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Emerging technologies for urine wastewater recycling in space exploration: A comprehensive review 空间探索中尿废水回收的新兴技术综述
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-20 DOI: 10.1016/j.jece.2026.121355
Rashmi Ranjan , Swatantra P. Singh
Efficient water recovery is crucial in long-range space missions, where resupply is limited and a sufficient water supply must be provided for the entire mission duration. Water can be resupplied to the International Space Station (ISS), but for missions outside Low Earth Orbit (LEO), it is almost impossible. Even after 50 years of research, the existing Urine Processor Assembly (UPA) and Water Processor Assembly (WPA) continue to be used on the ISS for water recovery at a suboptimal rate. There is a need to improve the existing system’s efficiency, adapt it to suit the needs of long-range missions, or develop new technology. This review examines the UPA and WPA systems, highlighting their roles, efficiency, and the need for further modification. Membrane-based technologies, including Forward Osmosis (FO) and Membrane Distillation (MD), as well as emerging hybrid technologies such as integrated FO-MD and the Photocatalytic Membrane Reactor (PMR), have been discussed. Special attention has been given to brine treatment technologies, such as the Forward Osmosis Brine Dryer (FOBD), Ionomer Water Processor (IWP), Capillary Brine Residual in Containment (CapiBRIC), and Brine Evaporation Bag (BEB), which various space agencies have identified as potential alternatives. Technological advancements in developing a closed-loop biological life support system, Micro-Ecological Life Support System Alternative (MELiSSA) are also discussed. These technologies can be used as a standalone system or integrated with other treatment methods for water recycling. The review offers a critical evaluation of current water recycling systems and examines innovative technologies that can be integrated to enhance system reliability in space exploration missions.
在远程空间任务中,有效的水回收是至关重要的,因为远程空间任务的再补给是有限的,必须在整个任务期间提供足够的水供应。水可以补给到国际空间站(ISS),但对于低地球轨道(LEO)以外的任务来说,这几乎是不可能的。即使经过50年的研究,现有的尿液处理器组件(UPA)和水处理器组件(WPA)仍然在国际空间站上使用,其水回收率低于最佳水平。有必要改进现有系统的效率,使其适应远程任务的需要,或者开发新技术。本文审查了UPA和WPA系统,强调了它们的作用、效率和进一步修改的需要。膜技术,包括正向渗透(FO)和膜蒸馏(MD),以及新兴的混合技术,如集成的FO-MD和光催化膜反应器(PMR),进行了讨论。特别关注的是盐水处理技术,如正向渗透盐水干燥器(FOBD)、离子水处理器(IWP)、毛细管容器内残留盐水(CapiBRIC)和盐水蒸发袋(BEB),这些技术已被各航天机构确定为潜在的替代方案。本文还讨论了开发闭环生物生命支持系统——微生态生命支持系统替代方案(MELiSSA)的技术进展。这些技术可以作为一个独立的系统使用,也可以与其他水循环处理方法相结合。该评估对当前的水循环系统进行了批判性评估,并研究了可以集成的创新技术,以提高空间探索任务中的系统可靠性。
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引用次数: 0
Manganese-based cathodes for aqueous zinc-ion batteries: Mechanistic insights and rational design strategies 水锌离子电池的锰基阴极:机械的见解和合理的设计策略
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-27 DOI: 10.1016/j.jece.2026.121461
Zhouxiao Wang , Zhengmin Zhong , Lisan Fu , Pengze Yang , Jinkai Liu , Qiliang Pan
Aqueous zinc-ion batteries (AZIBs) are promising for large-scale energy storage owing to their advantages of high theoretical capacity, low cost, and high safety. Manganese-based materials, characterized by rich reserves, low cost, multiple valence states, and relatively high operating potential, represent a very promising cathode material for AZIBs. This article reviews the latest advances in manganese-based cathode materials for AZIBs from a mechanistic perspective, elucidating the evolution of energy storage mechanisms. Representative manganese-based materials, including MnO2, Mn2O3, Mn3O4, ZnMn2O4, and manganese composite with other materials, are discussed in terms of their structural characteristics, dominant reaction pathways, and electrochemical behaviors. To address challenges of manganese dissolution, structural instability, and poor conductivity, key modification strategies (elemental doping, surface coating, structural design, and electrolyte optimization) are systematically reviewed, with a focus on their ability to enhance cycling stability and rate performance. Finally, this review outlines future research directions of manganese-based materials as AZIBs cathodes, providing a reference for developing high-performance AZIBs.
