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Spectral Analysis of the Morphology of Fresh Lunar Craters I: Rim Crest, Floor, and Rim Flank Outlines 新鲜月球陨石坑形态的光谱分析 I. 凸缘、底面和凸缘侧面轮廓环形山顶部、底部和环形山侧面轮廓
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-16 DOI: 10.1029/2024JE008357
Jun Du, David A. Minton, Austin M. Blevins, Caleb I. Fassett, Ya-Huei Huang

The morphology of fresh lunar craters contains information about the physical properties of both the impactors and the lunar surface, and is therefore crucial to our knowledge of the impact cratering process. Spectral analysis is a powerful tool to study crater morphology, as it can reveal the topographic variation on different scales. In this study, we calculate the power spectral densities of the radial distance and elevation of the rim crest, floor, and rim flank outlines of fresh lunar craters. The resulting power spectral density can be decomposed into an average component and a natural variability component. For the average component, we derive the classic morphometric parameter-crater diameter relations that are consistent with previous studies. For the natural variability component, we find that in general the spectral power increases with wavelength, which can be fitted by a piecewise function with four breakpoints. Among the four breakpoints, the power of the third breakpoint (i.e., the degree-2 power) is of particular interest, as it determines the ellipticity of the outline. The power of the third breakpoint is found to have a diameter dependence with a peak at 20 km, which indicates that transitional craters are more elliptical than simple and complex craters. The diameter dependence of the power spectral density enables us to generate the synthetic outlines of a crater of a particular size, which can be used to develop a preliminary 3-dimensional shape model for fresh lunar craters that is useful for improving Monte Carlo modeling of cratered surfaces on the Moon.

新鲜月球陨石坑的形态包含了有关撞击物和月球表面物理性质的信息,因此对我们了解撞击陨石坑过程至关重要。光谱分析是研究陨石坑形态的有力工具,因为它可以揭示不同尺度上的地形变化。在这项研究中,我们计算了新鲜月球陨石坑边缘峰顶、底部和边缘侧面轮廓的径向距离和高程的功率谱密度。得出的功率谱密度可分解为平均分量和自然变化分量。对于平均分量,我们得出了经典的形态参数与环形山直径的关系,这与之前的研究结果是一致的。对于自然变化分量,我们发现一般来说,频谱功率随波长的增加而增加,这可以用一个有四个断点的片断函数来拟合。在四个断点中,第三个断点的功率(即度数-2 功率)尤其值得关注,因为它决定了轮廓的椭圆度。第三个断点的功率与直径有关,峰值在 20 千米处,这表明过渡陨石坑比简单陨石坑和复杂陨石坑更椭圆。功率谱密度的直径依赖性使我们能够生成特定大小陨石坑的合成轮廓,这可用于开发新月球陨石坑的初步三维形状模型,有助于改进月球陨石坑表面的蒙特卡罗建模。
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引用次数: 0
Atomic-Level Structural Responses of Chang'e-5 Ilmenite to Space Weathering 嫦娥五号钛铁矿对空间风化的原子级结构响应
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-14 DOI: 10.1029/2024JE008447
Chaoqun Zhang, Xiaoguang Niu, Lixin Gu, Xu Tang, Yi Chen, Changrun Cai, Yanchao Dai, Gen Li, Hongping He, Yongxin Pan, Zhigang Zhang, Jinhua Li

Space weathering records provide insights to better understand the formation and evolution of the lunar regolith. Ilmenite has contrasting responses to different space weathering processes. However, the atomic-scale structural modification of ilmenite induced using different space weathering processes remains poorly understood. Here, we investigate the effects of spacing weathering on lunar ilmenite grains returned from Chang'e-5 (CE-5) mission using a combination of transmission electron microscopy and thermodynamic modeling approaches. Experimental results show that melt shock induces the formation of twining structures and vein-like Si-Ca-rich nanostructures in the outermost and sub-outermost layers of ilmenite, respectively. In contrast, solar wind causes the formation of multilayered nanostructures surrounding the ilmenite grains. These structures are characterized by an outermost amorphous Si-rich vapor deposited layer, a middle layer rich in titanium (Ti) oxides and zero-valent iron (Fe0) nanoparticles, and an innermost layer hosting crystallographic orientation defect. The Ti oxides were identified as poorly crystallized anatase. Thermodynamic calculations indicate that the disruptive sputtering of solar wind and the reduction of hydrogen under lunar surface pressure conditions can promote ilmenite transformation into Fe0 and Ti oxides; nevertheless, the pressure increase associated with melt shock can lead to a rise in the decomposition temperature of ilmenite. In other words, solar wind irradiation plays a more significant role in promoting nanoparticle (such as anatase and Fe0) formation as compared to melt shock. Thus, unlike the chemical alteration of ilmenite induced by the solar wind irradiation, melt shock mainly causes physical changes in ilmenite grains.

