Nawel GOUAL, Stéphane Maisonneuve, Fabrizio Medici, pascal retailleau, Jean-Francois GALLARD, juan Xie, Vincent Gandon, Angela Marinetti, Arnaud Voituriez
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引用次数: 0
Abstract
This work discloses a strategy for the implementation of ON-ON organometallic catalytic processes using photoresponsive phosphine ligands. The approach leverages on the regiodivergent reactivity of mono- and bimetallic gold complexes that result from π- vs σ,π-activations of alkynyl-substituted urea substrates, for the selective formation of either dihydroquinazolinone or indole-carboxamide products, via intramolecular hydroamidation.
期刊介绍：
Advanced Synthesis & Catalysis (ASC) is the leading primary journal in organic, organometallic, and applied chemistry.
The high impact of ASC can be attributed to the unique focus of the journal, which publishes exciting new results from academic and industrial labs on efficient, practical, and environmentally friendly organic synthesis. While homogeneous, heterogeneous, organic, and enzyme catalysis are key technologies to achieve green synthesis, significant contributions to the same goal by synthesis design, reaction techniques, flow chemistry, and continuous processing, multiphase catalysis, green solvents, catalyst immobilization, and recycling, separation science, and process development are also featured in ASC. The Aims and Scope can be found in the Notice to Authors or on the first page of the table of contents in every issue.
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