{"title":"Comparison of volatiles evolving from selected highland and mare lunar regolith simulants during vacuum sintering","authors":"","doi":"10.1016/j.pss.2024.105982","DOIUrl":null,"url":null,"abstract":"<div><div>Volatiles evolving from JSC-1A, NU-LHT-4M and CSM-LHT-1G lunar regolith simulants during <em>in vacuo</em> thermal processing were analyzed using mass spectrometry as a function of temperature. Two high-fidelity simulants, JSC-1A (mare) and NU-LHT-4M (highland), were compared to a newly developed CSM-LHT-1G highland simulant, modified to closely match lunar geochemistry. Large autogenous gas loads were observed for all investigated materials. Mineralogical knowledge was used to identify and attribute individual volatile species to reacting, transforming, or decomposing constituents (hydrates, carbonates, sulfates, sulfides, clays, etc.) of the respective regolith simulant in the self-generated gas environment. Cumulative mass losses for individual simulant components as a function of temperature were quantified using mass spectrometry in conjunction with thermogravimetric analysis. Investigation of the four components of CSM-LHT-1G – anorthosite, basalt, augite, and glass – aided the attribution of volatile species to specific compounds and their respective sources. The results showed significant decomposition of non-lunar phases present in the man-made regolith simulants below the typical glass crystallization temperatures, which paves the way to devising methods for enhancing the fidelity of the simulants. High gas loads and corrosive gases (HF and HCl) were recognized as potential hazards, pertaining to the development of large testbed facilities.</div></div>","PeriodicalId":20054,"journal":{"name":"Planetary and Space Science","volume":null,"pages":null},"PeriodicalIF":1.8000,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Planetary and Space Science","FirstCategoryId":"101","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0032063324001466","RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"ASTRONOMY & ASTROPHYSICS","Score":null,"Total":0}
引用次数: 0
Abstract
Volatiles evolving from JSC-1A, NU-LHT-4M and CSM-LHT-1G lunar regolith simulants during in vacuo thermal processing were analyzed using mass spectrometry as a function of temperature. Two high-fidelity simulants, JSC-1A (mare) and NU-LHT-4M (highland), were compared to a newly developed CSM-LHT-1G highland simulant, modified to closely match lunar geochemistry. Large autogenous gas loads were observed for all investigated materials. Mineralogical knowledge was used to identify and attribute individual volatile species to reacting, transforming, or decomposing constituents (hydrates, carbonates, sulfates, sulfides, clays, etc.) of the respective regolith simulant in the self-generated gas environment. Cumulative mass losses for individual simulant components as a function of temperature were quantified using mass spectrometry in conjunction with thermogravimetric analysis. Investigation of the four components of CSM-LHT-1G – anorthosite, basalt, augite, and glass – aided the attribution of volatile species to specific compounds and their respective sources. The results showed significant decomposition of non-lunar phases present in the man-made regolith simulants below the typical glass crystallization temperatures, which paves the way to devising methods for enhancing the fidelity of the simulants. High gas loads and corrosive gases (HF and HCl) were recognized as potential hazards, pertaining to the development of large testbed facilities.
期刊介绍：
Planetary and Space Science publishes original articles as well as short communications (letters). Ground-based and space-borne instrumentation and laboratory simulation of solar system processes are included. The following fields of planetary and solar system research are covered:
• Celestial mechanics, including dynamical evolution of the solar system, gravitational captures and resonances, relativistic effects, tracking and dynamics
• Cosmochemistry and origin, including all aspects of the formation and initial physical and chemical evolution of the solar system
• Terrestrial planets and satellites, including the physics of the interiors, geology and morphology of the surfaces, tectonics, mineralogy and dating
• Outer planets and satellites, including formation and evolution, remote sensing at all wavelengths and in situ measurements
• Planetary atmospheres, including formation and evolution, circulation and meteorology, boundary layers, remote sensing and laboratory simulation
• Planetary magnetospheres and ionospheres, including origin of magnetic fields, magnetospheric plasma and radiation belts, and their interaction with the sun, the solar wind and satellites
• Small bodies, dust and rings, including asteroids, comets and zodiacal light and their interaction with the solar radiation and the solar wind
• Exobiology, including origin of life, detection of planetary ecosystems and pre-biological phenomena in the solar system and laboratory simulations
• Extrasolar systems, including the detection and/or the detectability of exoplanets and planetary systems, their formation and evolution, the physical and chemical properties of the exoplanets
• History of planetary and space research
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