Fuzzy optimization of the photo-Fenton process on o-toluidine degradation in the aspect wastewater treatment

Abstract

Significant volumes of wastewater, particularly from the textile industry, pose environmental concerns due to the presence of hazardous substances such as ortho-toluidine (OT). The photo-Fenton process can be used to break down and remove this hazardous organic compound. Previous studies on the photo-Fenton process have focused on local optimization of operating variables without considering cost factors. The photo-Fenton process is studied in this paper with UVA irradiation, Fe²⁺ dosage, and H₂O₂ concentration considered as variables. The study uses fuzzy optimization in a multi-objective framework for making decisions to determine the optimal values of OT degradation with its corresponding cumulative uncertainty error (Y_A), and the total operating cost (C_T), both of which are essential for assessing the techno-economic feasibility of the process. The Pareto front was generated from the objective functions to establish the boundary limits for Y_A and C_T. The results show an overall satisfaction level of 71.81% for the objective functions, indicating a partially satisficing solution for maximizing OT degradation while minimizing operating cost. The optimum conditions of the variables require 85.70 W m⁻³ UVA irradiation, 0.5177 mM for Fe²⁺ dosage, and 7.85 mM for the H₂O₂ concentration. These conditions yielded an OT degradation value of 83.22% and a total operating cost of 768.61 USD·m⁻³. Comparison with previous literature showed an OT degradation efficiency that was 16.78% lower. However, this tradeoff in the process efficiency is offset by a total operating cost that is 2.28 times cheaper, emphasizing the cost-effectiveness of the fuzzy optimized solution.