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Graph theory-enhanced integrated distribution network reconfiguration and distributed generation planning: A comparative techno-economic and environmental impacts analysis
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-13 DOI: 10.1016/j.clet.2024.100808

In today's world, eco-friendly solutions are crucial for efficient power delivery and assessing their corresponding economic and environmental benefits is essential. As innovators, it is also imperative to continually improve on existing techniques to solve a problem. Evaluating the existing literature in this area of study, gaps of improving the optimization techniques by reducing the amount of infeasible configurations the reconfiguration procedure encounters was established, additionally, the need to utilize distributed generations that significantly reduce carbon footprint in the environment was also ascertained. Hence, this paper presents an effective integration method for the simultaneous reconfiguration of Radial Distribution Networks (RDNs) and Photovoltaic (PV) DGs allocation, considering the tripodal issues of cost, operational efficiency, and environmental sustainability. A modification of the adaptive mountain gazelle optimizer (AMGO) enhanced with graph theory is deployed for the optimization procedures. The crucial feature of the proposed approach is the reduction of unfeasible configurations throughout the optimization procedure toward satisfying the network's radiality constraints, achieving consistent convergence and reduced computation time. The technical benefits are active power loss minimization, voltage stability, and voltage profile improvement. The economic benefits are analyzed by estimating the purchased power, the associated cost of power losses, and the cost of DGs and switches over a planning period of 20 years. The consequent environmental benefits are analyzed in detail, highlighting the significant reduction in pollutant emissions. The proposed model was tested on the IEEE 33- and 69-bus RDN, considering several scenarios, including synchronous network reconfiguration and DG installations. From the results procured, the simultaneous network reconfiguration and DG allocation provided better outcomes, yielding minimum active power loss of 35.36 kW, minimum voltage of 0.9541 p.u., voltage stability index of 1.9936 p.u., total planning cost of $3.456 million, and emission of 1.744 million lb/hr, respectively, for the 33-bus systems. The corresponding value for the 69-bus system is 32.57 kW, 0.9832 p.u., 2.3847 p.u., $ 2.524 million, and 2.53 million lb/hr, respectively. The proposed model was compared with other reported techniques for performance validation, and its efficacy and superior performance was established.

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引用次数: 0
Assessing the durability of diverse leather tanning techniques for the manufacturing of leather goods through artificial aging processes
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-12 DOI: 10.1016/j.clet.2024.100807

In the context of the growing demand for sustainable consumption, especially in the fashion industry, leather remains an intriguing material. Its durability and quality not only ensure the longevity of products but also support the rise of practices like second-hand use and upcycling. This study evaluates the longevity of tanning alternatives - triazine-based and a combination of synthetic and vegetable tannins - compared to the widely used chrome tanning. Artificial aging processes, incorporating heat, humidity, UV exposure, and microbial conditions, were applied to leathers tanned with the three methods. Physico-mechanical measurements, commonly specified in industrial standards, were conducted alongside chemical analyses to evaluate potential degradations associated with chrome tanning as the reference. The aging processes impacted leather performances, but finished leathers remained suitable for applications. Indeed, results on finished leathers indicated minimal degradation after aging, emphasizing the importance of the protective layer for longevity. Considerations include adapting finishing to surface structures and addressing potential stiffness in triazine-tanned leather, necessitating further exploration.

在可持续消费需求不断增长的背景下,尤其是在时尚界,皮革仍然是一种耐人寻味的材料。它的耐用性和质量不仅确保了产品的使用寿命,而且还支持了二手使用和升级再造等做法的兴起。与广泛使用的铬鞣相比,本研究评估了鞣革替代品(基于三嗪的鞣革以及合成单宁和植物单宁的组合)的使用寿命。对使用这三种方法鞣制的皮革进行了人工老化处理,包括加热、湿度、紫外线照射和微生物条件。在进行化学分析的同时,还进行了工业标准中通常规定的物理机械测量,以评估与铬鞣相关的潜在降解作为参考。老化过程影响了皮革的性能,但成品皮革仍然适合应用。事实上,成品皮革的结果表明,老化后的降解程度极低,这强调了保护层对皮革使用寿命的重要性。需要考虑的问题包括根据表面结构进行涂饰,以及解决三嗪鞣革潜在的僵硬问题,这些都需要进一步的探索。
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引用次数: 0
Microfibres and coliforms determination and removal from wastewater treatment effluent 测定和去除废水处理废水中的微纤维和大肠菌群
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-08 DOI: 10.1016/j.clet.2024.100806

