Synthesis of functionalized pyrans catalyzed by amine functionalized plolyboricacid

IF 2.8 3区 化学 Q2 CHEMISTRY, MULTIDISCIPLINARY Research on Chemical Intermediates Pub Date : 2024-09-30 DOI:10.1007/s11164-024-05403-5
Babu Pejjai, K. Ashok, Reddi Mohan Naidu Kalla, Kholood A. Dahlous, Jaewoong Lee
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Abstract

This article describes the amalgamated of polyboric acid (PBA) and Aminoethyl-3-Aminopropyltriethoxysilane (AEAPTES) by straightforward extrusion process to produce composite (PBA/AEAPTES). It showed basic nature due to amine functionalities on surface of PBA. The composite is applied for the fabrication of pyran derivatives. These reactions are noteworthy for their large product yields, environmental friendliness, quick reaction times, wide range of substrates and no need of hazardous solvents. Moreover, there is no discernible decrease in activity after four reuses of the catalyst and catalyst separated by simple filtration method without any extraction. The resultant composite is characterized by FT-IR, XRD and SEM analysis. In addition, the synthesized compounds characterized by FT-IR, 1H, & 13C NMR analysis.

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胺官能化聚硼酸催化的官能化吡喃的合成
本文介绍了通过直接挤压工艺将聚硼酸(PBA)和氨基乙基-3-氨丙基三乙氧基硅烷(AEAPTES)混合制成复合材料(PBA/AEAPTES)的方法。由于 PBA 表面具有胺官能团,因此它具有碱性。该复合材料可用于制造吡喃衍生物。值得注意的是,这些反应具有产率高、环保、反应时间快、基质范围广以及无需使用有害溶剂等优点。此外,催化剂在重复使用四次后活性没有明显降低,而且催化剂可通过简单的过滤方法分离,无需提取。通过傅立叶变换红外光谱(FT-IR)、X 射线衍射(XRD)和扫描电子显微镜(SEM)分析,对合成的复合材料进行了表征。此外,还对合成的化合物进行了 FT-IR、1H、& 13C NMR 分析。
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来源期刊
CiteScore
5.70
自引率
18.20%
发文量
229
审稿时长
2.6 months
期刊介绍: Research on Chemical Intermediates publishes current research articles and concise dynamic reviews on the properties, structures and reactivities of intermediate species in all the various domains of chemistry. The journal also contains articles in related disciplines such as spectroscopy, molecular biology and biochemistry, atmospheric and environmental sciences, catalysis, photochemistry and photophysics. In addition, special issues dedicated to specific topics in the field are regularly published.
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