Counterintuitive Trend of Intrusion Pressure with Temperature in the Hydrophobic Cu2(tebpz) MOF (Small 42/2024)

IF 13 2区 材料科学 Q1 CHEMISTRY, MULTIDISCIPLINARY Small Pub Date : 2024-10-18 DOI:10.1002/smll.202470310
Sebastiano Merchiori, Andrea Le Donne, Ribhu Bhatia, Marta Alvelli, Jiang-Jing Yu, Xu-Dong Wu, Mian Li, Dan Li, Lukasz Scheller, Alexander R. Lowe, Monika Geppert-Rybczynska, Benjamin A. Trump, Andrey A. Yakovenko, Mirosław Chorążewski, Paweł Zajdel, Yaroslav Grosu, Simone Meloni
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Abstract

Intrusion Pressure

The high vapor confined within the hydrophobic Cu2(tebpz) metal–organic framework led to a counterintuitive trend of the intrusion pressure with temperature, compared to naïve interpretations of the classical Young-Laplace law. This is due to a peculiar combination of the geometrical and chemical characteristics of the porous medium, favoring the formation of a dense vapor inside the material. More in article number 2402173, Andrea Le Donne, Pawel Zajdel, Yaroslav Grosu, and co-workers.

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疏水性 Cu2(tebpz)MOF 中侵入压力随温度变化的反直觉趋势(小号 42/2024)
入侵压力
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来源期刊
Small
Small 工程技术-材料科学:综合
CiteScore
17.70
自引率
3.80%
发文量
1830
审稿时长
2.1 months
期刊介绍: Small serves as an exceptional platform for both experimental and theoretical studies in fundamental and applied interdisciplinary research at the nano- and microscale. The journal offers a compelling mix of peer-reviewed Research Articles, Reviews, Perspectives, and Comments. With a remarkable 2022 Journal Impact Factor of 13.3 (Journal Citation Reports from Clarivate Analytics, 2023), Small remains among the top multidisciplinary journals, covering a wide range of topics at the interface of materials science, chemistry, physics, engineering, medicine, and biology. Small's readership includes biochemists, biologists, biomedical scientists, chemists, engineers, information technologists, materials scientists, physicists, and theoreticians alike.
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