The research aim was to remove as many microfibres, microplastics and harmful bacteria as possible from the polluted water to produce suitable water for reuse. The test water was the effluent from the municipal wastewater treatment plant in Shalek Valley. A pilot plant with a ceramic SiC filter for membrane filtration and ozonation of filtered water was set up to remove suspended solids, micro-fibres, microplastics, and harmful microorganisms. The Microfibers Detection System was developed to identify microfibers on-site. The results showed that the microfiltration system combined with ozone treatment effectively removed total suspended solids, microfibres, microplastics and microorganisms. A detection system method for identifying microfibres and microplastic particles was used to determine how many microfibres and microorganisms were identified by membrane filtration and ozonation. The study showed that membrane filtration successfully removed all microfibres, 88% of total coliforms and 93% of E. coli. After additional ozonation, we achieved a 100% removal rate of total coliforms and a 100% removal rate of E. coli. The treated water (effluent from the municipal wastewater treatment plant) can be used for specific purposes, such as agricultural irrigation or enhancing bathing waters near the plant's water effluent.

研究的目的是尽可能多地去除污染水中的微纤维、微塑料和有害细菌,以生产出适合再利用的水。试验用水是来自沙莱克谷市政污水处理厂的污水。为了去除水中的悬浮固体、微纤维、微塑料和有害微生物,建立了一个使用碳化硅陶瓷过滤器进行膜过滤和臭氧处理的试验工厂。开发了微纤维检测系统,用于现场识别微纤维。结果表明,微过滤系统结合臭氧处理可有效去除总悬浮固体、微纤维、微塑料和微生物。使用了一种识别微纤维和微塑料颗粒的检测系统方法,以确定膜过滤和臭氧处理能识别多少微纤维和微生物。研究表明,膜过滤成功去除了所有微纤维、88% 的总大肠菌群和 93% 的大肠杆菌。经过额外的臭氧处理后,总大肠菌群的去除率达到 100%,大肠杆菌的去除率达到 100%。经过处理的水(城市污水处理厂的出水)可用于特定用途,如农业灌溉或改善工厂出水附近的浴场水质。
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引用次数: 0
Cloud point extraction of phenolics from sugarcane juice improves its usability as a carbon source in bioprocessing of lipids from Rhodosporidium kratochvilovae MTCC247 从甘蔗汁中云点提取酚类物质,提高了甘蔗汁作为碳源在从Rhodosporidium kratochvilovae MTCC247中提取脂质的生物加工中的可用性
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-05 DOI: 10.1016/j.clet.2024.100799

Sugarcane juice (ScJ) is a natural and renewable reservoir of sucrose, which makes it a sustainable carbon source for fermentative production of microbial products. This study encompasses the production of an oleaginous yeast (OY), Rhodosporidium kratochvilovae MTCC247 on ScJ-based nutrient medium and optimization of the fermentation process. Initially, ScJ was clarified by cloud point extraction (CPE) of polyphenols using Box Behnken Design resulting in 90.88 % reduction in polyphenols. After individual optimization of fermentation parameters such as initial pH, incubation temperature, agitation speed, aeration ratio and inoculum size, suitability of clarified ScJ as a sole carbon source was established by incorporating it in a fermentation medium to produce OY. Using a rotatable central composite design, optimal concentrations of medium components were determined to achieve maximum biomass production of 23.13 ± 1.72 g/L and maximum lipid production of 7.15 ± 0.377 g/L. The dynamics of fatty acid pool in OY were studied throughout fermentation. For efficient lipid extraction, a combination of mechanical method (high-speed homogenization) and chemical methods (acid treatment) could recover 93.14 ± 12 % lipids. Thus, this study illustrates the potential of clarified ScJ as a sustainable carbon source in bioprocessing of lipids from OY.

