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Magmatic Evolution of the Marius Hills, Rümker Hills, and Gardner Volcanic Complexes on the Moon: Constraints From Topography and Gravity 月球上马里乌斯山、r<s:1> mker山和加德纳火山复合体的岩浆演化:来自地形和重力的限制
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-21 DOI: 10.1029/2024JE008421
Haolin Yin, Qian Huang, Feng Zhang, Meixia Geng, Yuchao Chen, Jiannan Zhao

Marius Hills, Rümker Hills, and Gardner are three prominent volcanic complexes on the lunar nearside characterized by well-preserved elevated topography, highly concentrated domes/cones, and positive gravity anomalies. Here, we perform a comparative study of the geology and geophysics of these three volcanic complexes using multi-source remote-sensing data to better understand the volcanism diversity and magmatic evolution of the lunar nearside. Uniform and precise feature extraction methods are used to explore the morphological and geochemical characteristics of the volcanic complexes and their quasi-circular small shields (domes/cones). A new generalized approach based on three-dimensional (3D) gravity forward modeling is utilized to estimate the subsurface magma intrusion volumes. The results are about 2.63–6.65 × 104, 1.48–3.86 × 104, and 2.75–4.22 × 104 km3 for the Marius Hills, Rümker Hills, and Gardner, respectively. Together with their extrusion volumes, Marius Hills has the largest magnitude of magmatic activity and the lowest ratio of intrusive versus extrusive volumes. Taking into account their geological and geophysical diversities, we propose three magma intrusion and extrusion schematic models and suggest that potassium, rare earth elements, and phosphorus (KREEP) may serve as an important driving force for the long-term and large-magnitude volcanism in Marius Hills, while the relatively short-lived and small-scale volcanism in Rümker Hills and Gardner may not be related to KREEP. Future geochemical studies of basalt samples from the Marius Hills region may provide additional clues to the role of KREEP in lunar nearside volcanism and thermal evolution.

Marius Hills, r mker Hills和Gardner Hills是月球近侧三个著名的火山复合体,其特征是保存完好的高架地形,高度集中的圆顶/锥体,以及正重力异常。本文利用多源遥感数据对这三个火山复合体进行了地质和地球物理对比研究,以更好地了解月球近侧的火山作用多样性和岩浆演化。采用均匀、精确的特征提取方法,探索火山杂岩体及其准圆形小盾构(穹/锥)的形态和地球化学特征。采用一种基于三维重力正演模拟的广义方法估算地下岩浆侵入体积。结果表明,马里乌斯山、r mker山和加德纳山分别为2.63 ~ 6.65、1.48 ~ 3.86和2.75 ~ 4.22 × 104 km3。马略斯山岩浆活动强度最大,侵入体积与挤压体积之比最低。考虑到它们的地质和地球物理多样性,我们提出了3种岩浆侵入和挤压示意图模型,并认为钾、稀土元素和磷(KREEP)可能是Marius Hills长期和大规模火山活动的重要驱动力,而r mker Hills和Gardner Hills相对短暂和小规模的火山活动可能与KREEP无关。未来对马里乌斯山地区玄武岩样品的地球化学研究可能会为KREEP在月球近地火山作用和热演化中的作用提供更多线索。
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引用次数: 0
Tadpole-Shaped Nanoparticles in Impact Melt and Implication of High Temperature Chemical Garden in Lunar Soil 月球土壤中蝌蚪状纳米颗粒的撞击熔化及其高温化学园的意义
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-21 DOI: 10.1029/2024JE008584
Qi He, Wentao Hu, Long Xiao, Xiang Zhang, Zaicong Wang, Yuqi Qian, Jinfu Shu, Jiawei Zhao, Yuqing Chang, Chen Li, Zhiyong Xiao, Xiaoping Zhang, Yiheng Li, Papineau Dominic, Siyuan Zhao, Jun Huang, Jiannan Zhao, Jiang Wang, Xiang Wu, Zhaochu Hu, Keqing Zong, Zhenbing She, Yang Li