空间风化记录为更好地了解月球风化岩的形成和演变提供了启示。钛铁矿对不同空间风化过程的反应截然不同。然而,人们对不同空间风化过程引起的钛铁矿原子尺度结构变化仍然知之甚少。在此,我们采用透射电子显微镜和热力学建模相结合的方法,研究了嫦娥五号(CE-5)任务返回的月球钛铁矿晶粒的间距风化效应。实验结果表明,熔融冲击分别在钛铁矿的最外层和次最外层诱导形成了缠绕结构和富含Si-Ca的脉状纳米结构。相比之下,太阳风会在钛铁矿晶粒周围形成多层纳米结构。这些结构的特点是:最外层是富含硅的无定形气相沉积层,中间层富含钛(Ti)氧化物和零价铁(Fe0)纳米颗粒,最内层则存在晶体取向缺陷。钛氧化物被鉴定为结晶度较差的锐钛矿。热力学计算表明,太阳风的破坏性溅射和月球表面压力条件下的氢还原可促进钛铁矿转化为 Fe0 和 Ti 氧化物;然而,与熔融冲击相关的压力增加会导致钛铁矿的分解温度升高。换句话说,与熔融冲击相比,太阳风辐照在促进纳米粒子(如锐钛矿和 Fe0)形成方面发挥着更重要的作用。因此,与太阳风辐照引起的钛铁矿化学变化不同,熔融冲击主要引起钛铁矿晶粒的物理变化。
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引用次数: 0
Constraining the Duration and Ages of Stratigraphic Unconformities on Mars Using Exhumed Craters 利用出土陨石坑确定火星地层不整合的持续时间和年代
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-13 DOI: 10.1029/2023JE008073
A. M. Annex, K. W. Lewis

Crater counting is a widely applied methodology for dating large areas of planetary surfaces, but is difficult to apply the method to constrain the durations of stratigraphic unconformities. Unconformities with exhumed craters are thought to indicate long hiatuses that can only be indirectly dated through stratigraphic relationships with other surfaces with uniform exposure ages. On Mars, sedimentary deposits with prominent unconformities with exhumed craters are found in layered deposits in the Arabia Terra region as well as Gale crater within Mount Sharp. In this work, we present a Linear Crater Counting methodology and apply it to constrain these unconformities observed in Arabia Terra and in Mount Sharp. The method applies a linear sampling domain correction to conventional two-dimensional crater size frequency distributions and Bayesian Poisson process statistics in order to constrain the likely durations of these unconformities. We found that unconformities in Arabia Terra were on the order of 0.1–1 Gyr in length and that the unconformity preserved at Mount Sharp is at least 0.2 Gyr in length given estimates of the ages of the host craters. Hiatuses of these lengths constrain the age of the overlying deposits to be Late Hesperian or Amazonian in age. Two utility plots are also provided, along with the derivation, for researchers to apply this method to dating arbitrary geologic contacts on Mars and to adapt it to other bodies.

陨石坑计数是一种广泛应用于确定行星表面大面积年代的方法,但很难用这种方法来确定地层不整合的持续时间。人们认为,与被掘出的陨石坑不符的地层表明存在较长的间断期,只能通过与其他具有统一暴露年龄的地表的地层关系来间接确定其年代。在火星上,阿拉伯地球地区的层状沉积以及夏普山的盖尔陨石坑中都发现了与出露陨石坑有明显不整合的沉积物。在这项工作中,我们提出了一种线性陨石坑计数方法,并将其用于约束在阿拉伯地拉和夏普山观测到的这些不整合现象。该方法对传统的二维陨石坑大小频率分布和贝叶斯泊松过程统计进行了线性采样域校正,以确定这些非地貌的可能持续时间。我们发现,阿拉伯地拉的非整合长度大约为 0.1-1 Gyr,而根据对主陨石坑年龄的估计,夏普山保留的非整合长度至少为 0.2 Gyr。这些长度的吻合层将上覆沉积物的年龄限制在晚黑斯伯纪或亚马逊纪。此外,还提供了两个实用图,以及推导结果,供研究人员将此方法应用于火星上任意地质接触的年代测定,并将其应用于其他天体。
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引用次数: 0
Planetary Interior Configuration Control on Thermal Evolution and Geological History 行星内部构造对热演化和地质历史的控制
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-11 DOI: 10.1029/2024JE008361
L. H. Lark, C. Huber, E. M. Parmentier, J. W. Head