水溶液锌离子电池具有理论容量大、成本低、安全性高等优点,在大规模储能领域具有广阔的应用前景。锰基材料具有储量丰富、成本低、价态多、操作潜力高等特点,是极具发展前景的azib正极材料。本文从机理角度综述了锰基azib正极材料的最新进展,阐述了其储能机理的演变。讨论了锰基材料的结构特征、主要反应途径和电化学行为,包括MnO2、Mn2O3、Mn3O4、ZnMn2O4和锰基复合材料。为了解决锰溶解、结构不稳定和电导率差的挑战,系统地回顾了关键的改性策略(元素掺杂、表面涂层、结构设计和电解质优化),重点介绍了它们提高循环稳定性和速率性能的能力。最后,综述了锰基材料作为azib阴极的未来研究方向,为开发高性能azib提供参考。
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引用次数: 0
Advances and challenges in graphite recycling from spent lithium-ion batteries 废旧锂离子电池中石墨回收的进展与挑战
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-24 DOI: 10.1016/j.jece.2026.121412
Naizhe Zhang, Xue Jiang
With the continuous growth of global energy demand, the demand for graphite as an anode material for lithium-ion batteries (LIBs) has increased significantly. However, the large volume of end-of-life LIBs generates substantial amounts of retired graphite, which not only poses potential environmental risks but also raises challenges for strategic resource security, making its standardized management an urgent issue. This review focuses on the recycling and reuse of graphite from retired LIBs, systematically summarizing the core stages of the recovery process, including battery disassembly, graphite separation and purification, and strategies for restoring the performance of regenerated graphite. Key technologies, such as mechanical disassembly, hydrometallurgical/pyrometallurgical treatment, acid leaching, graphitization, flash joule heating, microwave treatment, and carbon coating, are analyzed in terms of their advantages and limitations, with discussion on effective approaches to enhance the electrochemical performance, structural repair, and cycling stability of regenerated graphite. Despite significant progress in graphite recycling and regeneration, several research gaps remain, such as the unclear quantitative relationship between defect repair efficiency and energy input during regeneration, which hinders precise process control, and the heterogeneity of retired graphite from different sources, which limits the adaptability of existing technologies. Furthermore, the industrial-scale application of regeneration technologies and the precise regeneration of various types of graphite are expected to be key research directions. These advances will facilitate the closed-loop utilization of LIBs materials, ensure strategic resource supply, and contribute to the development of sustainable energy.