Nanoparticles within lunar soil grains are a primary product of space weathering. The microstructural and chemical characteristics of the nanoparticles are diverse and their formation mechanisms are still under debate. In this paper, for the first time, tadpole-shaped nanoparticles (with Fe-Ni(-S) head and Fe-Ti-O tail) were found in the impact melt glass spherule of an agglutinate in the returned Chang'e-5 lunar soil, and their possible formation mechanisms were discussed. In terms of the Fe-Ni(-S) “head” formation mechanisms, they probably produced by shock-induced dissemination. Another possibility is that the Fe-Ni(-S) heads were derived from the impact glass due to liquid immiscibility. The S degassing of FeS was contributed to nanophase Fe-Ni metal. For the Fe-Ti-O tails, they are devitrified ilmenites, nucleated as a result of the passage of the Fe nanoparticles through the melt. These nanoparticles formed though impact-induced nonequilibrium growth and recorded the movement and migration of the Fe-Ni-S nanoparticles within the melt. The tadpole-shape nanoparticles provide a new example of viscous fingering in impact melts and the associated ilmenite dendrites point to the formation of high-temperature chemical gardens in lunar impact melt.

月球土壤颗粒中的纳米颗粒是空间风化的主要产物。纳米颗粒的微观结构和化学特性是多种多样的,其形成机制仍在争论中。本文首次在“嫦娥五号”返回月球土壤的撞击熔融玻璃球中发现了具有Fe-Ni(-S)头部和Fe-Ti-O尾部的蝌蚪状纳米颗粒,并对其可能的形成机制进行了探讨。就Fe-Ni(-S)“头”的形成机制而言,它们可能是由冲击诱导扩散产生的。另一种可能性是Fe-Ni(-S)头是由于液体不混溶而从冲击玻璃中产生的。fees的S脱气是纳米相Fe-Ni金属的重要组成部分。对于Fe- ti - o尾部,它们是反氮化钛矿,由于Fe纳米颗粒通过熔体而成核。这些纳米颗粒通过碰撞诱导的非平衡生长形成,并记录了Fe-Ni-S纳米颗粒在熔体中的运动和迁移。蝌蚪状纳米颗粒提供了撞击熔体中粘性指状的新例子,而相关的钛铁矿枝晶则指向了月球撞击熔体中高温化学园的形成。
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引用次数: 0
Mapping of Western Valles Marineris Light-Toned Layered Deposits and Newly Classified Rim Deposits 西部山谷水手号浅色层状矿床和新分类边缘矿床的测绘
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-19 DOI: 10.1029/2024JE008425
Ivan G. Mishev, Isaac B. Smith, Cathy Quantin, Patrick Thollot, Nathaniel E. Putzig, Christina Viviano, Matt Chojnacki, Bruce Campbell

Layered deposits are found on the plateaus surrounding the western portion of Valles Marineris, mantling the chasmata rims. These rim deposits exhibit intricate layering and are described as light-toned layered deposits (LLDs) in previous studies. Light-toned layered deposits are thought to be composed of pyroclastic ash that was emplaced during volcanic eruptions and later chemically altered. Using Shallow Radar (SHARAD) observations to map radar reflections from what appears to be the base of these deposits, we discovered two additional types of rim deposits that are contiguous with the well-known LLDs; weakly layered deposits (WLDs) that exhibit less obvious stratification and completely unstratified deposits designated as nonlayered deposits (NDs). Complementing the SHARAD data with imagery from Mars Reconnaissance Orbiter's High Resolution Imaging Science Experiment (HiRISE) and Context Camera (CTX) and with narrow-angle imagery from the Mars Global Surveyor Mars Observer Camera (MOC-NA), we mapped the full extent of all rim deposits and present the finished map within this study. We hypothesize that all three deposits originate from pyroclastic ashfall but experienced different degrees of modification due to the variable presence of liquid water. This hypothesis requires a source of volcanic depositional material and past aqueous environments in regions with LLDs and WLDs. We discuss the potential for several large Tharsis volcanoes and a hypothesized degraded volcano within Noctis Labyrinthus as sources of the ash, and we examine the evidence for past aqueous environments.