The terrestrial planetary bodies display a wide variety of surface expressions and histories of volcanic and tectonic, and magnetic activity, even those planets with apparently similar dominant modes of heat transport (e.g., conductive on Mercury, the Moon, and Mars). Each body also experienced differentiation in its earliest evolution, which may have led to density-stabilized layering in its mantle and a heterogenous distribution of heat-producing elements (HPE). We explore the hypothesis that mantle structure exerts an important control on the occurrence and timing of geological processes such as volcanism and tectonism. We numerically investigate the behavior of an idealized model of a planetary body where HPE are assumed to be sequestered in a stabilized layer at the top or bottom of the mantle. We find that the mantle structure alters the patterns of heat flow at the boundaries of major heat reservoirs: The mantle and core. This modulates the way in which heat production influences geological processes. In the model, the mantle structure is a dominant control on the relative timing of fundamental processes such as volcanism, magnetic field generation, and expansion/contraction, the record of which may be observable on planetary body surfaces. We suggest that Mercury exhibits characteristics of shallow sequestration of HPE and that Mars exhibits characteristics of deep sequestration.

地球上的行星体显示出多种多样的表面表现形式以及火山、构造和磁活动的历史,即使是那些具有明显相似的主要热传输模式(如水星、月球和火星上的传导模式)的行星也不例外。每个天体在其最早的演化过程中也都经历了分化,这可能导致其地幔的密度稳定分层以及产热元素(HPE)的异质分布。我们探讨了地幔结构对火山活动和构造运动等地质过程的发生和时间具有重要控制作用的假设。我们用数值方法研究了一个理想化的行星体模型的行为,在该模型中,假设产热元素被封存在地幔顶部或底部的稳定层中。我们发现地幔结构改变了主要热库边界的热流模式:地幔和地核。这就改变了热量产生对地质过程的影响方式。在这一模型中,地幔结构对火山活动、磁场生成和膨胀/收缩等基本过程的相对时间起着主要的控制作用,这些过程的记录可以在行星体表面观察到。我们认为,水星表现出 HPE 浅层封存的特征,而火星则表现出深层封存的特征。
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引用次数: 0
Analyzing the Mineralogy and Space Weathering Characteristics of the Finest Fraction in Apollo Core Sample 73002 分析阿波罗核心样品 73002 中最细小部分的矿物学和空间风化特征
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-08 DOI: 10.1029/2024JE008528
J. A. McFadden, M. S. Thompson, L. P. Keller, R. Christoffersen, R. V. Morris, C. Shearer, The ANGSA Science Team

Apollo 17 core sample 73001/2 was recently made available to researchers for analysis using state-of-the-art techniques in the framework of a modern understanding of lunar surface processes. In this work, we employ transmission electron microscopic analysis to observe the mineralogy, microstructural, and chemical characteristics of space weathering and solar energetic particle (SEP) track distribution in soil grains in the <20 μm size fraction in core sample 73002. The modal mineralogy and stratigraphic space weathered grain abundance suggests that a geologically recent mixing event affected the top 3 cm of 73002. Surface exposure age distributions derived from SEP tracks demonstrate that individual regolith grains rarely reside on the surface for longer than ∼4 million years. The abundance of surface exposed monomineralic fragments with respect to depth correlates well with bulk measurements of space weathered soils using other techniques, such as ferromagnetic resonance. Exposure age distributions suggest the presence of two unique in situ reworking zones spanning the top 8 cm of the core and median exposure ages decrease with increasing depth for both reworking zones, albeit at different rates. These rates were compared to reworking models and suggest a relationship between median exposure age and reworking rate with respect to depth. Applications of modern transmission electron microscopy to core sample 73001/2 have proven useful in understanding lunar regolith evolution both within the context of the Apollo 17 field site and more broadly via in situ reworking.