随着全球能源需求的持续增长,石墨作为锂离子电池负极材料的需求量大幅增加。然而,大量报废的锂电池产生了大量的退役石墨,不仅存在潜在的环境风险,而且对战略资源安全提出了挑战,使其标准化管理成为一个迫切需要解决的问题。本文综述了退役锂电池中石墨的回收再利用,系统地总结了回收过程的核心阶段,包括电池拆解、石墨分离和纯化,以及恢复再生石墨性能的策略。分析了机械拆卸、湿法/火法处理、酸浸、石墨化、闪蒸焦耳加热、微波处理、碳包覆等关键技术的优缺点,探讨了提高再生石墨电化学性能、结构修复和循环稳定性的有效途径。尽管石墨回收再生技术取得了重大进展,但仍存在一些研究空白,如缺陷修复效率与再生过程中能量输入之间的定量关系不明确,这阻碍了精确的过程控制,以及不同来源的退役石墨的非均质性限制了现有技术的适应性。此外,再生技术的工业规模应用和各种类型石墨的精确再生有望成为重点研究方向。这些进展将促进lib材料的闭环利用,确保战略性资源供应,并为可持续能源的发展做出贡献。
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引用次数: 0
A quantitative IC50-based framework integrating multidimensional toxicity of coal-wastewater inhibitors in biological wastewater treatment systems 基于ic50的定量框架整合了生物废水处理系统中煤废水抑制剂的多维毒性
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-29 DOI: 10.1016/j.jece.2026.121529
Samir I. Gadow , Bao-Shan Xing , Yu Qin , Yu-You Li
Coal-derived wastewater contains complex mixtures of persistent organic and inorganic pollutants that impair biological treatment. While many individual inhibitors have been studied, their combined toxicity and process-specific impacts remain poorly understood. This review develops an integrative assessment framework that links IC50-based toxicity thresholds to microbial susceptibility and biological process performance. Key inhibitors including cyanides, phenols, thiocyanates, ammonia, PAHs, heavy metals, and nitrogen-containing heterocycles are evaluated across four major biological treatment systems: aerobic oxidation, anaerobic digestion, partial nitritation, and anammox. Special emphasis is placed on synergistic toxicities (e.g., phenol–ammonia interactions) and on the acute sensitivity of nitrifying and anammox bacteria to heterocyclic compounds such as quinoline and pyridine. By aligning inhibitor profiles with mitigation strategies and removal pathways, this review provides a process-informed roadmap for designing resilient, adaptive treatment trains for coal-derived industrial effluents.
煤衍生废水含有复杂的持久性有机和无机污染物的混合物,损害生物处理。虽然已经研究了许多单独的抑制剂,但它们的综合毒性和特定过程的影响仍然知之甚少。本综述建立了一个综合评估框架,将基于ic50的毒性阈值与微生物敏感性和生物过程性能联系起来。主要抑制剂包括氰化物、酚类、硫氰酸酯、氨、多环芳烃、重金属和含氮杂环,在四种主要的生物处理系统中进行了评估:好氧氧化、厌氧消化、部分硝化和厌氧氨氧化。特别强调的是协同毒性(例如,酚-氨相互作用)和硝化细菌和厌氧氨氧化细菌对喹啉和吡啶等杂环化合物的急性敏感性。通过将抑制剂的特征与缓解策略和去除途径相结合,本综述为设计煤源工业废水的弹性、适应性处理方案提供了一个过程信息路线图。
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引用次数: 0
Conductive materials in anaerobic digestion: Mechanisms of process intensification and regulations of microbial metabolisms 厌氧消化中的导电材料:过程强化机制和微生物代谢调节
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-18 DOI: 10.1016/j.jece.2026.121305
Yuxin He , Shanying He , Juncong Zou , Dexin Wang , Xiang Li , Qiuya Niu , Chunping Yang
Anaerobic digestion (AD) technology has been widely adopted globally due to its multiple advantages in environmental soundness, energy recovery, and resource recycling. Conductive materials (CMs) are emerging tools to enhance AD stability and methane yield, and have garnered growing attention and significance. Firstly, this review systematically expounds on the current applications of CMs and further explores the potential enhancement mechanisms of CMs. Among these aspects, it analyzes the mechanisms underlying the enhancement of DIET by CMs and the synergistic effects between CMs and quorum sensing signaling molecules in enhancing AD system. Secondly, the effects of CMs on microorganisms are summarized. Specifically, CMs can enrich functional microbial populations and enhance metabolic activity. Thirdly, the current challenges are outlined and future research directions are discussed. This review is intended to provide valuable references for investigating the applications of CMs in AD, thereby facilitating the development of more economical and efficient strategies for AD optimization.
