Advanced catalytic and biomedical applications of silver functionalized SnCuO3 nanocomposites synthesized through novel surfactant mediated chemical approach

IF 2.5 Q2 CHEMISTRY, MULTIDISCIPLINARY Results in Chemistry Pub Date : 2024-10-01 DOI:10.1016/j.rechem.2024.101833
Riaz Ahmad Khan , Hidayat Ullah Khan , Sameerah I. Al-Saeedi , Shahnaz , Kamran Tahir , Afaq Ullah Khan , Nora Awad Alkudaisi , Zainab M. Almarhoon , Magdi E.A. Zaki , Abdus Subhan
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Abstract

In the current contribution, silver impregnated and un impregnated bimetallic oxide nanocomposites of SnCuO3 were synthesized by a novel surfactant mediated chemical approach. The tween-80 was used as a surfactant to effectively modulate the morphological features of the nanocomposites. The synthesized nanocomposites were characterized by XRD, HRTEM, SEM, EDX, FTIR and XPS. The results revealed the rod-shaped surface morphology of the nanocomposites with length and diameter of 245 nm and 66 nm respectively. The synthesized nanocomposites were tested for catalytic and biomedical applications. The rate of catalytic degradation reaction of methylene blue by the SnCuO3 and Ag/SnCuO3 nanocomposites were found to be 10.2 and 8.5 respectively. Only in 10 min all the dye molecules were degraded. The synthesized nanomaterials SnCuO3 and Ag/SnCuO3 are potent antileishmanial agents having CC50 value 12728.03 and 3001.70 µg/mL respectively that were found to be biocompatible with very low toxicity as revealed by their hemolytic activity results. Moreover, the nanostructures exhibited promising antibacterial properties by effectively inhibiting the growth of both E. coli and S. aureus bacteria through photoinhibition. When subjected to visible light irradiation, the growth inhibition zone of Ag/SnCuO3 against E. coli and S. aureus was measured at (15 ± 0.4 mm) and (17 ± 0.3 mm), respectively. These nanostructures demonstrated the ability to impede bacterial proliferation and viability, underscoring their potential for use in water disinfection and as antibacterial coatings utilizing Ag/SnCuO3.

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通过新型表面活性剂介导化学方法合成的银功能化 SnCuO3 纳米复合材料的高级催化和生物医学应用
本研究采用新型表面活性剂介导化学方法合成了浸银和未浸银的 SnCuO3 双金属氧化物纳米复合材料。使用吐温-80 作为表面活性剂可有效调节纳米复合材料的形态特征。通过 XRD、HRTEM、SEM、EDX、FTIR 和 XPS 对合成的纳米复合材料进行了表征。结果表明,纳米复合材料的表面形态呈棒状,长度和直径分别为 245 nm 和 66 nm。对合成的纳米复合材料进行了催化和生物医学应用测试。结果发现,SnCuO3 和 Ag/SnCuO3 纳米复合材料催化亚甲基蓝降解反应的速率分别为 10.2 和 8.5。仅在 10 分钟内,所有染料分子都被降解。合成的 SnCuO3 和 Ag/SnCuO3 纳米材料是强效的抗利什曼病菌剂,其 CC50 值分别为 12728.03 和 3001.70 µg/mL。此外,纳米结构通过光抑制作用有效抑制了大肠杆菌和金黄色葡萄球菌的生长,表现出良好的抗菌特性。在可见光照射下,Ag/SnCuO3 对大肠杆菌和金黄色葡萄球菌的生长抑制区分别为(15 ± 0.4 mm)和(17 ± 0.3 mm)。这些纳米结构显示出了阻碍细菌增殖和存活的能力,突出了它们在水消毒和利用 Ag/SnCuO3 作为抗菌涂层方面的应用潜力。
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来源期刊
Results in Chemistry
Results in Chemistry Chemistry-Chemistry (all)
CiteScore
2.70
自引率
8.70%
发文量
380
审稿时长
56 days
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