Outbursts Upon Cooling of Low-Temperature Binary Mixtures: Experiments and Their Planetary Implications

Abstract

For many binary mixtures, the three-phase solid-liquid-vapor equilibrium curve has intermediate pressures that are higher than the pressure at the two pure triple points. This curve shape results in a negative slope in the high-temperature region near the triple point of the less volatile component. When freezing mixtures in the negative slope regime, fluid trapped below confined ice has latent heat released with more vapor upon cooling, and thus increases in pressure. If the rising pressure of the confined fluid overcomes the strength of the confining solid, which may be its own ice, it can produce an abrupt outburst of material and an increase in the system's overall pressure. Here, we report experimental results of freezing-induced outbursts occurring in the N₂/CH₄, CO/CH₄, and N₂/C₂H₆ systems, and provide insight into the phenomenon through a thermodynamics perspective. We also propose other binary systems that may experience outbursts and explore the geological implications for icy worlds such as Titan, Triton, Pluto and Eris as well as rocky bodies, specifically Earth and Mars.