La2O2MQ2 phases: Stability and synthetic challenges

IF 3.4 3区 化学 Q2 CHEMISTRY, INORGANIC & NUCLEAR Solid State Sciences Pub Date : 2024-10-09 DOI:10.1016/j.solidstatesciences.2024.107719
Glen R. Hebberd, Budhika G. Mendis, Leon Bowen, Stewart J. Clark, Emma E. McCabe
{"title":"La2O2MQ2 phases: Stability and synthetic challenges","authors":"Glen R. Hebberd,&nbsp;Budhika G. Mendis,&nbsp;Leon Bowen,&nbsp;Stewart J. Clark,&nbsp;Emma E. McCabe","doi":"10.1016/j.solidstatesciences.2024.107719","DOIUrl":null,"url":null,"abstract":"<div><div>Oxychalcogenides containing transition metal or p block cations have potential for thermoelectric, photocatalytic and magnetic applications but the synthetic pathways to these quaternary phases are not fully understood. This presents a challenge to the design and preparation of new functional materials. Our combined experimental and computational study of La<sub>2</sub>O<sub>2</sub><em>MQ</em><sub>2</sub> (<em>M</em> = +2 cation; <em>Q</em> = sulfide, selenide anion) systems explores the thermodynamic constraints on synthesis and highlights the subtle balance in stabilities of phases formed via competing reaction pathways.</div></div>","PeriodicalId":432,"journal":{"name":"Solid State Sciences","volume":"157 ","pages":"Article 107719"},"PeriodicalIF":3.4000,"publicationDate":"2024-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Solid State Sciences","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S129325582400284X","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"CHEMISTRY, INORGANIC & NUCLEAR","Score":null,"Total":0}
引用次数: 0

Abstract

Oxychalcogenides containing transition metal or p block cations have potential for thermoelectric, photocatalytic and magnetic applications but the synthetic pathways to these quaternary phases are not fully understood. This presents a challenge to the design and preparation of new functional materials. Our combined experimental and computational study of La2O2MQ2 (M = +2 cation; Q = sulfide, selenide anion) systems explores the thermodynamic constraints on synthesis and highlights the subtle balance in stabilities of phases formed via competing reaction pathways.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
La2O2MQ2 相:稳定性与合成挑战
含有过渡金属或 p 块阳离子的氧化钙苷具有热电、光催化和磁性应用的潜力,但这些四元相的合成途径还不完全清楚。这对设计和制备新型功能材料提出了挑战。我们对 La2O2MQ2(M = +2 阳离子;Q = 硫化物、硒化阴离子)系统进行了实验和计算相结合的研究,探索了合成的热力学限制,并强调了通过相互竞争的反应途径形成的相在稳定性方面的微妙平衡。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Solid State Sciences
Solid State Sciences 化学-无机化学与核化学
CiteScore
6.60
自引率
2.90%
发文量
214
审稿时长
27 days
期刊介绍: Solid State Sciences is the journal for researchers from the broad solid state chemistry and physics community. It publishes key articles on all aspects of solid state synthesis, structure-property relationships, theory and functionalities, in relation with experiments. Key topics for stand-alone papers and special issues: -Novel ways of synthesis, inorganic functional materials, including porous and glassy materials, hybrid organic-inorganic compounds and nanomaterials -Physical properties, emphasizing but not limited to the electrical, magnetical and optical features -Materials related to information technology and energy and environmental sciences. The journal publishes feature articles from experts in the field upon invitation. Solid State Sciences - your gateway to energy-related materials.
期刊最新文献
Dual-functional high-crystalline 3D core-shell hexagonal tubular sulfur-doped carbon nitride for enhanced photocatalytic H2 production and simultaneously pollutants degradation Magnetocrystalline anisotropy and giant spontaneous magnetostriction in iron selenide Fe3Se4 studied on single crystals In situ synthesis of metal-organic frameworks on sulfonated cellulose nanofibrils The dielectric characteristics of spray deposited α-Si3N4:ZnO thin films: The nitride effect on frequency-dependent capacitance and conductance profiles Study of substrate dependent microstructural properties of sputtered Mo/CZTS heterojunctions using X ray diffraction
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1