在水手号峡谷西部的高原上发现了层状沉积物,覆盖着峡谷边缘。这些边缘沉积物表现出复杂的分层,在以前的研究中被描述为浅色层状沉积物(LLDs)。浅色的层状沉积物被认为是由火山爆发时形成的火山碎屑火山灰组成的,这些火山灰后来发生了化学变化。利用浅层雷达(SHARAD)观测来绘制这些矿床底部的雷达反射图,我们发现了两种附加类型的边缘矿床,它们与众所周知的LLDs相邻;弱层状矿床(wld),层状不太明显,完全无层状的矿床称为非层状矿床(NDs)。利用火星勘测轨道器的高分辨率成像科学实验(HiRISE)和背景相机(CTX)以及火星全球勘测者火星观测相机(MOC-NA)的窄角度图像补充SHARAD数据,我们绘制了所有边缘沉积物的全部范围,并在本研究中展示了完成的地图。我们假设这三种矿床都起源于火山碎屑火山灰,但由于液态水的存在变化而经历了不同程度的改造。这一假说需要有火山沉积物质的来源,以及有低陆块和低陆块的地区过去的水环境。我们讨论了几个大型塔尔西斯火山和诺克提斯迷宫内一个假设的退化火山作为火山灰来源的可能性,并研究了过去水环境的证据。
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引用次数: 0
Extensive Secondary Cratering From the InSight Sol 1034a Impact Event 来自洞察号Sol 1034a撞击事件的大量次级陨石坑
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-18 DOI: 10.1029/2024JE008535
P. M. Grindrod, I. J. Daubar, B. Fernando, D. Kim, G. S. Collins, S. C. Stähler, N. Wojcicka, L. V. Posiolova, M. Froment, É. Beucler, E. Sansom, R. Garcia, G. Zenhäusern

Impact cratering is one of the fundamental processes throughout the history of the Solar System. The formation of new impact craters on planetary bodies has been observed with repeat images from orbiting satellites. However, the time gap between images is often large enough to preclude detailed analysis of smaller-scale features such as secondary impact craters, which are often removed or buried over a short time period. Here we use a seismic event detected on Mars by the NASA InSight mission to investigate secondary cratering at a new impact crater. We strengthen the case that the seismic event that occurred on Sol 1034 (S1034a) is the result of a new impact cratering event. Using the exact timing of this event from InSight, we investigated the resulting new impact crater in orbital image data. The S1034a impact crater is approximately 9 m in diameter but is responsible for over 900 secondary impact events in the form of low albedo spots that are located at distances of up to almost 7 km from the primary crater. We suggest that the low albedo spots formed from relatively low energy ejecta, with individual ejecta block velocities less than 200 m s−1. We estimate that the low albedo spots, the main evidence of secondary impact processes at this new impact event, fade within 200–300 days after formation.

撞击坑是贯穿太阳系历史的基本过程之一。行星体上新撞击坑的形成是通过轨道卫星的重复图像观测到的。然而,由于图像之间的时间间隔往往足够大,因此无法对较小尺度的特征(如二次撞击坑)进行详细分析,这些撞击坑通常会在短时间内被移除或掩埋。在这里,我们利用美国国家航空航天局(NASA)"洞察"(InSight)任务在火星上探测到的地震事件来研究一个新撞击坑的二次塌陷。我们进一步证明,在第1034溶日(S1034a)发生的地震事件是新的撞击坑事件的结果。利用 InSight 提供的这次事件的确切时间,我们在轨道图像数据中调查了由此产生的新撞击坑。S1034a 撞击坑的直径约为 9 米,但却造成了 900 多次以低反照率斑形式出现的二次撞击事件,这些低反照率斑距离主撞击坑最远可达近 7 千米。我们认为,低反照率斑是由能量相对较低的抛射物形成的,单个抛射物块的速度小于 200 m s-1。我们估计,低反照度斑是这一新撞击事件二次撞击过程的主要证据,在形成后 200-300 天内消退。
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引用次数: 0
Characterizing the Modulation and Activation-Triggering Mechanisms of Main-Belt Comets via 3D Thermophysical Modeling of an Ellipsoidal Body 利用椭球体三维热物理模型表征主带彗星的调制和激活触发机制。
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-14 DOI: 10.1029/2023JE008047
Yun Zhang, Christine M. Hartzell

