{"title":"Luminescent o-carboranyl-containing molecules: A promising platform for stimuli-responsive smart materials","authors":"Zhiyu Ran, Mengmeng Zhao, Junqing Shi, Lei Ji","doi":"10.1016/j.dyepig.2024.112484","DOIUrl":null,"url":null,"abstract":"<div><div><em>o</em>-Carborane, spherical-shaped 12-vertex boron cluster molecule bearing two adjacent carbons, plays an increasingly important role in multifunctional optoelectronic materials due to its appealing luminescent properties. The sterically and conjugately special natures enable the building block of <em>o</em>-carborane display unique emissive features of aggregation-induced emission (AIE), multi- and excimer-emission. Molecules with these features are highly sensitive to subtle environmental factors and broadly applicable in smart and sensory materials. In this paper, holistic and in-depth perspectives on those phenomenon features, the underlying mechanistic analyses, as well as associated applications are addressed on recently developed <em>o</em>-carboranyl molecules, aiming to bridge the phenomenon-mechanism-application gap and offering an up-to-date progress report.</div></div>","PeriodicalId":302,"journal":{"name":"Dyes and Pigments","volume":"232 ","pages":"Article 112484"},"PeriodicalIF":4.1000,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Dyes and Pigments","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0143720824005503","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, APPLIED","Score":null,"Total":0}
引用次数: 0
Abstract
o-Carborane, spherical-shaped 12-vertex boron cluster molecule bearing two adjacent carbons, plays an increasingly important role in multifunctional optoelectronic materials due to its appealing luminescent properties. The sterically and conjugately special natures enable the building block of o-carborane display unique emissive features of aggregation-induced emission (AIE), multi- and excimer-emission. Molecules with these features are highly sensitive to subtle environmental factors and broadly applicable in smart and sensory materials. In this paper, holistic and in-depth perspectives on those phenomenon features, the underlying mechanistic analyses, as well as associated applications are addressed on recently developed o-carboranyl molecules, aiming to bridge the phenomenon-mechanism-application gap and offering an up-to-date progress report.
期刊介绍：
Dyes and Pigments covers the scientific and technical aspects of the chemistry and physics of dyes, pigments and their intermediates. Emphasis is placed on the properties of the colouring matters themselves rather than on their applications or the system in which they may be applied.
Thus the journal accepts research and review papers on the synthesis of dyes, pigments and intermediates, their physical or chemical properties, e.g. spectroscopic, surface, solution or solid state characteristics, the physical aspects of their preparation, e.g. precipitation, nucleation and growth, crystal formation, liquid crystalline characteristics, their photochemical, ecological or biological properties and the relationship between colour and chemical constitution. However, papers are considered which deal with the more fundamental aspects of colourant application and of the interactions of colourants with substrates or media.
The journal will interest a wide variety of workers in a range of disciplines whose work involves dyes, pigments and their intermediates, and provides a platform for investigators with common interests but diverse fields of activity such as cosmetics, reprographics, dye and pigment synthesis, medical research, polymers, etc.
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