阿波罗 17 号核心样本 73001/2 最近提供给研究人员,供其在现代月球表面过程认识框架内使用最先进的技术进行分析。在这项工作中,我们采用透射电子显微镜分析方法,观察了 73002 号岩心样本中 20 μm 尺寸部分土壤颗粒的矿物学、微观结构和空间风化化学特征以及太阳能量粒子(SEP)轨迹分布。模态矿物学和地层空间风化颗粒丰度表明,最近的一次地质混合事件影响了 73002 号样本的顶部 3 厘米。从 SEP 轨道得出的地表暴露年龄分布表明,单个碎屑岩颗粒在地表停留的时间很少超过 400 万年。暴露在地表的单矿物碎片的丰度与深度的关系与利用铁磁共振等其他技术对空间风化土壤的体积测量结果十分吻合。暴露年龄分布表明,在岩心顶部 8 厘米处存在两个独特的原地再加工区,两个再加工区的暴露年龄中值随深度增加而减小,尽管减小的速度不同。这些速率与再加工模型进行了比较,结果表明中位暴露年龄与再加工速率之间存在深度关系。事实证明,将现代透射电子显微镜技术应用于 73001/2 号岩心样本,有助于了解阿波罗 17 号实地考察点以及更广泛的原地再加工过程中月球碎屑岩的演变情况。
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引用次数: 0
Diagenetic History and Biosignature Preservation Potential of Fine-Grained Rocks at Hogwallow Flats, Jezero Crater, Mars 火星杰泽罗陨坑霍格沃洛平原细粒岩石的成因历史和生物特征保存潜力
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-08 DOI: 10.1029/2024JE008520
A. P. Broz, B. Horgan, H. Kalucha, J. R. Johnson, C. Royer, E. Dehouck, L. Mandon, E. L. Cardarelli, B. Garczynski, J. H. Haber, K. C. Benison, E. Ives, K. M. Stack, N. Mangold, T. Bosak, J. I. Simon, P. Gasda, E. Clave, B. S. Kathir, M. Zawaski, R. Barnes, S. Siljeström, N. Randazzo, J. M. Madariaga, K. Farley, J. Maki, L. Kah, W. Rapin, L. L. Kivrak, A. J. Williams, E. Hausrath, J. I. Núñez, F. Gómez, A. Steele, T. Fouchet, J. F. Bell, R. C. Wiens

The Mars 2020 Perseverance rover discovered fine-grained clastic sedimentary rocks in the “Hogwallow Flats” member of the “Shenandoah” formation at Jezero crater, Mars. The Hogwallow Flats member shows evidence of multiple phases of diagenesis including Fe/Mg-sulfate-rich (20–30 wt. %) outcrop transitioning downward into red-purple-gray mottled outcrop, Fe/Mg clay minerals and oxides, putative concretions, occasional Ca sulfate-filled fractures, and variable redox state over small (cm) spatial scales. This work uses Mastcam-Z and SuperCam instrument data to characterize and interpret the sedimentary facies, mineralogy and diagenetic features of the Hogwallow Flats member. The lateral continuity of bedrock similar in tone and morphology to Hogwallow Flats that occurs over several km within the western Jezero sedimentary fan suggests widespread deposition in a lacustrine or alluvial floodplain setting. Following deposition, sediments interacted with multiple fluids of variable redox state and salinity under habitable conditions. Three drilled sample cores were collected from this interval of the Shenandoah formation as part of the Mars Sample Return campaign. These samples have very high potential to preserve organic compounds and biosignatures. Drill cores may partially include dark-toned mottled outcrop that lies directly below light-toned, sulfate-cemented outcrop. This facies may represent some of the least oxidized material observed at this interval of the Shenandoah formation. This work reconstructs the diagenetic history of the Hogwallow Flats member and discusses implications for biosignature preservation in rock samples for possible return to Earth.

