In situ spectroelectrochemical and nanomechanical studies in the atomic force microscopy mode of the oxidation—reduction processes of poly-N,N′-ethylenebis(3-methoxysalicylideneimine)
A. M. Timonov, Yu. S. Danilova, E. A. Dmitrieva, E. A. Smirnova, I. A. Chepurnaya, A. V. Ankudinov
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引用次数: 0
Abstract
Redox processes in the polymer film of poly-N,N′-ethylenebis(3-methoxysalicylideneimine were studied for the first time by in situ methods including electron spin resonance spectroscopy, ultraviolet—visible—near-infrared spectroscopy, and Fourier transform infrared spectroscopy. The integration of the obtained data with the results of electrochemical nanomechanical atomic force microscopy measurements allowed us to determine causes of a low electrochemical oxidative polymerization efficiency of this compound and a rapid loss of its electrochemical activity in the oxidation—reduction processes.
期刊介绍:
Publishing nearly 500 original articles a year, by leading Scientists from Russia and throughout the world, Russian Chemical Bulletin is a prominent international journal. The coverage of the journal spans practically all areas of fundamental chemical research and is presented in five sections:
General and Inorganic Chemistry;
Physical Chemistry;
Organic Chemistry;
Organometallic Chemistry;
Chemistry of Natural Compounds and Bioorganic Chemistry.