Main-belt objects (MBOs) with volatile components provide important insights into the solar system's evolution and the origin of Earth's water. In this study, we employ a 3D thermophysical model to simulate the evolution of a representative ellipsoidal main-belt comet (MBC) and investigate the factors influencing its gas and dust activity. Our results highlight the important role of large obliquities in amplifying the detectability of sublimation-driven dust emission in MBCs. For the modeled ellipsoidal 133P/Elst-Pizarro, we found an obliquity of at least 30° ${sim} 30{}^{circ}$ is likely required to sustain a dust production rate of ${sim} $0.01 kg/s (this required obliquity increases to 45° ${ge} sim 45{}^{circ}$ for a dust production rate of ${ge} sim $0.1 kg/s). By exploring the influence of locations and sizes of ice-exposed surface regions, we find that both the impact-triggered and landslide-triggered ice-exposure mechanisms can lead to detectable dust and gas activities for the modeled MBC. With probable distributions of ice-exposed surface regions, our results show that MBCs' sublimation-driven activity should be predominantly detectable near perihelion, independent of the true anomaly at solstice and the activation-triggering mechanism. Moreover, we find that the landslide-triggered mechanism results in dual peaks in dust and gas emission curves. This enables potential differentiation between the two mechanisms, suggesting that monitoring of MBCs' activity at various orbital positions is important to discern the underlying activation-triggering mechanism. Our analyses provide quantitative constraints on producing the observable cometary activity in ice-containing MBOs and highlight the importance of studying the rotational evolution and structural dynamics of ice-containing MBOs in characterizing their overall population.

具有挥发性成分的主带天体(MBO)为了解太阳系的演化和地球水的起源提供了重要线索。在这项研究中,我们采用三维热物理模型模拟了一颗具有代表性的椭圆形主带彗星(MBC)的演化过程,并研究了影响其气体和尘埃活动的因素。我们的研究结果凸显了大倾角在放大升华驱动的尘埃发射的可探测性方面的重要作用。对于建模的椭圆形 133P/Elst-Pizarro 星,我们发现要维持每秒 ∼ 0.01 千克的尘埃产生率,至少需要 30 ° 的倾角(尘埃产生率≥ ∼ 0.1 千克时,所需的倾角增加到≥ ∼ 45 °)。通过探索冰暴露表面区域的位置和大小的影响,我们发现撞击触发和滑坡触发的冰暴露机制都能导致模拟的中生代冰川出现可探测到的尘埃和气体活动。根据冰暴露表面区域的可能分布,我们的结果表明,在近日点附近,主要应能探测到中生代的升华驱动活动,这与至日的真实异常和激活触发机制无关。此外,我们还发现滑坡触发机制会导致尘埃和气体发射曲线出现双峰。这就为区分这两种机制提供了可能,表明监测不同轨道位置上的多溴联苯活动对于辨别潜在的激活触发机制非常重要。我们的分析为在含冰 MBOs 中产生可观测到的彗星活动提供了定量约束,并强调了研究含冰 MBOs 的旋转演变和结构动态对确定其总体特征的重要性。
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引用次数: 0
Complex Crater Collapse: A Comparison of the Block and Melosh Acoustic Fluidization Models of Transient Target Weakening 复杂陨石坑坍塌:瞬态目标弱化的块体模型与梅洛什声学流化模型的比较。
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-14 DOI: 10.1029/2024JE008544
Hamish C. F. C. Hay, Gareth S. Collins, Thomas M. Davison, Andrea Rajšić, Brandon C. Johnson

The collapse of large impact craters requires a temporary reduction in the resistance to shear deformation of the target rocks. One explanation for such weakening is acoustic fluidization, where impact-generated pressure fluctuations temporarily and locally relieve overburden pressure facilitating slip. A model of acoustic fluidization widely used in numerical impact simulations is the Block model. Simulations employing the Block model have successfully reproduced large-scale crater morphometry and structural deformation but fail to predict localized weakening in the rim area and require unrealistically long pressure fluctuation decay times. Here, we modify the iSALE shock physics code to implement an alternative model of acoustic fluidization, which we call the Melosh model, that accounts for regeneration and scattering of acoustic vibrations not considered by the Block model. The Melosh model of acoustic fluidization is shown to be an effective model of dynamic weakening, differing from the Block model in the style of crater collapse and peak ring formation that it promotes. While the Block model facilitates complex crater collapse by weakening rocks deep beneath the crater, the Melosh model results in shallower and more localized weakening. Inclusion of acoustic energy regeneration in the Melosh model reconciles required acoustic energy dissipation rates with those typically derived from crustal seismic wave propagation analysis.

