Enhancement in clinker hydration degrees and later stage-ettringite stability of calcium sulfoaluminate cements by the incorporation of dolomite

Abstract

The hydration degrees of clinkers and ettringite stability in calcium sulfoaluminate (C $\bar{S}$ A) cements in the presence of externally supplied dolomite were investigated in this study. The mineralogical and microstructural characteristics of C $\bar{S}$ A cements containing different dosages of dolomite were characterized using X-ray diffractometry, Rietveld refinement-based quantification analysis, thermogravimetry analysis, mercury intrusion porosimetry, scanning electron microscopy observation, and energy dispersive spectroscopy point analysis. Furthermore, the binder systems were simulated using thermodynamic modeling to observe the phase changes of hydration products and the underlying hydration kinetics. The incorporation of dolomite accelerated clinker consumption and enhanced the stability of ettringite throughout the testing period, due possibly to the nucleation seeding effect and provision of carbonate ions by dolomite. The modeling outcomes showed the stability of ettringite at later stage by the incorporation of dolomite in the simulated timeframe, yet the active dissolution of dolomite assumed in the modeling procedure overestimated the Mg-bearing hydrates in the samples.