The depolymerization of lignin over polyoxometalate catalysis: A review

IF 7.4 2区 工程技术 Q1 ENGINEERING, CHEMICAL Journal of Environmental Chemical Engineering Pub Date : 2024-10-23 DOI:10.1016/j.jece.2024.114540
Qingxuan Yin , Shumin Wang , Haoyu Deng , Junyou Shi , Dan Zhang , Wenbiao Xu
{"title":"The depolymerization of lignin over polyoxometalate catalysis: A review","authors":"Qingxuan Yin ,&nbsp;Shumin Wang ,&nbsp;Haoyu Deng ,&nbsp;Junyou Shi ,&nbsp;Dan Zhang ,&nbsp;Wenbiao Xu","doi":"10.1016/j.jece.2024.114540","DOIUrl":null,"url":null,"abstract":"<div><div>Lignin, as the most abundant natural aromatic compound, holds immense potential for the production of fuels and fine chemicals, making it a focal point in green chemistry. The efficient depolymerization of lignin hinges on the discovery of catalysts that are not only efficient but also stable and recyclable. Understanding the structure-function relationships and mechanisms governing lignin-catalyst depolymerization is paramount for its effective valorization. Polyoxometalates (POMs) have emerged as promising candidates due to their versatile structural composition and design flexibility. In this review, we explore the utilization of POMs in various methods of lignin transformation, encompassing oxidative catalysis, reduction catalysis, and photocatalysis. By summarizing these approaches, we aim to elucidate the current trends and challenges in the depolymerization of lignin using POMs.</div></div>","PeriodicalId":15759,"journal":{"name":"Journal of Environmental Chemical Engineering","volume":"12 6","pages":"Article 114540"},"PeriodicalIF":7.4000,"publicationDate":"2024-10-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Environmental Chemical Engineering","FirstCategoryId":"5","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S221334372402671X","RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"ENGINEERING, CHEMICAL","Score":null,"Total":0}
引用次数: 0

Abstract

Lignin, as the most abundant natural aromatic compound, holds immense potential for the production of fuels and fine chemicals, making it a focal point in green chemistry. The efficient depolymerization of lignin hinges on the discovery of catalysts that are not only efficient but also stable and recyclable. Understanding the structure-function relationships and mechanisms governing lignin-catalyst depolymerization is paramount for its effective valorization. Polyoxometalates (POMs) have emerged as promising candidates due to their versatile structural composition and design flexibility. In this review, we explore the utilization of POMs in various methods of lignin transformation, encompassing oxidative catalysis, reduction catalysis, and photocatalysis. By summarizing these approaches, we aim to elucidate the current trends and challenges in the depolymerization of lignin using POMs.
查看原文
分享 分享
微信好友 朋友圈 QQ好友 复制链接
本刊更多论文
聚氧化金属催化木质素的解聚:综述
木质素作为最丰富的天然芳香族化合物,在生产燃料和精细化学品方面具有巨大的潜力,因此成为绿色化学的一个焦点。木质素的高效解聚取决于催化剂的发现,催化剂不仅要高效,而且要稳定和可回收。了解木质素-催化剂解聚的结构-功能关系和机理对于有效实现木质素的价值化至关重要。聚氧甲基丙烯酸酯(POMs)因其结构组成的多样性和设计的灵活性而成为前景广阔的候选材料。在本综述中,我们探讨了在各种木质素转化方法中利用 POMs 的情况,包括氧化催化、还原催化和光催化。通过总结这些方法,我们旨在阐明当前使用 POMs 解聚木质素的趋势和挑战。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
求助全文
约1分钟内获得全文 去求助
来源期刊
Journal of Environmental Chemical Engineering
Journal of Environmental Chemical Engineering Environmental Science-Pollution
CiteScore
11.40
自引率
6.50%
发文量
2017
审稿时长
27 days
期刊介绍: The Journal of Environmental Chemical Engineering (JECE) serves as a platform for the dissemination of original and innovative research focusing on the advancement of environmentally-friendly, sustainable technologies. JECE emphasizes the transition towards a carbon-neutral circular economy and a self-sufficient bio-based economy. Topics covered include soil, water, wastewater, and air decontamination; pollution monitoring, prevention, and control; advanced analytics, sensors, impact and risk assessment methodologies in environmental chemical engineering; resource recovery (water, nutrients, materials, energy); industrial ecology; valorization of waste streams; waste management (including e-waste); climate-water-energy-food nexus; novel materials for environmental, chemical, and energy applications; sustainability and environmental safety; water digitalization, water data science, and machine learning; process integration and intensification; recent developments in green chemistry for synthesis, catalysis, and energy; and original research on contaminants of emerging concern, persistent chemicals, and priority substances, including microplastics, nanoplastics, nanomaterials, micropollutants, antimicrobial resistance genes, and emerging pathogens (viruses, bacteria, parasites) of environmental significance.
期刊最新文献
Research progress of simultaneous nitrogen and phosphorus removal adsorbents in wastewater treatment Recent progress of piezoelectric materials applied in photocatalytic CO2 reduction: A review Recent advances and future prospects of MXene-based photocatalysts in environmental remediations Layered double hydroxides as versatile materials for detoxification of hexavalent chromium: Mechanism, kinetics, and environmental factors Pyruvate-formate lyase and beyond
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
现在去查看 取消
×
提示
确定
0
微信
客服QQ
Book学术公众号 扫码关注我们
反馈
×
意见反馈
请填写您的意见或建议
请填写您的手机或邮箱
已复制链接
已复制链接
快去分享给好友吧!
我知道了
×
扫码分享
扫码分享
Book学术官方微信
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术
文献互助 智能选刊 最新文献 互助须知 联系我们:info@booksci.cn
Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。
Copyright © 2023 Book学术 All rights reserved.
ghs 京公网安备 11010802042870号 京ICP备2023020795号-1