甘蔗汁(ScJ)是一种天然、可再生的蔗糖库,这使其成为发酵生产微生物产品的可持续碳源。本研究包括在以甘蔗汁为基础的营养培养基上生产一种含油酵母(OY)--Rhodosporidium kratochvilovae MTCC247,并优化发酵过程。最初,ScJ 采用盒式贝恩肯设计(Box Behnken Design)浊点萃取法(CPE)对多酚进行澄清,结果减少了 90.88 % 的多酚。在对发酵参数(如初始 pH 值、培养温度、搅拌速度、通气比和接种物大小)进行单独优化后,通过将澄清的 ScJ 加入发酵培养基中生产 OY,确定了其作为唯一碳源的适用性。采用可旋转中心复合设计,确定了培养基组分的最佳浓度,以实现 23.13 ± 1.72 克/升的最大生物量产量和 7.15 ± 0.377 克/升的最大脂质产量。在整个发酵过程中,对 OY 中脂肪酸池的动态进行了研究。为了高效提取脂质,机械方法(高速均质)和化学方法(酸处理)相结合可回收 93.14 ± 12 % 的脂质。因此,这项研究表明,在从 OY 中提取脂质的生物加工过程中,澄清的 ScJ 具有作为可持续碳源的潜力。
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引用次数: 0
Assessment of CO2 capture and storage onboard LNG vessels driven by energy recovery from engine exhaust 评估由发动机废气能量回收驱动的液化天然气船上二氧化碳捕集与封存技术
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-05 DOI: 10.1016/j.clet.2024.100802

The pressing need to significantly reduce global CO2 emissions requires the decarbonization of the shipping industry. Currently, shipping relies on fossil fuels with a shift from heavy oil to liquefied natural gas. The main engine is the primary energy user onboard vessels, and its exhaust is the main CO2 emission source. A potential path to reduce emissions onboard vessels is the capture, compression, and storage of CO2 from the exhaust gases. This requires effective integration across the engine, the capture technology, the CO2 compression, cooling, and storage. The integration of four alternative capture technology options is conceptually explored and assessed: chemical absorption, membranes, temperature swing adsorption, and cryogenic distillation. Integration schemes are developed for each of the four technologies that achieve carbon capture, compression, and storage driven by the exhaust gas waste heat as the only energy source. Heat and power requirements are met through heat integration and heat-to-power conversions using organic Rankine cycles (ORCs). The study was performed on an LNG vessel using LNG fuel in its main engine. Thermal capture technologies (absorption and adsorption) are observed to significantly outperform their alternatives (membranes and cryogenic distillation) and capture, compress, and store more than twice the amount of CO2 emissions from the engine exhaust stream. Finally, the proposed integration schemes resulted in self-sustainable onboard capture systems without combusting additional fuel.

大幅减少全球二氧化碳排放量的迫切需要要求航运业去碳化。目前,航运业依赖化石燃料,从重油转向液化天然气。主机是船上的主要能源消耗者,其废气是主要的二氧化碳排放源。从废气中捕捉、压缩和储存二氧化碳是减少船上排放的一条潜在途径。这需要对发动机、捕集技术、二氧化碳压缩、冷却和储存进行有效整合。我们从概念上探索和评估了四种可选捕集技术方案的整合:化学吸收、膜、变温吸附和低温蒸馏。为四种技术中的每一种制定了集成方案,以废气余热作为唯一能源,实现碳捕集、压缩和储存。通过热集成和使用有机郎肯循环 (ORC) 进行热电转换,可满足热能和电能需求。这项研究是在一艘使用液化天然气燃料的液化天然气船上进行的。据观察,热捕获技术(吸收和吸附)明显优于替代技术(膜和低温蒸馏),从发动机废气流中捕获、压缩和储存的二氧化碳排放量是替代技术的两倍多。最后,所提出的集成方案产生了可自我维持的车载捕获系统,而无需燃烧额外的燃料。
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引用次数: 0
Innovative pathways to sustainable energy: Advancements in clean coal technologies in Bangladesh - A review 可持续能源的创新之路:孟加拉国洁净煤技术的进步--综述
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-04 DOI: 10.1016/j.clet.2024.100805

As a densely populated country experiencing rapid economic growth, Bangladesh faces a surging demand for energy. Despite efforts to develop renewable energy sources, coal remains a significant share of the energy mix with a consumption of 2,099,900 tons. However, conventional coal utilization raises environmental concerns like greenhouse gas emissions and other hazardous pollutants. To tackle these issues, viable solutions like clean coal technologies come into play. These encompass high-efficiency low-emission (HELE) power stations, carbon capture utilization and storage (CCUS) systems, integrated gasification combined cycle (IGCC), as well as supercritical and ultra-supercritical steam cycles (S/USC), providing adequate means to reduce the ecological effects tied to coal-powered electricity production. This paper asserts that the strategic adoption of clean coal technologies can play a pivotal role in shaping Bangladesh's sustainable energy future, contingent upon robust policy frameworks, environmental impact and recommend that the government must incentivize HELE, CCUS, and clean coal as well as promote international collaboration. Moreover, modern coal preparation techniques and the future research direction are also discussed in this paper and additionally this study suggests that HELE technologies are more suitable for Bangladesh than other current technologies. These strategies have the potential to yield enhanced economic benefits and offer viable solutions for achieving the clean and efficient conversion of coal resources.

