Covalent organic framework (COF) materials since their inception in 2005 have seen extensive applications in various fields including environmental remediation, photo-catalysts, electrocatalysis and in integrated devices to improve thermal and mechanical stability besides their application in energy storage systems such as batteries and supercapacitors. In this work, we report easily synthesizable, low-cost, chemically stable amine-based COF/metal oxide composites to function as high-performance supercapacitor (SC) electrodes. A one-step hydrothermal method has been used for the facile synthesis of Hexamine-phenylenediamine (HPd) COF and three COF/metal oxide composites- HPd/MoO2, HPd/NiO, and HPd/ZnO, respectively. Initial characterization techniques employed included powder X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and Field-emission scanning electron microscopy (FESEM), which show successful synthesis of the COF/metal oxide composites. The electrochemical investigation found the specific capacitances to be 181.1, 177.4, and 394.3 F/g for HPd/MoO2, HPd/NiO, and HPd/ZnO, respectively, at the current density of 0.5 A/g. The specific energy was found to be highest in the case of HPd/ZnO at 39.43 Wh/kg at 0.5 A/g. The work presents effective prospects for designing novel COF composites as electrode materials for SC applications.