大型撞击坑的坍塌需要暂时降低目标岩石的抗剪切变形能力。对这种减弱的一种解释是声流体化,即撞击产生的压力波动暂时和局部缓解了覆盖层压力,从而促进了滑移。数值冲击模拟中广泛使用的声流化模型是布洛克模型。采用布洛克模型进行的模拟成功地再现了大尺度陨石坑形态和结构变形,但无法预测边缘区域的局部减弱,而且需要不切实际的较长的压力波动衰减时间。在这里,我们修改了 iSALE 冲击物理代码,以实现另一种声学流化模型,我们称之为 Melosh 模型,该模型考虑了 Block 模型未考虑的声学振动的再生和散射。研究表明,Melosh 声流化模型是一种有效的动态衰弱模型,它与布洛克模型的不同之处在于它所促进的陨石坑坍塌和峰环形成的方式。布洛克模型通过削弱陨石坑下方深处的岩石来促进复杂的陨石坑坍塌,而梅洛什模型则导致更浅、更局部的削弱。在梅洛什模型中加入声能再生,使所需的声能耗散率与通常从地壳地震波传播分析中得出的声能耗散率相一致。
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引用次数: 0
Using the Melosh Model of Acoustic Fluidization to Simulate Impact Crater Collapse on the Earth and Moon 利用Melosh声流化模型模拟地球和月球上的撞击坑坍塌。
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-14 DOI: 10.1029/2024JE008562
A. Rajšić, B. C. Johnson, G. S. Collins, H. C. F. C. Hay
<p>The formation of complex craters requires some form of transient weakening of target rocks. Acoustic fluidization is one proposed mechanism applied in many numerical simulations of large crater formation. In a companion paper, we describe implementing the Melosh model of acoustic fluidization in the iSALE shock physics code. Here, we explore the effect of Melosh model parameters on crater collapse and determine the range of parameters that reproduce observed crater depth-to-diameter trends on the Earth and Moon. Target viscosity in the Melosh model is proportional to the vibrational wavelength, <span></span><math> <semantics> <mrow> <mi>λ</mi> </mrow> <annotation> $lambda $</annotation> </semantics></math>, and the longevity of acoustic vibrations is <span></span><math> <semantics> <mrow> <mo>∝</mo> <mi>λ</mi> <mi>Q</mi> </mrow> <annotation> $propto lambda Q$</annotation> </semantics></math> (<span></span><math> <semantics> <mrow> <mi>Q</mi> </mrow> <annotation> $Q$</annotation> </semantics></math>—quality factor). Our simulations show that <span></span><math> <semantics> <mrow> <mi>λ</mi> </mrow> <annotation> $lambda $</annotation> </semantics></math> affects the size of the fluidized region, its fluidity, and the magnitude of the vibrations, producing a variety of crater collapse styles. The size of the fluidized region is strongly affected by the <span></span><math> <semantics> <mrow> <mi>Q</mi> </mrow> <annotation> $Q$</annotation> </semantics></math>. The regeneration factor, <span></span><math> <semantics> <mrow> <mi>e</mi> </mrow> <annotation> $e$</annotation> </semantics></math>, controls the amount of (re)generated acoustic energy and its localization. We find that a decrease in <span></span><math> <semantics> <mrow> <mi>e</mi> </mrow> <annotation> $e$</annotation> </semantics></math> leads to less crater collapse and that there are trade-offs between <span></span><math> <semantics> <mrow> <mi>e</mi> </mrow> <annotation> $e$</annotation> </semantics></math> and <span></span><math> <semantics> <mrow> <mi>Q</mi>
复杂陨石坑的形成需要对目标岩石进行某种形式的瞬时削弱。声流化是许多大型陨石坑形成数值模拟中应用的一种拟议机制。在另一篇论文中,我们介绍了在 iSALE 冲击物理代码中实施梅洛什声流化模型的情况。在这里,我们探讨了梅洛什模型参数对陨石坑坍塌的影响,并确定了能够再现地球和月球上观测到的陨石坑深度-直径趋势的参数范围。梅洛什模型中的目标粘度与振动波长λ成正比,声振动的寿命为∝ λ Q(Q - 质量因子)。我们的模拟结果表明,λ 会影响流化区的大小、流动性和振动幅度,从而产生各种陨石坑崩塌方式。流化区的大小受 Q 的影响很大。再生因子 e 控制着(重新)产生的声能及其定位。我们发现,减少 e 会导致更少的陨石坑坍塌,并且 e 和 Q 之间存在权衡。这种权衡使得 Q 值比 Block 模型中使用的 Q 值更符合实际情况。振动在高应力和高应变区域的扩散由散射项 ξ 控制。与布洛克模型相比,梅洛什模型使复杂陨石坑中的削弱区变浅,并增强了陨石坑边缘周围的应变局部化。产生最佳深度-直径趋势的参数集是 λ = 0.2 × 撞击器半径,Q = 10-50,e = 0.025-0.1,ξ = 10- 10 5 m 2 s - 1。
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引用次数: 0
Diagenesis of the Clay-Sulfate Stratigraphic Transition, Mount Sharp Group, Gale Crater, Mars 火星盖尔陨石坑夏普山群粘土-硫酸盐地层转换的成岩作用。
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-06 DOI: 10.1029/2024JE008531
C. H. Seeger, J. P. Grotzinger

