Structural, optical, photocatalytic and thermal behaviour of (Nb, Ta) co-doped WO3 nanoparticles and its application in photocatalytic degradation of MG and RhB dyes

Abstract

In this communication, eco-friendly, cost effective and facile hydrothermal route was adopted to synthesize pure WO₃, Nb-doped WO₃ and (Nb, Ta) co-doped WO₃ nanoparticles. Phase, lattice constants, crystallite size and crystallinity have been evaluated through X-ray diffraction. The insertion of Nb and Ta ions into WO₃ nanoparticles was confirmed by XPS, FTIR and EDS studies. HRTEM and SAED micrographs exhibited highly nanocrystalline nature of samples. UV–visible studies was carried out to analyse nature of band gap, band gap energy, extinction coefficient, refractive index, Urbach energy and optical conductivity of prepared samples. Optical band gap was narrowed from 2.94 to 2.49 eV and Urbach energy was extended from 0.08 to 0.35 eV through co-doping of (Nb, Ta) ions into WO₃ NPs. Reduction in PL intensity revealed that electron-hole pair recombination rate was decreased with co-doping of (Nb, Ta) ions. The photo-degradation efficiency of (Nb 5 %, Ta 5 %) co-doped WO₃ nanophotocatalysts was 93.12 % against MG and 90.11 % against RhB dyes. The rate constant was found to be increased from 0.0107 to 0.0203 min⁻¹ for MG and 0.0086 to 0.0174 min⁻¹ for RhB. Thermal results exhibited the weight loss in three phase degradation processes, and thermal stability. The results showed that (Nb 5 %, Ta 5 %) co-doped WO₃ NPs is a potential candidate for practical applications in environmental remediation (organic dyes degradation).