Synergistic Effects of Deposition Temperatures for Active and Gate Insulator of Top-Gate Thin-Film Transistors Using InGaZnO Channels Prepared by Thermal Atomic-Layer Deposition

IF 5.4 3区 材料科学 Q2 CHEMISTRY, PHYSICAL ACS Applied Energy Materials Pub Date : 2024-09-30 DOI:10.1021/acsaelm.4c0138010.1021/acsaelm.4c01380
Ye-Jin Seo, Jae-Wook Lee, Young-Ha Kwon, Nak-Jin Seong, Kyu-Jeong Choi and Sung-Min Yoon*, 
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Abstract

The synergistic impact of deposition temperature conditions for the InGaZnO (IGZO) and gate insulator (GI) layers during the thermal atomic-layer deposition process on the device performance and operational reliability was examined for the top-gate thin-film transistors (TFTs). The Ga increased with an increase in the channel deposition temperature and did not change significantly following the GI deposition process. Prior to the postannealing process, the transfer characteristics of the devices were predominantly influenced by the GI deposition temperature. Following the postannealing process, however, the thermal stability was affected by both the deposition temperatures of the channel and GI layers. An increase in the GI deposition temperature from 200 to 300 °C resulted in an improvement in the IGZO channel quality, accompanied by a reduction in the hydrogen concentration of the GI. These results indicated that the device, wherein GI was prepared at 300 °C, was appropriate from both perspectives of performance and subsequent postannealing. Nevertheless, only Dev-HD, in which the channel and GI layers were prepared at 270 and 300 °C, respectively, demonstrated favorable thermal stability after a postannealing at 300 °C. Two potential effects may be the formation of a complete network and the content of Ga, which contribute to stable bonding in IGZO channel. It can thus be concluded that the IGZO network structure and cationic composition can be adjusted to control the defect states in the channel, leading to an enhancement in both the device performance and thermal stability of the TG IGZO TFTs.

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使用热原子层沉积制备的 InGaZnO 沟道的顶栅薄膜晶体管的活性和栅极绝缘体沉积温度的协同效应
在顶栅薄膜晶体管(TFT)的热原子层沉积过程中,研究了 InGaZnO(IGZO)层和栅极绝缘体(GI)层的沉积温度条件对器件性能和运行可靠性的协同影响。镓随沟道沉积温度的升高而增加,但在 GI 沉积过程之后并没有发生显著变化。在后退火工艺之前,器件的传输特性主要受 GI 沉积温度的影响。但在后退火工艺之后,热稳定性同时受到沟道层和 GI 层沉积温度的影响。将 GI 沉积温度从 200 ℃ 提高到 300 ℃ 可改善 IGZO 沟道质量,同时降低 GI 的氢浓度。这些结果表明,从性能和后续退火的角度来看,在 300 ℃ 下制备 GI 的器件是合适的。然而,只有 Dev-HD 器件的沟道层和 GI 层分别在 270 ℃ 和 300 ℃ 下制备,在 300 ℃ 下进行后退火后显示出良好的热稳定性。两个潜在的影响可能是完整网络的形成和镓的含量,它们有助于 IGZO 沟道中的稳定键合。因此可以得出结论,IGZO 网络结构和阳离子成分可以通过调整来控制沟道中的缺陷态,从而提高 TG IGZO TFT 的器件性能和热稳定性。
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来源期刊
ACS Applied Energy Materials
ACS Applied Energy Materials Materials Science-Materials Chemistry
CiteScore
10.30
自引率
6.20%
发文量
1368
期刊介绍: ACS Applied Energy Materials is an interdisciplinary journal publishing original research covering all aspects of materials, engineering, chemistry, physics and biology relevant to energy conversion and storage. The journal is devoted to reports of new and original experimental and theoretical research of an applied nature that integrate knowledge in the areas of materials, engineering, physics, bioscience, and chemistry into important energy applications.
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