Physicochemical and antibacterial properties of ceramic membranes based on silicon carbide

IF 2.2 4区 化学 Q2 Engineering Chemical Papers Pub Date : 2024-09-23 DOI:10.1007/s11696-024-03695-w
Yliia Molchan, Victoria Vorobyova, Georgii Vasyliev, Ihor Pylypenko, Oleksandr Shtyka, Tomasz Maniecki, Tetiana Dontsova
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Abstract

Ceramic membranes based on SiC have a number of advantages, namely high surface hydrophilicity, good water permeability and negative surface charge, which leads to better performance during their operation, but they require high sintering temperatures due to covalent bonds. The use of sintering agents can significantly reduce the final sintering temperature. The aim of this work was to synthesise ceramic membranes based on silicon carbide and to study the effect of liquid glass on their mechanical, electrical and antibacterial properties. The physicochemical properties of SiC ceramic membranes were investigated by diffraction analysis and scanning electron microscopy. It was found that, regardless of the type of carbonate, only two phases are identified: the main phase of the initial mixture, silicon carbide and the phase added to the mixture, corundum. The obtained SiC ceramic membranes are macroporous, as indicated by the transport properties (9.03–18.66 cm3/(min-cm2)) and the results of electron microscopy (13–20 μm). SiC ceramic membranes obtained are characterised by high strength (16.3–46.8 MPa). Studies of antibacterial properties have shown that SiC-based ceramic membranes do not exhibit antibacterial properties, but modification of ceramic membranes with titanium oxide inhibits the growth of gram-negative bacteria. The results of this study are useful for enriching the knowledge about the production of silicon carbide membranes and are aimed at further research and development of selective membranes (micro- and ultrafiltration) based on them.

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基于碳化硅的陶瓷膜的物理化学和抗菌特性
基于碳化硅的陶瓷膜具有许多优点,即表面亲水性高、透水性好和表面带负电荷,这使其在运行过程中具有更好的性能,但由于共价键的存在,它们需要较高的烧结温度。使用烧结剂可以大大降低最终烧结温度。这项工作的目的是合成基于碳化硅的陶瓷膜,并研究液态玻璃对其机械、电气和抗菌性能的影响。通过衍射分析和扫描电子显微镜研究了碳化硅陶瓷膜的物理化学特性。研究发现,无论碳酸盐的类型如何,都只能确定两种相:初始混合物的主相碳化硅和添加到混合物中的相刚玉。从传输特性(9.03-18.66 cm3/(min-cm2))和电子显微镜结果(13-20 μm)来看,获得的碳化硅陶瓷膜是大孔的。获得的碳化硅陶瓷膜具有高强度(16.3-46.8 兆帕)的特点。抗菌性能研究表明,SiC 基陶瓷膜不具有抗菌性能,但用氧化钛对陶瓷膜进行改性可抑制革兰氏阴性菌的生长。这项研究的结果有助于丰富有关碳化硅膜生产的知识,并旨在进一步研究和开发基于碳化硅膜的选择性膜(微滤和超滤)。
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来源期刊
Chemical Papers
Chemical Papers Chemical Engineering-General Chemical Engineering
CiteScore
3.30
自引率
4.50%
发文量
590
期刊介绍: Chemical Papers is a peer-reviewed, international journal devoted to basic and applied chemical research. It has a broad scope covering the chemical sciences, but favors interdisciplinary research and studies that bring chemistry together with other disciplines.
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