{"title":"Novel magnetic properties of nanostructured Fe50Cr40P10 (wt.%) powders","authors":"","doi":"10.1080/10426507.2024.2395256","DOIUrl":null,"url":null,"abstract":"<div><div>The purpose of this investigation is to examine the evolution of phase formation, structural, microstructural, and magnetic properties of the Fe<sub>50</sub>Cr<sub>40</sub>P<sub>10</sub> (wt.%) powder mixture as a function of milling time. The Rietveld refinements of X-ray diffraction patterns indicated the formation of two <em>bcc</em> chromium solid solutions, Fe<sub>33</sub>Cr<sub>2</sub> and Fe<sub>2</sub>Cr<sub>5</sub>, embedded within α-Fe (P) solid solution. The magnetic measurements reveal a ferromagnetic behavior regardless of milling time, but highlight a new behavior of phosphorus as an alphagen element to promote the alpha iron chromium solid solution formation with lower hysteresis loss energy and maximum values of the magnetic properties (coercivity, H<sub>c</sub>, nucleation field, H<sub>n</sub>, initial µ<sub>i</sub> and maximum µ<sub>max</sub> magnetizations permeabilities as well as the hysteresis loss energy E<sub>HL</sub>). The evolution of magnetic fields has been correlated with the evolution of <<em>L</em>>, rms <σ<sup>2</sup>><sup>1/2</sup>, and dislocation density ρ.</div></div>","PeriodicalId":20056,"journal":{"name":"Phosphorus, Sulfur, and Silicon and the Related Elements","volume":null,"pages":null},"PeriodicalIF":1.4000,"publicationDate":"2024-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Phosphorus, Sulfur, and Silicon and the Related Elements","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/org/science/article/pii/S1042650724000340","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q4","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0
Abstract
The purpose of this investigation is to examine the evolution of phase formation, structural, microstructural, and magnetic properties of the Fe50Cr40P10 (wt.%) powder mixture as a function of milling time. The Rietveld refinements of X-ray diffraction patterns indicated the formation of two bcc chromium solid solutions, Fe33Cr2 and Fe2Cr5, embedded within α-Fe (P) solid solution. The magnetic measurements reveal a ferromagnetic behavior regardless of milling time, but highlight a new behavior of phosphorus as an alphagen element to promote the alpha iron chromium solid solution formation with lower hysteresis loss energy and maximum values of the magnetic properties (coercivity, Hc, nucleation field, Hn, initial µi and maximum µmax magnetizations permeabilities as well as the hysteresis loss energy EHL). The evolution of magnetic fields has been correlated with the evolution of <L>, rms <σ2>1/2, and dislocation density ρ.
期刊介绍:
Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.