火星2020 "坚毅 "号探测器在火星杰泽罗陨石坑的 "雪兰多 "地层的 "猪腰子平地 "部分发现了细粒碎屑沉积岩。Hogwallow Flats 成员显示了多个成岩阶段的证据,包括富含铁/镁-硫酸盐(20-30 wt.%)的露头向下过渡到红-紫-灰斑驳露头、铁/镁粘土矿物和氧化物、假定的凝块、偶尔的硫酸钙填充裂缝,以及小(厘米)空间尺度的可变氧化还原状态。这项研究利用 Mastcam-Z 和 SuperCam 仪器数据来描述和解释猪腰子平地岩层的沉积面貌、矿物学和成岩特征。在杰泽罗沉积扇西部数公里范围内,基岩在色调和形态上与霍格瓦洛平地相似,这种横向连续性表明,沉积物广泛沉积于湖泊或冲积洪积平原环境中。沉积后,沉积物在适宜居住的条件下与多种氧化还原状态和盐度不同的流体相互作用。在 "火星样本送回 "活动中,从谢南多地层的这一区间采集了三个钻孔样本岩心。这些样本极有可能保存有机化合物和生物特征。钻探岩心可能部分包括直接位于浅色硫酸盐胶结岩层之下的深色斑驳岩层。该岩层可能代表了在谢南多纳地层这一区间观察到的一些氧化程度最低的物质。这项研究重建了猪腰子平地岩层的成岩历史,并讨论了岩石样本中的生物特征保存对可能返回地球的影响。
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引用次数: 0
Shallow Moonquake Mechanisms Illuminated by Rheologic Characteristics of Basaltic Gouges 玄武岩裂隙流变特性揭示的浅层月震机制
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-08 DOI: 10.1029/2024JE008370
Fengshou Zhang, Wenzhi Zhao, Mengke An, Xianda Shen, Jizhou Tang, Luanxiao Zhao, Hai Liu, Derek Elsworth, Hehua Zhu, Manchao He

The projected evolutionary history of the Moon and observed occurrence of moonquakes suggest that brittle faulting is present in the shallow lunar crust. The main component of the lunar crust, plagioclase, shows velocity-strengthening behavior in the range of crustal temperatures. Chang'e 5 samples of lunar regolith show a mineral composition almost identical to basaltic bedrock. We measured the friction-stability characteristics of dry synthetic gouges representative of basaltic faults assumed to be present in the lunar crust. Frictional strengths are ∼0.7 and exhibit an overall velocity-strengthening response but transition to velocity-weakening at intermediate temperatures (∼200–300°C) and stresses (∼25–100 MPa). Bounding temperature profiles representative of the lunar crust suggest that moonquakes are feasible in the lunar crust. The rheological heterogeneity of mineral fragments in basalt is a potential cause of unstable sliding on faults with the related steady-state stress drop close to the minimum of the estimated dynamic stress drop. This suggests that some events with small stress drops are associated with the instability of mature basalt faults. However, observations of shallow moonquakes with high stress drop but merely moderate magnitude suggest that high degrees of healing on immature faults, small seismic nucleation lengths, or the failure of intact crust are present. We emphasize that moonquakes may arise from stress transfer and accumulation due to processes such as cooling contraction.

