance and functionality of many materials. The reinforcement of polymers is of keen interest due to their low density and flexible manufacturing methods. However, dispersing graphene in them has proven to be an enduring challenge due to the particles’ propensity to form performance-degrading agglomerations. Furthermore, effective solvents for nanoparticle dispersion are commonly harmful, non-renewable, petrochemicals. In this work, a bio-derived solvent, 1,4-cineole, is demonstrated as a renewable alternative to these solvents that can be used to form highly stable graphene nanoplatelet (GnP) suspensions and used to gel spin well-dispersed UHMWPE/GnP nanocomposite fibers. The GnP concentration in the fibers was varied across three orders of magnitude, 0.01 to 1 wt%, to examine its effect on fiber microstructure and properties. At low concentrations, the particles act as point defects without affecting the fiber microstructure, and poor particle/matrix interfacial adhesion results in significantly reduced mechanical properties. At 1 wt% GnPs, a network effect takes hold thereby reinforcing the fibers, but the particles also impede the growth and orientation of crucial load-carrying crystalline structures in the fiber. Unveiling the microstructural effects of GnPs on highly oriented and crystalline polymers in this study provides crucial insights for future work developing high-performance polymer nanocomposite fibers.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"7 5","pages":""},"PeriodicalIF":23.2000,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advanced Composites and Hybrid Materials","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s42114-024-00977-5","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"MATERIALS SCIENCE, COMPOSITES","Score":null,"Total":0}
引用次数: 0

Abstract

The exceptional properties of carbon nanoparticles, such as graphene, promise to expand the performance and functionality of many materials. The reinforcement of polymers is of keen interest due to their low density and flexible manufacturing methods. However, dispersing graphene in them has proven to be an enduring challenge due to the particles’ propensity to form performance-degrading agglomerations. Furthermore, effective solvents for nanoparticle dispersion are commonly harmful, non-renewable, petrochemicals. In this work, a bio-derived solvent, 1,4-cineole, is demonstrated as a renewable alternative to these solvents that can be used to form highly stable graphene nanoplatelet (GnP) suspensions and used to gel spin well-dispersed UHMWPE/GnP nanocomposite fibers. The GnP concentration in the fibers was varied across three orders of magnitude, 0.01 to 1 wt%, to examine its effect on fiber microstructure and properties. At low concentrations, the particles act as point defects without affecting the fiber microstructure, and poor particle/matrix interfacial adhesion results in significantly reduced mechanical properties. At 1 wt% GnPs, a network effect takes hold thereby reinforcing the fibers, but the particles also impede the growth and orientation of crucial load-carrying crystalline structures in the fiber. Unveiling the microstructural effects of GnPs on highly oriented and crystalline polymers in this study provides crucial insights for future work developing high-performance polymer nanocomposite fibers.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
1,4-松油:一种生物衍生溶剂,可用于制造高度稳定的石墨烯纳米板悬浮液和分散良好的超高分子量聚乙烯纳米复合纤维
石墨烯等碳纳米粒子的优异特性有望提高许多材料的性能和功能。由于聚合物密度低、制造方法灵活,因此聚合物的增强技术备受关注。然而,由于石墨烯颗粒容易形成降低性能的团聚体,在聚合物中分散石墨烯已被证明是一项持久的挑战。此外,用于纳米粒子分散的有效溶剂通常是有害的、不可再生的石化产品。在这项工作中,一种生物衍生溶剂 1,4-蒎烯被证明是这些溶剂的可再生替代品,可用于形成高度稳定的石墨烯纳米板(GnP)悬浮液,并用于凝胶纺丝分散良好的超高分子量聚乙烯/GnP 纳米复合纤维。纤维中的 GnP 浓度在 0.01 至 1 wt% 三个数量级之间变化,以考察其对纤维微观结构和性能的影响。在低浓度下,颗粒作为点缺陷不会影响纤维的微观结构,而颗粒/基质界面粘附性差会导致机械性能显著降低。当 GnPs 含量为 1 wt% 时,网络效应开始显现,从而增强了纤维,但颗粒也阻碍了纤维中关键承载结晶结构的生长和取向。本研究揭示了 GnPs 对高度取向和结晶聚合物的微观结构影响,为今后开发高性能聚合物纳米复合纤维提供了重要启示。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
CiteScore
26.00
自引率
21.40%
发文量
185
期刊介绍: Advanced Composites and Hybrid Materials is a leading international journal that promotes interdisciplinary collaboration among materials scientists, engineers, chemists, biologists, and physicists working on composites, including nanocomposites. Our aim is to facilitate rapid scientific communication in this field. The journal publishes high-quality research on various aspects of composite materials, including materials design, surface and interface science/engineering, manufacturing, structure control, property design, device fabrication, and other applications. We also welcome simulation and modeling studies that are relevant to composites. Additionally, papers focusing on the relationship between fillers and the matrix are of particular interest. Our scope includes polymer, metal, and ceramic matrices, with a special emphasis on reviews and meta-analyses related to materials selection. We cover a wide range of topics, including transport properties, strategies for controlling interfaces and composition distribution, bottom-up assembly of nanocomposites, highly porous and high-density composites, electronic structure design, materials synergisms, and thermoelectric materials. Advanced Composites and Hybrid Materials follows a rigorous single-blind peer-review process to ensure the quality and integrity of the published work.
期刊最新文献
Photocatalytic degradation of Toluene by three-dimensional monolithic Titanium Dioxide / Cuprous Oxide foams with Z-schemed Heterojunction Development and characterization of zein/gum Arabic nanocomposites incorporated edible films for improving strawberry preservation Dynamically interactive nanoparticles in three-dimensional microbeads for enhanced sensitivity, stability, and filtration in colorimetric sensing Efficient charge separation in Z-scheme heterojunctions induced by chemical bonding-enhanced internal electric field for promoting photocatalytic conversion of corn stover to C1/C2 gases Multifunctional PVA/PNIPAM conductive hydrogel sensors enabled human-machine interaction intelligent rehabilitation training
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1