Quantitative Dynamic Evolution of Unoccupied States in Hydrogen Diffused InGaZnSnO TFT under Positive Bias Temperature Stress

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-09-27 DOI:10.1021/acsaelm.4c0143010.1021/acsaelm.4c01430
Hyunmin Hong, Min Jung Kim, Dong-Joon Yi, Dong Yeob Shin, Yeon-Keon Moon, Kyoung-Seok Son, Jun Hyung Lim, KwangSik Jeong* and Kwun-Bum Chung*, 
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Abstract

Positive bias temperature stress (PBTS)-induced defects in self-aligned top-gate coplanar amorphous indium–gallium–zinc–tin oxide (a–IGZTO) thin-film transistors (TFTs) were quantitatively extracted as a function of hydrogen concentration. As the hydrogen concentration increased, the device properties and stability improved. As the stress time increased, the two decay constants that were extracted from the recovery of PBTS increased. Under PBTS, electrons were trapped in multiple defects simultaneously. Quantitative dynamic evolution of defect measurements showed that as the stress time increased, the activation energy and density of defects changed. As electrons moved to the dielectric, the density of shallow-level defects in the channel decreased, while the activation energy and density of deep-level defects increased. With a higher hydrogen concentration in the channel, the changes in defects were smaller. These findings indicate that hydrogen improves stability by passivating electron trap sites.

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正偏压温度应力下氢扩散 InGaZnSnO TFT 中未占态的定量动态演化
在自对齐顶栅共面非晶铟镓锌锡氧化物(a-IGZTO)薄膜晶体管(TFT)中定量提取了正偏压温度应力(PBTS)诱导的缺陷与氢浓度的函数关系。随着氢浓度的增加,器件的性能和稳定性得到改善。随着应力时间的增加,从 PBTS 恢复中提取的两个衰变常数也随之增加。在 PBTS 作用下,电子同时被困在多个缺陷中。缺陷测量的定量动态演变表明,随着应力时间的增加,缺陷的活化能和密度发生了变化。随着电子向电介质移动,沟道中浅层缺陷的密度降低,而深层缺陷的活化能和密度增加。通道中氢浓度越高,缺陷的变化越小。这些发现表明,氢能通过钝化电子陷阱点来提高稳定性。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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