Yulia N. Toikka , Alexander R. Badikov , Nikita A. Bogachev , Ilya E. Kolesnikov , Mikhail Yu. Skripkin , Sergey N. Orlov , Andrey S. Mereshchenko
{"title":"Luminescent properties and thermal stability of (Lu0.98Eu0.02)2bdc3·10H2O metal–organic frameworks","authors":"Yulia N. Toikka , Alexander R. Badikov , Nikita A. Bogachev , Ilya E. Kolesnikov , Mikhail Yu. Skripkin , Sergey N. Orlov , Andrey S. Mereshchenko","doi":"10.1016/j.mencom.2024.09.003","DOIUrl":null,"url":null,"abstract":"<div><div>Two new heterometallic lutetium(III)–europium(III) terephthalate metal–organic frameworks were synthesized. The compounds demonstrated bright red emission of Eu<sup>3+</sup> ions upon UV excitation into the <sup>1</sup>ππ* excited state of terephthalate anion. Photoluminescence properties of the compounds were shown to be determined by the local environment of europium ions.</div></div>","PeriodicalId":18542,"journal":{"name":"Mendeleev Communications","volume":"34 5","pages":"Pages 634-636"},"PeriodicalIF":1.8000,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Mendeleev Communications","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0959943624002426","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
Two new heterometallic lutetium(III)–europium(III) terephthalate metal–organic frameworks were synthesized. The compounds demonstrated bright red emission of Eu3+ ions upon UV excitation into the 1ππ* excited state of terephthalate anion. Photoluminescence properties of the compounds were shown to be determined by the local environment of europium ions.
期刊介绍：
Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications.
Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
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