The diversity and abundance of diagenetic textures observed in sedimentary rocks of the clay-sulfate transition recorded in the stratigraphic record of Gale crater are distinctive within the rover's traverse. This study catalogs all textures observed by the MAHLI instrument, including their abundances, morphologies, and cross-cutting relationships in order to suggest a paragenetic sequence in which multiple episodes of diagenetic fluid flow were required to form co-occurring color variations, pits, and nodules; secondary nodule populations; and two generations of Ca sulfate fracture-filling vein precipitation. Spatial heterogeneities in the abundance and diversity of these textures throughout the studied stratigraphic section loosely correlate with stratigraphic unit, suggesting that grain size and compaction controls on fluid pathways influenced their formation; these patterns are especially prevalent in the Pontours member, where primary stratigraphy is entirely overprinted by a nodular fabric, and the base of the stratigraphic section, where increased textural diversity may be influenced by the underlying less permeable clay-bearing rocks of the Glen Torridon region. Correlations between quantitative nodule abundance and subtle variations in measured bulk rock chemistry (especially MgO and SO3 enrichment) by the Alpha Particle X-Ray Spectrometer instrument suggest that an increase in Mg sulfate upsection is linked to precipitation of pore-filling diagenetic cement. Due to a lack of sedimentological evidence for widespread evaporite or near-surface crust formation of these Mg sulfates, we propose three alternative hypotheses for subsurface groundwater-related remobilization of pre-existing sulfates and reprecipitation at depth in pore spaces.

