Fluorinated poly(p-triphenylene isatin) anion exchange membranes based on hydrophilic hydroxyl side chain modulation for fuel cells

IF 13.1 1区 化学 Q1 Energy Journal of Energy Chemistry Pub Date : 2024-09-13 DOI:10.1016/j.jechem.2024.09.008
Yiman Gu , Yanchao Zhang , Zhanyu Li , Yijia Lei , Baozeng Sun , Xiaoyu Yu , Zhe Wang
{"title":"Fluorinated poly(p-triphenylene isatin) anion exchange membranes based on hydrophilic hydroxyl side chain modulation for fuel cells","authors":"Yiman Gu ,&nbsp;Yanchao Zhang ,&nbsp;Zhanyu Li ,&nbsp;Yijia Lei ,&nbsp;Baozeng Sun ,&nbsp;Xiaoyu Yu ,&nbsp;Zhe Wang","doi":"10.1016/j.jechem.2024.09.008","DOIUrl":null,"url":null,"abstract":"<div><div>The development of alkaline fuel cells is moving forward at an accelerated pace, and the application of ether-free bonded polymers to anion exchange membranes (AEMs) has been widely investigated. However, the question of the “trade-off” between AEM ionic conductivity and dimensional stability remains difficult. The strategy of inducing microphase separation to improve the performance of AEM has attracted much attention recently, but the design of optimal molecular structures is still being explored. Here, this work introduced different ratios of 3-bromo-1,1,1-trifluoroacetone (<em>x</em> = 40, 50, and 60) into the main chain of poly(p-terphenylene isatin). Because fluorinated groups have excellent hydrophobicity, hydrophilic hydroxyl-containing side chains are introduced to jointly adjust the formation of phase separation structure. The results show that PTI-PTF<sub>50</sub>-NOH AEM with the appropriate fluorinated group ratio has the best ionic conductivity and alkali stability under the combined effect of both. It has an ionic conductivity of 133.83 mS cm<sup>−1</sup> at 80 °C. In addition, the OH<sup>−</sup> conductivity remains at 89% of the initial value at 80 °C and 3 M KOH for 1056 h of immersion. The cell polarization curve based on PTI-PTF<sub>50</sub>-NOH shows a power density of 734.76 mW cm<sup>−2</sup> at a current density of 1807.7 mA cm<sup>−2</sup>.</div></div>","PeriodicalId":15728,"journal":{"name":"Journal of Energy Chemistry","volume":"100 ","pages":"Pages 702-709"},"PeriodicalIF":13.1000,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Energy Chemistry","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2095495624006296","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"Energy","Score":null,"Total":0}
引用次数: 0

Abstract

The development of alkaline fuel cells is moving forward at an accelerated pace, and the application of ether-free bonded polymers to anion exchange membranes (AEMs) has been widely investigated. However, the question of the “trade-off” between AEM ionic conductivity and dimensional stability remains difficult. The strategy of inducing microphase separation to improve the performance of AEM has attracted much attention recently, but the design of optimal molecular structures is still being explored. Here, this work introduced different ratios of 3-bromo-1,1,1-trifluoroacetone (x = 40, 50, and 60) into the main chain of poly(p-terphenylene isatin). Because fluorinated groups have excellent hydrophobicity, hydrophilic hydroxyl-containing side chains are introduced to jointly adjust the formation of phase separation structure. The results show that PTI-PTF50-NOH AEM with the appropriate fluorinated group ratio has the best ionic conductivity and alkali stability under the combined effect of both. It has an ionic conductivity of 133.83 mS cm−1 at 80 °C. In addition, the OH conductivity remains at 89% of the initial value at 80 °C and 3 M KOH for 1056 h of immersion. The cell polarization curve based on PTI-PTF50-NOH shows a power density of 734.76 mW cm−2 at a current density of 1807.7 mA cm−2.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
基于亲水性羟基侧链调制的氟化聚(对三亚苯基靛蓝)阴离子交换膜,用于燃料电池
碱性燃料电池的开发正在加速进行,无醚键合聚合物在阴离子交换膜(AEM)中的应用已得到广泛研究。然而,如何在 AEM 离子导电性和尺寸稳定性之间进行 "权衡 "仍然是一个难题。最近,诱导微相分离以提高 AEM 性能的策略引起了广泛关注,但最佳分子结构的设计仍在探索之中。在此,本研究将不同比例的 3-溴-1,1,1-三氟丙酮(x = 40、50 和 60)引入聚对苯二甲酸丁二酯的主链中。由于氟化基团具有优异的疏水性,因此引入了亲水性的含羟基侧链,以共同调节相分离结构的形成。结果表明,在两者的共同作用下,具有适当氟化基比例的 PTI-PTF50-NOH AEM 具有最佳的离子导电性和碱稳定性。它在 80 °C 时的离子电导率为 133.83 mS cm-1。此外,在 80 °C 和 3 M KOH 溶液中浸泡 1056 小时后,羟基电导率仍保持在初始值的 89%。基于 PTI-PTF50-NOH 的电池极化曲线显示,在电流密度为 1807.7 mA cm-2 时,功率密度为 734.76 mW cm-2。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Journal of Energy Chemistry
Journal of Energy Chemistry CHEMISTRY, APPLIED-CHEMISTRY, PHYSICAL
CiteScore
19.10
自引率
8.40%
发文量
3631
审稿时长
15 days
期刊介绍: The Journal of Energy Chemistry, the official publication of Science Press and the Dalian Institute of Chemical Physics, Chinese Academy of Sciences, serves as a platform for reporting creative research and innovative applications in energy chemistry. It mainly reports on creative researches and innovative applications of chemical conversions of fossil energy, carbon dioxide, electrochemical energy and hydrogen energy, as well as the conversions of biomass and solar energy related with chemical issues to promote academic exchanges in the field of energy chemistry and to accelerate the exploration, research and development of energy science and technologies. This journal focuses on original research papers covering various topics within energy chemistry worldwide, including: Optimized utilization of fossil energy Hydrogen energy Conversion and storage of electrochemical energy Capture, storage, and chemical conversion of carbon dioxide Materials and nanotechnologies for energy conversion and storage Chemistry in biomass conversion Chemistry in the utilization of solar energy
期刊最新文献
Catalytic production of high-energy-density spiro polycyclic jet fuel with biomass derivatives Metallized polymer current collector as “stress acceptor” for stable micron-sized silicon anodes Microdynamic modulation through Pt–O–Ni proton and electron “superhighway” for pH-universal hydrogen evolution High-areal-capacity and long-life sulfide-based all-solid-state lithium battery achieved by regulating surface-to-bulk oxygen activity Introducing strong metal–oxygen bonds to suppress the Jahn-Teller effect and enhance the structural stability of Ni/Co-free Mn-based layered oxide cathodes for potassium-ion batteries
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1