{"title":"The cyclotriborate trianion","authors":"Manjur O. Akram, Caleb D. Martin","doi":"10.1016/j.chempr.2024.09.002","DOIUrl":null,"url":null,"abstract":"In this issue of <em>Chem</em>, Kinjo and Feng report the synthesis of a cyclotriborate trianion (B<sub>3</sub>R<sub>6</sub><sup>3−</sup>), a highly charged boron ring system with discrete two-center two-electron bonds. With three contiguous borates, the B<sub>3</sub><sup>3−</sup> core of the feature compound defies Coulomb’s law and represents the first homocyclic boron analog of the ubiquitous cyclopropane. The remarkable stability enabled full characterization and opens new vistas in the field of multiply charged boron ions.","PeriodicalId":268,"journal":{"name":"Chem","volume":"94 1","pages":""},"PeriodicalIF":19.1000,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chem","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.chempr.2024.09.002","RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
Abstract
In this issue of Chem, Kinjo and Feng report the synthesis of a cyclotriborate trianion (B3R63−), a highly charged boron ring system with discrete two-center two-electron bonds. With three contiguous borates, the B33− core of the feature compound defies Coulomb’s law and represents the first homocyclic boron analog of the ubiquitous cyclopropane. The remarkable stability enabled full characterization and opens new vistas in the field of multiply charged boron ions.
期刊介绍：
Chem, affiliated with Cell as its sister journal, serves as a platform for groundbreaking research and illustrates how fundamental inquiries in chemistry and its related fields can contribute to addressing future global challenges. It was established in 2016, and is currently edited by Robert Eagling.
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