In situ spectroelectrochemical and nanomechanical studies in the atomic force microscopy mode of the oxidation—reduction processes of poly-N,N′-ethylenebis(3-methoxysalicylideneimine)

IF 1.7 4区 化学 Q3 CHEMISTRY, MULTIDISCIPLINARY Russian Chemical Bulletin Pub Date : 2024-10-26 DOI:10.1007/s11172-024-4373-9
A. M. Timonov, Yu. S. Danilova, E. A. Dmitrieva, E. A. Smirnova, I. A. Chepurnaya, A. V. Ankudinov
{"title":"In situ spectroelectrochemical and nanomechanical studies in the atomic force microscopy mode of the oxidation—reduction processes of poly-N,N′-ethylenebis(3-methoxysalicylideneimine)","authors":"A. M. Timonov,&nbsp;Yu. S. Danilova,&nbsp;E. A. Dmitrieva,&nbsp;E. A. Smirnova,&nbsp;I. A. Chepurnaya,&nbsp;A. V. Ankudinov","doi":"10.1007/s11172-024-4373-9","DOIUrl":null,"url":null,"abstract":"<div><p>Redox processes in the polymer film of poly-<i>N</i>,<i>N′</i>-ethylenebis(3-methoxysalicylideneimine were studied for the first time by <i>in situ</i> methods including electron spin resonance spectroscopy, ultraviolet—visible—near-infrared spectroscopy, and Fourier transform infrared spectroscopy. The integration of the obtained data with the results of electrochemical nanomechanical atomic force microscopy measurements allowed us to determine causes of a low electrochemical oxidative polymerization efficiency of this compound and a rapid loss of its electrochemical activity in the oxidation—reduction processes.</p></div>","PeriodicalId":756,"journal":{"name":"Russian Chemical Bulletin","volume":null,"pages":null},"PeriodicalIF":1.7000,"publicationDate":"2024-10-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Russian Chemical Bulletin","FirstCategoryId":"92","ListUrlMain":"https://link.springer.com/article/10.1007/s11172-024-4373-9","RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0

Abstract

Redox processes in the polymer film of poly-N,N′-ethylenebis(3-methoxysalicylideneimine were studied for the first time by in situ methods including electron spin resonance spectroscopy, ultraviolet—visible—near-infrared spectroscopy, and Fourier transform infrared spectroscopy. The integration of the obtained data with the results of electrochemical nanomechanical atomic force microscopy measurements allowed us to determine causes of a low electrochemical oxidative polymerization efficiency of this compound and a rapid loss of its electrochemical activity in the oxidation—reduction processes.

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
在原子力显微镜模式下对聚-N,N′-乙烯双(3-甲氧基水杨酰亚胺)的氧化还原过程进行原位光谱电化学和纳米力学研究
通过电子自旋共振光谱、紫外-可见-近红外光谱和傅立叶变换红外光谱等原位方法,首次研究了聚-N,N′-乙烯双(3-甲氧基水杨酰亚胺)聚合物薄膜中的氧化还原过程。将获得的数据与电化学纳米机械原子力显微镜测量结果相结合,我们确定了该化合物电化学氧化聚合效率低以及在氧化还原过程中电化学活性迅速丧失的原因。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Russian Chemical Bulletin
Russian Chemical Bulletin 化学-化学综合
CiteScore
2.70
自引率
47.10%
发文量
257
审稿时长
3-8 weeks
期刊介绍: Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections: General and Inorganic Chemistry; Physical Chemistry; Organic Chemistry; Organometallic Chemistry; Chemistry of Natural Compounds and Bioorganic Chemistry.
期刊最新文献
Interaction of 2-unsubstituted imidazole N-oxides with electron-deficient olefins: a quantum chemical analysis Determination of intracrystalline diffusion coefficient of organic solvents in metal organic framework adsorbents by zero-length column method Current trends in organic chemistry: contribution of the N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences Triphenylphosphine in the identification of oxidation products of organic compounds with molecular oxygen and peroxides In situ spectroelectrochemical and nanomechanical studies in the atomic force microscopy mode of the oxidation—reduction processes of poly-N,N′-ethylenebis(3-methoxysalicylideneimine)
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1