预计的月球演化历史和观测到的月震现象表明,浅月壳中存在脆性断层。月壳的主要成分斜长石在地壳温度范围内显示出速度强化行为。嫦娥五号的月球碎屑岩样本显示出与玄武岩基岩几乎相同的矿物成分。我们测量了干燥合成沟槽的摩擦稳定性特征,这些沟槽代表了假定存在于月壳中的玄武岩断层。摩擦强度为0.7,总体上表现出速度增强响应,但在中等温度(200-300°C)和应力(25-100兆帕)条件下过渡到速度减弱响应。具有代表性的月壳边界温度曲线表明,月震在月壳中是可行的。玄武岩中矿物碎片的流变异质性是断层上不稳定滑动的潜在原因,相关的稳态应力降接近估计动态应力降的最小值。这表明,一些应力降较小的事件与成熟玄武岩断层的不稳定性有关。然而,对应力降大但震级仅为中等的浅月震的观测表明,不成熟断层的高度愈合、地震成核长度小或完整地壳的破坏是存在的。我们强调,月震可能源于冷却收缩等过程造成的应力传递和积累。
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引用次数: 0
Greenhouse Warming Potential of a Suite of Gas Species on Early Mars Evaluated Using a Radiative-Convective Climate Model 利用辐射对流气候模型评估早期火星上一系列气体的温室增温潜力
IF 3.9 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-11-07 DOI: 10.1029/2024JE008443
Jason Jorge, Robin Wordsworth, Danica Adams
<p>Abundant geomorphological and geochemical evidence of liquid water on the surface of early Mars during the late Noachian and early Hesperian periods needs to be reconciled with a fainter young Sun. While a dense <span></span><math> <semantics> <mrow> <msub> <mrow> <mi>C</mi> <mi>O</mi> </mrow> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{C}mathrm{O}}_{2}$</annotation> </semantics></math> atmosphere and related warming mechanisms are potential solutions to the early Mars climate problem, further investigation is warranted. Here, we complete a comprehensive survey of the warming potential of all known greenhouse gases and perform detailed calculations for 15 different minor gas species under early Martian conditions. We find that of these 15 species, <span></span><math> <semantics> <mrow> <msub> <mi>H</mi> <mn>2</mn> </msub> <msub> <mi>O</mi> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{H}}_{2}{mathrm{O}}_{2}$</annotation> </semantics></math>, <span></span><math> <semantics> <mrow> <msub> <mrow> <mi>H</mi> <mi>N</mi> <mi>O</mi> </mrow> <mn>3</mn> </msub> </mrow> <annotation> ${mathrm{H}mathrm{N}mathrm{O}}_{3}$</annotation> </semantics></math>, <span></span><math> <semantics> <mrow> <msub> <mrow> <mi>N</mi> <mi>H</mi> </mrow> <mn>3</mn> </msub> </mrow> <annotation> ${mathrm{N}mathrm{H}}_{3}$</annotation> </semantics></math>, <span></span><math> <semantics> <mrow> <msub> <mrow> <mi>S</mi> <mi>O</mi> </mrow> <mn>2</mn> </msub> </mrow> <annotation> ${mathrm{S}mathrm{O}}_{2}$</annotation> </semantics></math>, and <span></span><math> <semantics> <mrow> <msub> <mrow> <msub> <mi>C</mi> <mn>2</mn> </msub> <mi>H</mi> </mrow> <
早期火星表面在诺奇纪晚期和赫斯珀纪早期存在液态水的大量地貌和地球化学证据需要与较暗的年轻太阳相协调。虽然致密的 C O 2 ${mathrm{C}mathrm{O}}_{2}$ 大气层和相关的变暖机制是解决早期火星气候问题的潜在方案,但仍需要进一步的研究。在这里,我们完成了对所有已知温室气体变暖潜力的全面调查,并对早期火星条件下 15 种不同的次要气体进行了详细计算。We find that of these 15 species, H 2 O 2 ${mathrm{H}}_{2}{mathrm{O}}_{2}$ , H N O 3 ${mathrm{H}mathrm{N}mathrm{O}}_{3}$ , N H 3 ${mathrm{N}mathrm{H}}_{3}$ , S O 2 ${mathrm{S}mathrm{O}}_{2}$ , and C 2 H 4 ${{mathrm{C}}_{mathrm{2}}mathrm{H}}_{4}$ cause significant greenhouse warming at concentrations of ∼ ${sim} $ 0.1 ppmv or greater.然而,最高效的温室气体物种也往往更容易凝结、溶解和被光解破坏。为了给未来的大气演变和光化学研究提供参考,我们在网上免费提供了升温潜能值数据库。
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引用次数: 0
Thermoelastic Properties and Thermal Evolution of the Martian Core From Ab Initio Calculated Magnetic Fe-S Liquid 从 Ab Initio 计算的磁性 Fe-S 液体看火星核心的热弹性特性和热演化
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-20 DOI: 10.1029/2023JE007874
Wei-Jie Li, Zi Li, Zhe Ma, Jie Zhou, Cong Wang, Ping Zhang

Accurate thermoelastic properties and thermal conductivity are crucial for understanding the thermal evolution of the Martian core. A fitting method based on ab initio calculated pressure-volume-temperature data was proposed for the formulation of the equation of state with high accuracy, by which the pressure and temperature dependent thermoelastic properties can be directly calculated by definitions. Ab initio results showed that Fe0.75S0.25 liquid under Martian core conditions was thoroughly in a magnetic state without existing spin crossover. The Fe0.75S0.25 liquid in magnetic calculations had a low thermal conductivity (21–23 W/m/K) when compared with non-magnetic calculations at the same state. Based on Insight's estimated Martian core properties (Stähler et al., 2021, https://doi.org/10.1126/science.abi7730) and ab initio calculated properties of the Fe0.75S0.25 liquid, the scenario for the thermal evolution of the Martian core is the iron-snow model crystallization regime. The parameter uncertainty effect on the cessation time of the dynamo and zone of iron snow was systematically analyzed.

