Unusual condensation of acetone giving η3-allyl ligand in the [Pd(η3-C6H9O)(μ-Cl)]2 complex

IF 1.8 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Mendeleev Communications Pub Date : 2024-09-01 DOI:10.1016/j.mencom.2024.09.040
Inessa A. Efimenko , Alexey S. Kubasov , Nina A. Ivanova , Olga S. Erofeeva , Ludmila I. Demina
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Abstract

A one-step reaction was discovered giving the h3-allyl complex [Pd(h3-C6H9O)(μ-Cl)]2. The formation of the substituted h3-allyl ligand in the complex occurs as a result of the condensation of acetone at room temperature in a solution containing [Pd(PhCN)2Cl2] and organic acids. The structure of the resulting Pdii complex was determined by single crystal X-ray diffraction analysis.

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丙酮与η3-烯丙基配体在[Pd(η3-C6H9O)(μ-Cl)]2 复合物中的非同寻常的缩合作用
发现了一种一步反应生成 h3-烯丙基配合物 [Pd(h3-C6H9O)(μ-Cl)]2。在室温下,丙酮在含有[Pd(PhCN)2Cl2]和有机酸的溶液中缩合,形成了该配合物中的取代 h3-烯丙基配体。通过单晶 X 射线衍射分析确定了 Pdii 复合物的结构。
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来源期刊
Mendeleev Communications
Mendeleev Communications 化学-化学综合
CiteScore
3.00
自引率
21.10%
发文量
226
审稿时长
4-8 weeks
期刊介绍: Mendeleev Communications is the journal of the Russian Academy of Sciences, launched jointly by the Academy of Sciences of the USSR and the Royal Society of Chemistry (United Kingdom) in 1991. Starting from 1st January 2007, Elsevier is the new publishing partner of Mendeleev Communications. Mendeleev Communications publishes short communications in chemistry. The journal primarily features papers from the Russian Federation and the other states of the former USSR. However, it also includes papers by authors from other parts of the world. Mendeleev Communications is not a translated journal, but instead is published directly in English. The International Editorial Board is composed of eminent scientists who provide advice on refereeing policy.
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