盖尔陨石坑地层记录中所记录的粘土-硫酸盐转变沉积岩中所观察到的成岩结构的多样性和丰富性在探测器的穿越中是独特的。本研究对MAHLI仪器观察到的所有纹理进行了编目,包括它们的丰度、形态和横切关系,以便提出一个共生序列,在这个序列中,需要多期成岩流体流动来形成共同发生的颜色变化、坑和结节;次生结节群;两代硫酸钙裂隙充填脉状降水。在整个地层剖面中,这些结构的丰度和多样性的空间非均质性与地层单元大致相关,表明颗粒大小和压实作用对流体通道的控制影响了它们的形成;这些模式在本图尔段尤其普遍,那里的原始地层完全被结核结构覆盖,而在地层剖面的底部,纹理多样性的增加可能受到格伦托里登地区下伏渗透性较差的含粘土岩石的影响。定量结核丰度与α粒子x射线光谱仪测量的块状岩石化学(特别是MgO和SO3富集)的细微变化之间的相关性表明,硫酸镁上剖面的增加与充填孔隙的成岩胶结物的沉淀有关。由于缺乏这些Mg硫酸盐广泛蒸发岩或近地表地壳形成的沉积学证据,我们提出了三种与地下水相关的预先存在的硫酸盐的再活化和孔隙空间深处的再沉淀的假设。
{"title":"Diagenesis of the Clay-Sulfate Stratigraphic Transition, Mount Sharp Group, Gale Crater, Mars","authors":"C. H. Seeger,&nbsp;J. P. Grotzinger","doi":"10.1029/2024JE008531","DOIUrl":"10.1029/2024JE008531","url":null,"abstract":"<p>The diversity and abundance of diagenetic textures observed in sedimentary rocks of the clay-sulfate transition recorded in the stratigraphic record of Gale crater are distinctive within the rover's traverse. This study catalogs all textures observed by the MAHLI instrument, including their abundances, morphologies, and cross-cutting relationships in order to suggest a paragenetic sequence in which multiple episodes of diagenetic fluid flow were required to form co-occurring color variations, pits, and nodules; secondary nodule populations; and two generations of Ca sulfate fracture-filling vein precipitation. Spatial heterogeneities in the abundance and diversity of these textures throughout the studied stratigraphic section loosely correlate with stratigraphic unit, suggesting that grain size and compaction controls on fluid pathways influenced their formation; these patterns are especially prevalent in the Pontours member, where primary stratigraphy is entirely overprinted by a nodular fabric, and the base of the stratigraphic section, where increased textural diversity may be influenced by the underlying less permeable clay-bearing rocks of the Glen Torridon region. Correlations between quantitative nodule abundance and subtle variations in measured bulk rock chemistry (especially MgO and SO<sub>3</sub> enrichment) by the Alpha Particle X-Ray Spectrometer instrument suggest that an increase in Mg sulfate upsection is linked to precipitation of pore-filling diagenetic cement. Due to a lack of sedimentological evidence for widespread evaporite or near-surface crust formation of these Mg sulfates, we propose three alternative hypotheses for subsurface groundwater-related remobilization of pre-existing sulfates and reprecipitation at depth in pore spaces.</p>","PeriodicalId":16101,"journal":{"name":"Journal of Geophysical Research: Planets","volume":"129 12","pages":""},"PeriodicalIF":3.9,"publicationDate":"2024-12-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC11622355/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142801126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electron-Induced Radiolysis of Water Ice and the Buildup of Oxygen 水冰的电子诱导辐射分解和氧的形成
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-03 DOI: 10.1029/2024JE008393
Chantal Tinner, André Galli, Fiona Bär, Antoine Pommerol, Martin Rubin, Audrey Vorburger, Peter Wurz
<p>Irradiation by energetic ions, electrons, and UV photons induces sputtering and chemical processes (radiolysis) in the surfaces of icy moons, comets, and icy grains. Laboratory experiments, both of ideal surfaces and of more complex and realistic analog samples, are crucial to understand the interaction of surfaces of icy moons and comets with their space environment. This study shows the first results of mass spectrometry measurements from porous water ice regolith samples irradiated with electrons as a representative analogy to water-ice rich surfaces in the solar system. Previous studies have shown that most electron-induced <span></span><math> <semantics> <mrow> <msub> <mi>H</mi> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{H}}_{2}$</annotation> </semantics></math>O radiolysis products leave the ice as <span></span><math> <semantics> <mrow> <msub> <mi>H</mi> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{H}}_{2}$</annotation> </semantics></math> and <span></span><math> <semantics> <mrow> <msub> <mi>O</mi> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{O}}_{2}$</annotation> </semantics></math> and that <span></span><math> <semantics> <mrow> <msub> <mi>O</mi> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{O}}_{2}$</annotation> </semantics></math> can be trapped under certain conditions in the irradiated ice. Our new laboratory experiments confirm these findings. Moreover, they quantify residence times and saturation levels of <span></span><math> <semantics> <mrow> <msub> <mi>O</mi> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{O}}_{2}$</annotation> </semantics></math> in originally pure water ice. <span></span><math> <semantics> <mrow> <msub> <mi>H</mi> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{H}}_{2}$</annotation> </semantics></math>O may also be released from the water ice by irradiation, but the quantification of the released <span></span><math> <semantics> <mrow> <msub> <mi>H</mi> <mn>2</mn> </msub> </mrow> <annotation>
高能离子、电子和紫外光子的照射在冰冷的卫星、彗星和冰粒表面引起溅射和化学过程(辐射分解)。实验室实验,无论是理想表面还是更复杂和现实的模拟样品,对于理解冰卫星和彗星表面与其空间环境的相互作用至关重要。这项研究显示了用电子照射多孔水冰风化层样品的质谱测量的第一个结果,作为太阳系中富水冰表面的代表性类比。先前的研究表明,大多数电子诱导的h2 { mathm {H}}_{2}$ O辐射分解产物以h2 ${ mathm {H}}_{2}$和o2 ${mathrm{O}}_{2}$和o2 ${mathrm{O}}_{2}$在一定条件下可以被捕获在辐照冰中。我们新的实验室实验证实了这些发现。此外,他们量化了o2 ${ mathm {O}}_{2}$在原始纯水冰中的停留时间和饱和度。辐照也可从水冰中释放出H 2 ${ mathm {H}}_{2}$ O,但释放的H 2 ${ mathm {H}}_{2}$ O的定量较为困难,且总量对电子通量和能量敏感。
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引用次数: 0
Ultraviolet NO and Visible O2 Nightglow in the Mars Southern Winter Polar Region: Statistical Study and Model Comparison 火星南极冬季极地地区的紫外线NO和可见O2夜光:统计研究和模式比较
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-12-02 DOI: 10.1029/2024JE008620
L. Soret, F. González-Galindo, J.-C. Gérard, I. R. Thomas, B. Ristic, Y. Willame, A. C. Vandaele, B. Hubert, F. Lefèvre, F. Daerden, M. R. Patel

