Effect of magnesium doping on the structure, optical properties and photocatalytic efficiency of ZnO nanostructures deposited by atmospheric pressure MOCVD

IF 2.8 3区 化学 Q3 CHEMISTRY, PHYSICAL Chemical Physics Letters Pub Date : 2024-10-24 DOI:10.1016/j.cplett.2024.141720
Arsenii Ievtushenko , Vitalii Karpyna , Liliia Myroniuk , Denys Myroniuk , Larisa Petrosian , Olena Olifan , Oleksandr Kolomys , Victor Strelchuk
{"title":"Effect of magnesium doping on the structure, optical properties and photocatalytic efficiency of ZnO nanostructures deposited by atmospheric pressure MOCVD","authors":"Arsenii Ievtushenko ,&nbsp;Vitalii Karpyna ,&nbsp;Liliia Myroniuk ,&nbsp;Denys Myroniuk ,&nbsp;Larisa Petrosian ,&nbsp;Olena Olifan ,&nbsp;Oleksandr Kolomys ,&nbsp;Victor Strelchuk","doi":"10.1016/j.cplett.2024.141720","DOIUrl":null,"url":null,"abstract":"<div><div>ZnO nanostructures doped by magnesium impurity were grown on Si substrates by atmospheric pressure MOCVD deposition using Zn and Mg acetylacetonates as initial precursors. XRD patterns confirm the successful incorporation of Mg ions into ZnO lattice. Room-temperature photoluminescence spectra of Mg-doped ZnO nanostructures demonstrate near-band edge emission and visible deep-level emission with ratios 2.9, 1.3 and 0.3 correspondingly for 1, 2.4 and 5.7 at. % of Mg in ZnO nanostructures. Raman measurements showed decreasing in intensity for ZnO modes with increasing Mg content. The best photodegradation rate constant was observed for ZnO NS with 2.4 at. % of Mg.</div></div>","PeriodicalId":273,"journal":{"name":"Chemical Physics Letters","volume":"857 ","pages":"Article 141720"},"PeriodicalIF":2.8000,"publicationDate":"2024-10-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Chemical Physics Letters","FirstCategoryId":"92","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0009261424006626","RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"CHEMISTRY, PHYSICAL","Score":null,"Total":0}
引用次数: 0

Abstract

ZnO nanostructures doped by magnesium impurity were grown on Si substrates by atmospheric pressure MOCVD deposition using Zn and Mg acetylacetonates as initial precursors. XRD patterns confirm the successful incorporation of Mg ions into ZnO lattice. Room-temperature photoluminescence spectra of Mg-doped ZnO nanostructures demonstrate near-band edge emission and visible deep-level emission with ratios 2.9, 1.3 and 0.3 correspondingly for 1, 2.4 and 5.7 at. % of Mg in ZnO nanostructures. Raman measurements showed decreasing in intensity for ZnO modes with increasing Mg content. The best photodegradation rate constant was observed for ZnO NS with 2.4 at. % of Mg.

Abstract Image

查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
镁掺杂对常压 MOCVD 沉积的氧化锌纳米结构的结构、光学特性和光催化效率的影响
以锌和镁乙酰丙酮酸盐为初始前驱体,通过常压 MOCVD 沉积法在硅基底上生长了掺杂镁杂质的氧化锌纳米结构。XRD 图谱证实镁离子成功地掺入了氧化锌晶格中。掺镁氧化锌纳米结构的室温光致发光光谱显示了近带边缘发射和可见深层发射,镁在氧化锌中的含量分别为 1、2.4 和 5.7 at.氧化锌纳米结构中的镁含量分别为 1、2.4 和 5.7%时,近带边缘发射和可见深层发射的比率分别为 2.9、1.3 和 0.3。拉曼测量结果表明,随着镁含量的增加,氧化锌模式的强度也在下降。镁含量为 2.4 at.%的 ZnO NS 的光降解速率常数最佳。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Chemical Physics Letters
Chemical Physics Letters 化学-物理:原子、分子和化学物理
CiteScore
5.70
自引率
3.60%
发文量
798
审稿时长
33 days
期刊介绍: Chemical Physics Letters has an open access mirror journal, Chemical Physics Letters: X, sharing the same aims and scope, editorial team, submission system and rigorous peer review. Chemical Physics Letters publishes brief reports on molecules, interfaces, condensed phases, nanomaterials and nanostructures, polymers, biomolecular systems, and energy conversion and storage. Criteria for publication are quality, urgency and impact. Further, experimental results reported in the journal have direct relevance for theory, and theoretical developments or non-routine computations relate directly to experiment. Manuscripts must satisfy these criteria and should not be minor extensions of previous work.
期刊最新文献
Modulation of surface plasmon polariton lasing modes via nanowire-metal contact distance and area Adsorption behaviors and gas-sensing properties of Agn(n = 1–3)-MoSSe for gases (C2H2, C2H4, CO) in oil-filled electrical equipment DFT insights upon Pd assisted MoX2 (X = Se, S, Te) capture of air decomposition products (CO, NO2) in switch cabinet Aromaticity of charged cyclocarbon radicals (Cn± = 6–30) Directional design of interface and thermal performance for CL-20 using hollow fiber embed in desensitizer membranes
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1