Electrochemical boost via thermally reduced graphene oxide for tailoring composite paste electrodes

Abstract

Carbon-based composite materials are employed in diverse electrochemical applications, such as in catalysis, (bio)molecular sensing, and energy storage. In practice, electrode material needs to be highly conductive to allow high-speed electron transference to electrolyte species and possess high-surface area to obtain greater measured signals and power capabilities, as well as long useful life and stability. In this sense, graphene derivatives emerge as interesting candidates, even more so if they constitute part of practical, economical and versatile paste electrodes.

This work presents a detailed analysis of the electrochemical performance of paste electrodes fabricated with multilayer partially reduced graphene oxide (rGO). The rGO was strategically produced via thermal treatment as a key factor that minimizes both mass loss and energy consumption. The results obtained through diffraction, microscopy and spectroscopy techniques show an effective partial reduction in the range of 100 to 400 °C. Furthermore, the enhanced electrochemical performance of rGO was determined by exploring the specific capacitance from cyclic voltammetry (CV) and galvanostatic charge–discharge measurements (GCD) as well as charge transfer resistance via electrochemical impedance spectroscopy (EIS). Our results evidence how an integral performance with suitable chemical, structural and morphological properties achieved for GO heat-treated at 200 °C leads to an improved electronic conductivity when a small part is combined with graphite in paste electrodes. This latter combination provides higher versatility compared to other alternatives since it arises as an economical and effective carbonaceous matrix for (bio)electrochemical sensors, hybrid supercapacitors or other desired nanotechnological applications.