准确的热弹性特性和热导率对于了解火星内核的热演化至关重要。该研究提出了一种基于ab initio计算的压力-体积-温度数据的拟合方法,用于制定高精度的状态方程,从而可以通过定义直接计算与压力和温度相关的热弹性特性。Ab initio 结果表明,火星地核条件下的 Fe0.75S0.25 液体完全处于磁性状态,不存在自旋交叉。与相同状态下的非磁性计算相比,磁性计算中的 Fe0.75S0.25 液体具有较低的热导率(21-23 W/m/K)。根据 Insight 对火星内核特性的估计(Stähler 等人,2021 年,https://doi.org/10.1126/science.abi7730)和对 Fe0.75S0.25 液体特性的非初始计算,火星内核的热演化方案是铁雪模型结晶机制。系统分析了参数不确定性对动力机和铁雪区停止时间的影响。
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引用次数: 0
Retrieval of Ar, N2, O, and CO in the Martian Thermosphere Using Dayglow Limb Observations by EMM EMUS 利用 EMM EMUS 的日辉边缘观测数据检索火星热大气层中的 Ar、N2、O 和 CO
IF 4.8 1区 地球科学 Q1 GEOCHEMISTRY & GEOPHYSICS Pub Date : 2024-04-20 DOI: 10.1029/2023JE008181
J. S. Evans, J. Deighan, S. Jain, V. Veibell, J. Correira, H. Al Matroushi, H. Al Mazmi, M. Chaffin, S. Curry, N. El-Kork, S. England, F. Eparvier, M. Fillingim, G. Holsclaw, M. Khalil, R. Lillis, F. Lootah, S. Mahmoud, T. Plummer, E. Soto, J. Tennyson, E. Thiemann, S. N. Yurchenko

The Emirates Ultraviolet Spectrometer (EMUS) onboard the Emirates Mars Mission (EMM) Hope probe images Mars at wavelengths extending from approximately 100 to 170 nm. EMUS observations began in February 2021 and cover over a full Mars year. We report the first limb scan observations at Mars of ultraviolet emissions Ar I 106.6 nm, N I 120 nm, and carbon monoxide (CO) Fourth Positive Group (A − X) band system excited by electron impact on CO. We use EMUS limb scan observations to retrieve number density profiles of argon, molecular nitrogen, atomic oxygen, and CO in the upper atmosphere of Mars from 130 to 160 km. CO is a sensitive tracer of the thermal profile and winds in Mars' middle atmosphere and the chemistry that balances CO2 in the atmosphere of Mars. EMUS insertion orbit special observations demonstrate that far ultraviolet limb measurements of the Martian thermosphere can be spectroscopically analyzed with a robust retrieval algorithm to further quantify variations of CO composition in the Martian upper atmosphere.

阿联酋希望号火星探测器(EMM)上的阿联酋紫外线分光计(EMUS)以大约100到170纳米的波长对火星进行成像。EMUS的观测始于2021年2月,覆盖了整个火星年。我们报告了首次在火星边缘扫描观测到的紫外线发射Ar I 106.6 nm、N I 120 nm以及电子撞击CO激发的一氧化碳(CO)第四正组(A - X)波段系统。我们利用 EMUS 边缘扫描观测数据来获取火星 130 至 160 公里高层大气中的氩、分子氮、原子氧和一氧化碳的数量密度曲线。一氧化碳是火星中层大气热剖面和风以及平衡火星大气中二氧化碳的化学反应的灵敏示踪剂。EMUS插入轨道特别观测表明,火星热层的远紫外边缘测量值可以通过一种强大的检索算法进行光谱分析,以进一步量化火星高层大气中二氧化碳成分的变化。
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引用次数: 0
期刊
Journal of Geophysical Research: Planets
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