Adsorption-Based Thermal Energy Storage Using Zeolites for Mobile Heat Transfer

Energy Storage Pub Date : 2024-10-22 DOI:10.1002/est2.70041
Kapil Narwal, Saeed Farsad, Roger Kempers, Paul G. O'Brien
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Abstract

The utilization of the water–zeolite pair as an adsorbate–adsorbent system has garnered significant attention in the realm of thermochemical energy storage, offering great potential for various applications. Despite promising results in laboratory settings, widespread implementation of this technology has yet to be realized. Recent advancements in mobile thermal energy storage (m-TES) employing thermochemical materials have opened new avenues for enhancing the practicality and cost-effectiveness of solar thermal energy harnessing and waste heat recovery. This experimental study investigates the feasibility of storing thermal energy in zeolites, charged externally to the heat recovery reactor, and discusses the potential applications of externally charged zeolites for m-TES over short distances, shedding light on their practicality and significance in advancing the field of mobile thermal energy storage. Our findings reveal that zeolites charged at 200°C and subsequently stored outside the discharging unit exhibit an impressive energy storage density (ESD) exceeding 110 kWhth/m3 under conditions of 0.45 m/s air velocity and 60% relative humidity during zeolite discharging. These ESD values are comparable to previously reported figures in the literature. Moreover, ESD values of 30.6 kWhth/m3 were achieved by charging zeolite beads contained within packed transportable tubes constructed from stainless-steel mesh.

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利用沸石进行移动传热的吸附式热能存储
利用水-沸石对作为吸附剂-吸附剂系统在热化学储能领域备受关注,为各种应用提供了巨大潜力。尽管在实验室环境中取得了可喜的成果,但这一技术尚未得到广泛应用。采用热化学材料的移动热能储存(m-TES)技术的最新进展为提高太阳能热能利用和余热回收的实用性和成本效益开辟了新途径。本实验研究调查了在热回收反应器外部充电的沸石中储存热能的可行性,并讨论了外部充电沸石在短距离移动热能储存(m-TES)中的潜在应用,阐明了其在推动移动热能储存领域发展方面的实用性和意义。我们的研究结果表明,在沸石放电过程中,在 0.45 米/秒的气流速度和 60% 的相对湿度条件下,沸石在 200°C 的温度下充电,随后储存在放电装置外,其能量储存密度(ESD)超过 110 kWhth/m3,令人印象深刻。这些 ESD 值与之前文献报道的数字相当。此外,通过对装入由不锈钢网制成的可运输包装管中的沸石珠进行充电,ESD 值达到了 30.6 kWhth/m3。
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