作为一个人口稠密、经济快速增长的国家,孟加拉国面临着能源需求激增的问题。尽管孟加拉国努力开发可再生能源,但煤炭仍在能源结构中占有重要份额,消耗量达 209.99 万吨。然而,传统的煤炭利用方式引发了温室气体排放和其他有害污染物等环境问题。为了解决这些问题,清洁煤炭技术等可行的解决方案应运而生。这些技术包括高效低排放(HELE)发电站、碳捕集利用与封存(CCUS)系统、整体煤气化联合循环(IGCC)以及超临界和超超临界蒸汽循环(S/USC),为减少煤炭发电对生态环境的影响提供了充分的手段。本文认为,战略性地采用洁净煤技术可在塑造孟加拉国可持续能源未来方面发挥关键作用,但这取决于强有力的政策框架、环境影响,并建议政府必须激励 HELE、CCUS 和洁净煤,并促进国际合作。此外,本文还讨论了现代煤炭制备技术和未来的研究方向,并认为 HELE 技术比其他现有技术更适合孟加拉国。这些战略具有提高经济效益的潜力,并为实现煤炭资源的清洁高效转化提供了可行的解决方案。
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引用次数: 0
Soft computing approaches for photovoltaic water pumping systems: A review 光伏水泵系统的软计算方法:综述
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-04 DOI: 10.1016/j.clet.2024.100800

Water pumping systems are crucial for extracting water from deep wells. However, electricity shortages and high fuel prices significantly impact the efficiency and reliability of these systems. Therefore, renewable energy sources have gained more attention as alternatives to fossil fuels. Photovoltaic (PV) energy-based pumping systems, in particular, are becoming popular, especially in rural areas where grid connections are often unavailable. Several factors influence the performance of photovoltaic water pumping systems (PVWPS), including solar irradiance, temperature, system design, maintenance, and pumping load. To ensure optimal performance under these varying conditions, two controllers are crucial. The first controller is the Maximum Power Point Tracking (MPPT) controller, designed to maximize power extraction from the PV panels under varying environmental conditions (in particular, solar radiation and temperature). The second controller regulates the speed and torque of the induction motor (IM) which drives the pump responsible for water extraction. Therefore, to improve the performance of these controllers under different conditions. This review paper first examines widely used soft computing methods, providing a detailed description of each. These methods are then applied to both the MPPT and the IM controllers, offering valuable insights for researchers looking to develop advanced PVWPS control configurations for future applications.

水泵系统对于从深井中抽水至关重要。然而,电力短缺和燃料价格高昂严重影响了这些系统的效率和可靠性。因此,作为化石燃料的替代品,可再生能源受到越来越多的关注。基于光伏(PV)能源的抽水系统尤其受到欢迎,特别是在农村地区,因为那里通常没有电网连接。影响光伏水泵系统(PVWPS)性能的因素很多,包括太阳辐照度、温度、系统设计、维护和水泵负荷。为确保在这些不同条件下实现最佳性能,两个控制器至关重要。第一个控制器是最大功率点跟踪 (MPPT) 控制器,设计用于在不同的环境条件下(尤其是太阳辐射和温度)最大限度地提取光伏电池板的功率。第二个控制器用于调节感应电机 (IM) 的速度和扭矩,该电机驱动负责抽水的水泵。因此,为了提高这些控制器在不同条件下的性能。本综述论文首先探讨了广泛使用的软计算方法,并对每种方法进行了详细说明。然后将这些方法应用于 MPPT 和 IM 控制器,为希望为未来应用开发先进 PVWPS 控制配置的研究人员提供有价值的见解。
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引用次数: 0
Optimizing biomass supply chains: A probabilistic approach to managing uncertainties in southwest Nigeria 优化生物质供应链:尼日利亚西南部管理不确定性的概率方法
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-03 DOI: 10.1016/j.clet.2024.100785

