Surface engineering of silica to control creep failure resistance of natural rubber-based composites for potential application in the suspension of rolling stock
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引用次数: 0
Abstract
Immobilization of polymer chains by silica on one side could increase the viscoelastic energy loss and on the other could postpone chain relaxations and temporarily conceal creep deformation. It is not yet clear how the formation of an interphase layer contributes to the change of creep resistance. Bifunctional silane, “Bis(triethoxysilylpropyl) disulfide” is employed to induce various degrees of covalent bonds at the rubber-silica interface, and also brings multiple degrees of immobilization. Interestingly, it was found that by controlling interfacial phenomena, the creep rate can be altered in a wide range of 4.35–1.65 (%/decade). It was mechanistically explained how the maximum creep resistance is observed for the sample having a medium level of surface treatment. The formation of a filler network indicated an essential role in increasing the high-temperature creep failure of systems having no favorable polymer-filler interaction.
期刊介绍：
Engineering Failure Analysis publishes research papers describing the analysis of engineering failures and related studies.
Papers relating to the structure, properties and behaviour of engineering materials are encouraged, particularly those which also involve the detailed application of materials parameters to problems in engineering structures, components and design. In addition to the area of materials engineering, the interacting fields of mechanical, manufacturing, aeronautical, civil, chemical, corrosion and design engineering are considered relevant. Activity should be directed at analysing engineering failures and carrying out research to help reduce the incidences of failures and to extend the operating horizons of engineering materials.
Emphasis is placed on the mechanical properties of materials and their behaviour when influenced by structure, process and environment. Metallic, polymeric, ceramic and natural materials are all included and the application of these materials to real engineering situations should be emphasised. The use of a case-study based approach is also encouraged.
Engineering Failure Analysis provides essential reference material and critical feedback into the design process thereby contributing to the prevention of engineering failures in the future. All submissions will be subject to peer review from leading experts in the field.
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