Photoluminescence optical and thermal quenching in heavily doped Gd3(Ga,Al)5O12:Ce, Mg single crystals: Dependence on the Ga3+, Ce3+, and Mg2+ concentration

Abstract

Heavily doped single crystals of Gd₃Ga_xAl_5-xO₁₂:Ce, Mg (x = 2.46–2.95) with different concentrations of Ce (0.016–0.188 at.%) and Mg (0–0.083 at.%) are investigated by the X-ray diffraction, photoluminescence, and thermoluminescence methods. Dependences of the luminescence characteristics, as well as crystal lattice parameters and distances between the Ce³⁺ and Mg²⁺ ions, on the Ga, Ce, and Mg concentration are studied. Mechanisms of the processes, resulting in the photoluminescence optical and thermal quenching and acceleration of decay kinetics, and the influence of the crystal composition on these processes are discussed. The role of close {Ce³⁺ - Mg²⁺_Ga} pairs in these processes is considered. At T > 400 K, the luminescence thermal quenching is caused by the crossover process, while in the 200–350 K temperature range, by the electron transfer from the 5d₁ excited state of Ce³⁺ to nearby defect levels (electron traps) located between the 5d₁ level and the conduction band. The latter process results also in the appearance of thermally stimulated luminescence, and its efficiency depends on the Ga³⁺ content and concentration of intrinsic defects. The optimum concentrations of Ga³⁺ and Mg²⁺ ions in the investigated crystals are determined.