Deconvoluting the cation effect on carbon monoxide electroreduction

IF 42.8 1区化学 Q1 CHEMISTRY, PHYSICAL Nature Catalysis Pub Date : 2024-10-23 DOI:10.1038/s41929-024-01228-y

引用次数: 0

Abstract

The performance of the electrochemical CO2 and CO reduction reactions is affected by the presence of alkali metal cations in the electrolyte, but the mechanism remains under debate. Now, experimental determination of the energetics and kinetic barriers of key elementary steps in the electrochemical CO reduction reaction on Cu enables deconvolution of the cation effect.

Abstract Image

查看原文

微信好友朋友圈 QQ好友复制链接

本刊更多论文

解除阳离子对一氧化碳电还原的影响

电化学二氧化碳和一氧化碳还原反应的性能受到电解液中碱金属阳离子存在的影响，但其机理仍存在争议。现在，通过实验确定了铜上电化学 CO 还原反应中关键基本步骤的能量和动力学障碍，从而得以解构阳离子效应。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

求助全文

约1分钟内获得全文去求助

来源期刊

Nature Catalysis Chemical Engineering-Bioengineering

CiteScore

52.10

自引率

1.10%

发文量

140

期刊介绍： Nature Catalysis serves as a platform for researchers across chemistry and related fields, focusing on homogeneous catalysis, heterogeneous catalysis, and biocatalysts, encompassing both fundamental and applied studies. With a particular emphasis on advancing sustainable industries and processes, the journal provides comprehensive coverage of catalysis research, appealing to scientists, engineers, and researchers in academia and industry. Maintaining the high standards of the Nature brand, Nature Catalysis boasts a dedicated team of professional editors, rigorous peer-review processes, and swift publication times, ensuring editorial independence and quality. The journal publishes work spanning heterogeneous catalysis, homogeneous catalysis, and biocatalysis, covering areas such as catalytic synthesis, mechanisms, characterization, computational studies, nanoparticle catalysis, electrocatalysis, photocatalysis, environmental catalysis, asymmetric catalysis, and various forms of organocatalysis.

期刊最新文献

Face to phase Surface (dis)order sleuthing Coacervation-enhanced peptide catalysis An enantioselective HAT for diols Effective anions