Characterization of a highly integrated, natural convection-driven, condensing methanol reactor

Abstract

A highly integrated, natural convection-driven, condensing methanol reactor with the catalyst bed, heat integration section and liquid product separation in a single pressure vessel without moving parts is successfully tested. Space-time yields of up to $600{\mathrm{kg}}_{\mathrm{MeOH}}{m}_{\mathrm{cat.}}^{-3}{h}^{-1}$ are demonstrated, comparable to other CO₂-to-methanol processes. The internal recycle by natural convection is successfully achieved as well as significant heat integration. A further reduction of heat losses to the environment is needed for autothermal operation. The dynamic characteristics of the process, with fast start-up times, a high turn-down ratio add to the potential to deal with intermittent feed supply. Overall the LOGIC 2.0 reactor concept is a promising process configuration for green methanol production.