Efficient and sustainable use of biomass resources is crucial to meet the increasing demand for bio-based products and renewable energy. The biomass supply chain, which includes harvesting, collecting, logistics, storage, and pre-treatment, faces challenges due to uncertainties such as market fluctuations, equipment availability, weather conditions, and transportation constraints. These uncertainties often hinder the optimisation of the supply chain. This research work explores the performance of the biomass supply chain by optimizing operations while accounting for these uncertainties. Nigeria is faced with power issues and there are resources to combat the problem through generation of cleaner energy from biomass. Using mathematical modelling, the study evaluates the impact of uncertainty on key performance areas like feedstock supply, inventory management, transportation efficiency, and processing capacity. The research demonstrates the importance of incorporating uncertainty-aware solutions to minimize risks and improve the flexibility of the biomass supply chain. Sensitivity analyses and case studies shows that the proposed probabilistic modelling approach provides valuable insights into system vulnerabilities and effective strategies for optimizing operations under uncertain conditions. The findings highlight the potential of this approach to improve decision making, resource allocation, and promote sustainable practices in the biomass sector. Ultimately, the study contributes to advancing biomass supply chain management, paving the way for a more resilient and efficient use of bioresources.

生物质资源的高效和可持续利用对于满足日益增长的生物基产品和可再生能源需求至关重要。生物质供应链包括收获、收集、物流、储存和预处理,由于市场波动、设备可用性、天气条件和运输限制等不确定因素,生物质供应链面临着挑战。这些不确定性往往会阻碍供应链的优化。本研究工作在考虑这些不确定性的同时,通过优化操作来探索生物质供应链的性能。尼日利亚面临着电力问题,有资源可以通过利用生物质生产更清洁的能源来解决这一问题。通过数学建模,该研究评估了不确定性对原料供应、库存管理、运输效率和加工能力等关键绩效领域的影响。研究表明,纳入不确定性感知解决方案对于最大限度地降低风险和提高生物质供应链的灵活性非常重要。灵敏度分析和案例研究表明,所提出的概率建模方法可提供对系统脆弱性的宝贵见解,以及在不确定条件下优化运营的有效策略。研究结果凸显了这种方法在改善生物质行业的决策、资源分配和促进可持续发展实践方面的潜力。最终,这项研究有助于推进生物质供应链管理,为更有弹性、更有效地利用生物资源铺平道路。
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引用次数: 0
Aerodynamic performance improvement of 3-PB VAWT using blades with optimized tilted angles 使用优化倾斜角度的叶片改善 3-PB VAWT 的空气动力性能
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-03 DOI: 10.1016/j.clet.2024.100801

In the present work, a new configuration of the three-part blade (3-PB) Vertical Axis Wind Turbine (VAWT) is introduced. This new configuration is designed to further improve the aerodynamic performance of the 3-PB VAWT by tilting all three parts of every single blade along its central chord line. An optimization process is conducted to find the best tilt angle of blade parts in order to maximize the average total torque coefficient. The optimization process is applied to reference 3-PB VAWT with the help of a Genetic Algorithm (GA) and Artificial Neural Network (ANN) using the solutions of three-dimensional Reynolds averaged Navier-Stokes (RANS) equations at wind speed of 7 m/s and tip speed ratios from 0.44 to 1.77. Having analyzed different sets of tilt angles, a configuration with tilt angles of 30°, 31° , and 30° with respect to part 1, 2, and 3 was detected to be the best choice. The tilted 3-PB VAWT shows promising improvements in most tip speed ratios. Among them, a maximum improvement of 42.99% on the average of the total torque coefficient occurred at tip speed ratio of 0.89.

