{"title":"Effect of nano-aluminum hydroxide on the liquid phase properties and fire-fighting foam performance of the mixed surfactants solution","authors":"Qingguo Wang, Weixiang Wang, Xing Zhang, Xu Geng, Yuanyuan Zhang","doi":"10.1016/j.firesaf.2024.104277","DOIUrl":null,"url":null,"abstract":"<div><div>Short-chain fluorocarbon surfactants show synergistic effects with hydrocarbon surfactants in foaming and foam stability. Nano-aluminum hydroxide (nano-ATH) was added as an additive to the short-chain fluorocarbon surfactant mixture solution, which was found to increase the surface tension and viscosity of the surfactant mixture solution, and decrease the foaming properties of the solution, as measured by Wilhelmy method, Waring Blender method and viscometer. By measuring zeta potential experiments, surfactant molecules were found to be adsorbed on nano-ATH through charge gravity, which increased the desorption energy of nano-ATH. Measuring the visco-elastic modulus of the solution by rheometer, it was found that nano-ATH increased the visco-elastic modulus of the surfactant mixture solution, which improved the foam's resistance to the external disturbances. Observed by the image analysis system on the foam, the uniform distribution of nano-ATH in the liquid film reduced the coarsening and coalescence speed of foam. Through the self-developed oil resistance test, nano-ATH enhanced the oil resistance stability and inhibition of fuel vapor diffusion of the foam by about 12 %; through self-developed foam fire extinguishing and anti-burning tests, nano-ATH shortened the fire extinguishing time of the two-phase foam by 25 %, and showed better fire extinguishing and anti-burning performance than the foam.</div></div>","PeriodicalId":50445,"journal":{"name":"Fire Safety Journal","volume":null,"pages":null},"PeriodicalIF":3.4000,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Fire Safety Journal","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0379711224001905","RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"ENGINEERING, CIVIL","Score":null,"Total":0}
引用次数: 0
Abstract
Short-chain fluorocarbon surfactants show synergistic effects with hydrocarbon surfactants in foaming and foam stability. Nano-aluminum hydroxide (nano-ATH) was added as an additive to the short-chain fluorocarbon surfactant mixture solution, which was found to increase the surface tension and viscosity of the surfactant mixture solution, and decrease the foaming properties of the solution, as measured by Wilhelmy method, Waring Blender method and viscometer. By measuring zeta potential experiments, surfactant molecules were found to be adsorbed on nano-ATH through charge gravity, which increased the desorption energy of nano-ATH. Measuring the visco-elastic modulus of the solution by rheometer, it was found that nano-ATH increased the visco-elastic modulus of the surfactant mixture solution, which improved the foam's resistance to the external disturbances. Observed by the image analysis system on the foam, the uniform distribution of nano-ATH in the liquid film reduced the coarsening and coalescence speed of foam. Through the self-developed oil resistance test, nano-ATH enhanced the oil resistance stability and inhibition of fuel vapor diffusion of the foam by about 12 %; through self-developed foam fire extinguishing and anti-burning tests, nano-ATH shortened the fire extinguishing time of the two-phase foam by 25 %, and showed better fire extinguishing and anti-burning performance than the foam.
期刊介绍:
Fire Safety Journal is the leading publication dealing with all aspects of fire safety engineering. Its scope is purposefully wide, as it is deemed important to encourage papers from all sources within this multidisciplinary subject, thus providing a forum for its further development as a distinct engineering discipline. This is an essential step towards gaining a status equal to that enjoyed by the other engineering disciplines.