Exploring the potential of fast pyrolysis of invasive biomass species for the production of chemicals

IF 5.8 2区 化学 Q1 CHEMISTRY, ANALYTICAL Journal of Analytical and Applied Pyrolysis Pub Date : 2024-10-01 DOI:10.1016/j.jaap.2024.106817
Enara Fernandez , Maider Amutio , Maite Artetxe , Gartzen Lopez , Laura Santamaria , Julian E. Lopez , Martin Olazar , Juan F. Saldarriaga
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Abstract

The pyrolysis of five invasive plants crowded in Colombia (Liquidambar styraciflua, Sambucus nigra, Cecropia telenitida, Ruta greveolens, and Clusia orthoneura) has been studied for the first time in order to assess their potential for the production of liquid and solid fuels and chemical products. The volatiles produced from the fast pyrolysis of these biomass species at three different temperatures (500, 600 and 700 ºC) were analyzed by Py-GC/MS. In spite of the different nature of the feedstock, the bio-oil produced from the pyrolysis of all the biomasses at the three temperatures studied is mainly composed of phenols (with a relative content in the 19–26.5 % range), acids (14.6–19.5 %), ketones (13.4–19.2 %) and levoglucosan (6.7–15.4 %). Temperature has a moderate effect, leading to a decrease in the relative content of all component families, except aldehydes and hydrocarbons, when it is increased. Biochars produced at 500 ºC show high calorific values, as well as low H/C and O/C ratios, which prove their high stability in the soil. These results are clear evidence that the valorization of these invasive plants by pyrolysis may be an effective strategy for the mitigation of their associated impacts.
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探索入侵生物质物种快速热解生产化学品的潜力
为了评估哥伦比亚五种入侵植物(Liquidambar styraciflua、Sambucus nigra、Cecropia telenitida、Ruta greveolens 和 Clusia orthoneura)生产液体和固体燃料及化学产品的潜力,我们首次对这些植物进行了热解研究。Py-GC/MS 分析了这些生物质在三种不同温度(500、600 和 700 ºC)下快速热解产生的挥发物。尽管原料性质不同,但所有生物质在三种温度下热解产生的生物油主要由酚类(相对含量在 19-26.5 % 之间)、酸类(14.6-19.5 %)、酮类(13.4-19.2 %)和左旋葡聚糖(6.7-15.4 %)组成。温度的影响不大,当温度升高时,除醛和碳氢化合物外,所有组分族的相对含量都会降低。在 500 ºC 温度下生产的生物炭显示出较高的热值以及较低的 H/C 和 O/C 比值,这证明它们在土壤中具有较高的稳定性。这些结果清楚地证明,通过热解使这些入侵植物增值可能是减轻其相关影响的有效策略。
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来源期刊
CiteScore
9.10
自引率
11.70%
发文量
340
审稿时长
44 days
期刊介绍: The Journal of Analytical and Applied Pyrolysis (JAAP) is devoted to the publication of papers dealing with innovative applications of pyrolysis processes, the characterization of products related to pyrolysis reactions, and investigations of reaction mechanism. To be considered by JAAP, a manuscript should present significant progress in these topics. The novelty must be satisfactorily argued in the cover letter. A manuscript with a cover letter to the editor not addressing the novelty is likely to be rejected without review.
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