The Mars NO and the O2 nightglow are produced by the recombination of atoms produced on the dayside by photodissociation and transported to the nightside. These emissions are tracers of the summer to winter pole dynamics in the upper Mars atmosphere. The UV-visible (UVIS) channel of the Nadir and Occultation for MArs Discovery (NOMAD) spectrometer onboard Trace Gas Orbiter (TGO) is the first instrument able to simultaneously monitor both nightglow emissions. Observations by NOMAD/UVIS during the first part of the Martian year show that both the NO and O2 nightglow emissions are enhanced near the southern winter pole. Their mean brightnesses are 15 and 108 kR, respectively. These nightglow emissions generally occur between 30 and 60 km, the NO emitting layer being consistently located ∼10 km higher than the O2 nightglow layer. Numerical simulations with the Mars Planetary Climate Model (MPCM, v6.1) properly reproduce the nightglow brightness but tend to overestimate the NO peak altitude by ∼10 km. These results suggest that the atomic oxygen density is correctly predicted by the model but that the nitrogen density altitude distribution might not be properly modeled.

火星的NO和O2夜光是由白天产生的原子通过光解作用重新组合而产生的,并被运送到夜晚。这些排放物是火星上层大气中夏季到冬季两极动态的示踪剂。搭载在痕量气体轨道飞行器(TGO)上的火星探测探测(NOMAD)光谱仪的紫外-可见(UVIS)通道是第一个能够同时监测两种夜光发射的仪器。NOMAD/UVIS在火星年上半年的观测表明,在南极冬极附近,NO和O2的夜光排放都增强了。它们的平均亮度分别为15 kR和108 kR。这些夜光发射通常发生在30至60公里之间,NO发射层始终位于比O2夜光层高约10公里的位置。用火星行星气候模式(MPCM, v6.1)进行的数值模拟正确地再现了夜光亮度,但往往高估了NO峰值高度约10公里。这些结果表明,该模型正确地预测了原子氧密度,但氮密度的高度分布可能没有正确地模拟。
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引用次数: 0
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Journal of Geophysical Research: Planets
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