在本研究中,介绍了一种新的三部分叶片(3-PB)垂直轴风力涡轮机(VAWT)配置。这种新配置旨在通过沿中心弦线倾斜每个叶片的所有三个部分,进一步提高 3-PB VAWT 的气动性能。为了使平均总扭矩系数最大化,我们进行了优化处理,以找到叶片部件的最佳倾斜角度。在遗传算法(GA)和人工神经网络(ANN)的帮助下,利用三维雷诺平均纳维-斯托克斯(RANS)方程的解法,在风速为 7 米/秒、叶尖速度比为 0.44 至 1.77 的条件下,将优化过程应用于参考的 3-PB VAWT。在分析了不同的倾斜角度后,发现相对于第一、第二和第三部分的倾斜角度分别为 30°、31° 和 30°的配置是最佳选择。倾斜的 3-PB VAWT 在大多数叶尖速度比上都有可喜的改进。其中,在 0.89 的叶尖速度比下,总扭矩系数平均值的最大改进幅度为 42.99%。
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引用次数: 0
Clean and durable thick nanodiamond composite hard coating deposited on cemented carbide towards sustainable machining: Eco-friendly fabrication, characterization, and 3-E analysis 在硬质合金上沉积清洁耐用的厚纳米金刚石复合硬涂层,实现可持续加工:生态友好型制造、表征和 3-E 分析
IF 5.3 Q2 ENGINEERING, ENVIRONMENTAL Pub Date : 2024-09-03 DOI: 10.1016/j.clet.2024.100804

This research explores a sustainable approach for fabricating high-performance nanodiamond composite (NDC) hard coatings for dry machining. Aiming to address limitations in conventional coatings, such as environmental concerns, restricted film thickness, and compromised performance. The study utilizes Coaxial Arc Plasma Deposition (CAPD), a clean and efficient technique, to deposit thick (10 μm) NDC films directly on WC−Co substrates without chemical etching. Compared to traditional Chemical Vapor Deposition (CVD), CAPD offers significant advantages: lower temperature deposition, faster growth rate, and precise control over film thickness and morphology. The resulting NDC films boast exceptional durability due to their unique nanostructure, diamond nanocrystallites embedded in an amorphous carbon matrix. The addition of Al-interlayers (100–500 nm thickness) optimizes film properties. The optimal interlayer at 100 nm thickness not only mitigates the catalytic effects of Co but also enhances film hardness (50.4–58 GPa), Young's modulus (516–613.75 GPa), and adhesion (13–18.5 N) compared to films without an interlayer. Notably, the 100 nm Al-interlayer triples the deposition rate to 3.3 μm/h, achieving the desired thickness for effective hard coatings. The high density of grain boundaries within the films allows for exceptional stress release, enabling this increased thickness. Furthermore, these grain boundaries and the graphitic phase contribute to the film's superior tribological performance – a low coefficient of friction (0.1) and minimal wear rate (1.5 × 10⁻7 mm³/N⋅m) under dry machining conditions. These findings demonstrate the immense potential of CAPD-deposited NDC films as a sustainable alternative for advanced cutting tools, promoting environmental responsibility, economic viability, and energy efficiency.

这项研究探索了一种可持续的方法,用于制造用于干式加工的高性能纳米金刚石复合材料(NDC)硬涂层。旨在解决传统涂层的局限性,如环境问题、膜厚受限和性能受损。该研究利用同轴电弧等离子体沉积(CAPD)这一清洁高效的技术,直接在 WC-Co 基底上沉积厚(10 μm)的 NDC 薄膜,而无需进行化学蚀刻。与传统的化学气相沉积 (CVD) 相比,CAPD 具有显著的优势:沉积温度更低、生长速度更快、可精确控制薄膜厚度和形态。生成的 NDC 薄膜具有独特的纳米结构,即在无定形碳基体中嵌入金刚石纳米晶体,因而具有超强的耐久性。添加铝中间膜(厚度为 100-500 纳米)可优化薄膜性能。100 nm 厚度的最佳夹层不仅能减轻钴的催化作用,而且与没有夹层的薄膜相比,还能提高薄膜硬度(50.4-58 GPa)、杨氏模量(516-613.75 GPa)和附着力(13-18.5 N)。值得注意的是,100 nm 的铝中间膜将沉积速率提高了三倍,达到 3.3 μm/h,达到了有效硬涂层所需的厚度。薄膜内高密度的晶界可释放出特殊的应力,从而实现厚度的增加。此外,这些晶界和石墨相还有助于提高薄膜的摩擦学性能--在干式加工条件下,摩擦系数低(0.1),磨损率小(1.5 × 10-7 mm³/N-m)。这些发现证明了 CAPD 沉积 NDC 薄膜作为先进切削工具的可持续替代品的巨大潜力,可促进环境责任、经济可行性和能源效率。
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引用次数: 0
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Cleaner Engineering and Technology
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