In situ synthesis and deposition of palladium nanoparticles on gas diffusion layers via gamma radiolysis for cathode electrodes in proton exchange membrane fuel cells

IF 2.8 3区 化学 Q3 CHEMISTRY, PHYSICAL Chemical Physics Letters Pub Date : 2024-10-20 DOI:10.1016/j.cplett.2024.141699
Kok-Seng Leong , Thye-Foo Choo , Nur Ubaidah Saidin , Nurazila Mat Zali , Norhazirah Azhar , Mohd Shahbudin Masdar
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Abstract

This study investigates gamma radiolysis technique for synthesising and depositing palladium (Pd) nanoparticles on gas diffusion layers (GDLs). The Pd-coated GDLs were then used to fabricate MEAs, which were evaluated for their single-cell performance. The fabricated PEMFCs with Pd-loaded GDLs successfully generated potential and produced electricity, with the PEMFC with a Pd-loaded GDL prepared using a 0.05 M Pd precursor solution and 50 KGy dose achieved performances comparable to the PEMFC with commercial gas diffusion electrodes (GDEs). This study represents the first demonstration of a functional PEMFC using a novel gamma radiolysis-synthesised Pd catalyst GDL as the cathode electrode.

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通过伽马辐射在气体扩散层上原位合成和沉积钯纳米粒子,用于质子交换膜燃料电池的阴极电极
本研究采用伽马辐射分解技术合成钯(Pd)纳米粒子并将其沉积在气体扩散层(GDL)上。然后用涂有 Pd 的 GDL 制作 MEA,并对其单细胞性能进行了评估。使用 0.05 M Pd 前驱体溶液和 50 KGy 剂量制备的 Pd 负载 GDL PEMFC 的性能与使用商用气体扩散电极 (GDE) 的 PEMFC 相当。这项研究首次展示了使用新型伽马射线分解合成的钯催化剂 GDL 作为阴极电极的功能性 PEMFC。
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来源期刊
Chemical Physics Letters
Chemical Physics Letters 化学-物理:原子、分子和化学物理
CiteScore
5.70
自引率
3.60%
发文量
798
审稿时长
33 days
期刊介绍: Chemical Physics Letters has an open access mirror journal, Chemical Physics Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Chemical Physics Letters publishes brief reports on molecules, interfaces, condensed phases, nanomaterials and nanostructures, polymers, biomolecular systems, and energy conversion and storage. Criteria for publication are quality, urgency and impact. Further, experimental results reported in the journal have direct relevance for theory, and theoretical developments or non-routine computations relate directly to experiment. Manuscripts must satisfy these criteria and should not be minor extensions of previous work.
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