Microstructure and corrosion behavior of Ti-Mo-Zr alloy fabricated by selective laser melting in simulated oral environment

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY International Journal of Electrochemical Science Pub Date : 2024-10-09 DOI:10.1016/j.ijoes.2024.100829
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Abstract

The microstructure of Ti-Mo-Zr alloy fabricated by selective laser melting (SLM) was studied and its corrosion behavior was investigated by a series of electrochemical methods. The results showed that α+β phases of different proportions were formed after heat treatment, the grain size of the alloy treated at 950℃ slightly increased, because of the existence of the original α grain, the orientation of the α grain was not significantly changed by heat treatment below the β transition temperature. However, heat treatment above β transition temperature significantly changed the orientation of α grains. Electrochemical measurements were conducted in artificial saliva solution and artificial saliva solution containing hydrogen peroxide. The results showed that the corrosion resistance of the original Ti-Mo-Zr alloy was better than that of the Ti-Mo-Zr alloy treated at 950°C and worse than that of the Ti-Mo-Zr alloy treated at 1050°C. The differences in corrosion behavior can be attributed to grain size and orientation and phase distribution.
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在模拟口腔环境中通过选择性激光熔化制造的 Ti-Mo-Zr 合金的微观结构和腐蚀行为
研究了选择性激光熔化(SLM)技术制备的钛-钼-锆合金的微观结构,并采用一系列电化学方法对其腐蚀行为进行了研究。结果表明,热处理后形成了不同比例的 α+β 相,在 950℃下处理的合金晶粒尺寸略有增大,这是因为原始 α 晶粒的存在,α 晶粒的取向在 β 转变温度以下的热处理中没有明显变化。然而,高于 β 转变温度的热处理会明显改变 α 晶粒的取向。在人工唾液和含有过氧化氢的人工唾液中进行了电化学测量。结果表明,原始 Ti-Mo-Zr 合金的耐腐蚀性优于在 950°C 下处理的 Ti-Mo-Zr 合金,而劣于在 1050°C 下处理的 Ti-Mo-Zr 合金。腐蚀行为的差异可归因于晶粒大小、取向和相分布。
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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