厌氧消化(AD)技术因其在环保、能源回收和资源循环等方面的优势而在全球范围内得到广泛应用。导电材料(CMs)是提高AD稳定性和甲烷产率的新兴工具,受到越来越多的关注和重视。本文首先系统阐述了CMs的应用现状,并进一步探讨了CMs的潜在增强机制。其中,分析了CMs增强AD系统的机制,以及CMs与群体感应信号分子在AD系统中的协同作用。其次,综述了CMs对微生物的影响。具体来说,CMs可以丰富功能性微生物种群,增强代谢活性。第三,概述了当前面临的挑战,并对未来的研究方向进行了讨论。本文旨在为研究CMs在AD中的应用提供有价值的参考,从而促进开发更经济高效的AD优化策略。
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引用次数: 0
Dynamic competitive removal mechanism for petroleum hydrocarbon under consideration of soil water during the thermal enhanced soil vapor extraction 热强化土壤蒸汽抽提过程中考虑土壤水分的石油烃动态竞争去除机制
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-14 DOI: 10.1016/j.jece.2026.121239
Liangliang Lu , Shui Wang , Zhibin Liu , Min Song , Dingwen Zhang , Lisen Bai
The remediation of low-permeability contaminated soils poses a significant challenge. Soil water serves as a crucial factor that restricts the mass transfer of contaminants. The thermal enhanced soil vapor extraction (T-SVE) is an effective technique for treating low-permeability contaminated soils. This paper investigated the removal and migration characteristics of diesel in low-permeability contaminated soils considering water competitive adsorption from a new insight of low-field nuclear magnetism resonance (LF NMR). In this study, a new method for simultaneous testing contaminant concentration and water content was proposed. The results shows that the removal efficiency of diesel is significantly lower than that of soil water during the dynamic extraction process. The diesel re-adsorption is a primary mechanism leading to the low remediation efficiency in low-permeability contaminated soils. Due to the competitive adsorption advantage of water molecules, the phenomenon of diesel re-adsorption was observed below 7 % water content. An optimal water content range of 7 %-16 % was proposed, which can provide optimized parameter for SVE remediation. After the T-SVE process with heating to 250℃, diesel can be removed with a removal rate of 99.8 %. The removal process of different carbon number groups in diesel conforms to an exponential decay kinetic model. Among them, the C10-C12 are mostly desorbed by SVE process. The C13-C20 and C21-C24 are removed during the T-SVE process at 150℃ and 250℃, respectively. In addition, the T1-T2 relaxation behaviors provide insights into the typical migration characteristic of diesel and soil water, including the dynamic migration of diesel, free water and bound water.
低渗透污染土壤的修复面临着重大挑战。土壤水分是制约污染物传质的关键因素。热强化土壤蒸汽萃取技术是处理低渗透污染土壤的有效技术。本文从低场核磁共振(LF NMR)的新视角出发,研究了柴油在低渗透污染土壤中竞争吸附的去除和迁移特性。本文提出了一种同时检测污染物浓度和含水量的新方法。结果表明,在动态提取过程中,柴油的去除效率明显低于土壤水的去除效率。柴油的再吸附是导致低渗透污染土壤修复效率低的主要机制。由于水分子的竞争吸附优势,在7 %含水率以下观察到柴油的再吸附现象。提出了7 % ~ 16 %的最佳含水率范围,为SVE修复提供了优化参数。经过加热至250℃的T-SVE工艺,柴油的去除率可达99.8 %。柴油中不同碳数基团的去除过程符合指数衰减动力学模型。其中,C10-C12主要通过SVE解吸。C13-C20和C21-C24分别在150℃和250℃的T-SVE过程中被去除。此外,T1-T2弛豫行为揭示了柴油和土壤水的典型迁移特征,包括柴油、自由水和束缚水的动态迁移。
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引用次数: 0
Enhanced amoxicillin degradation using HKUST–1(Cu/Fe)–derived CuO–Fe/BiVO4 photocatalyst: Reduction of toxicity and antimicrobial activity 利用HKUST-1 (Cu/Fe)衍生的CuO-Fe /BiVO4光催化剂增强阿莫西林降解:降低毒性和抗菌活性
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-08 DOI: 10.1016/j.jece.2026.121045
Brenda Liset Coronado–García , Jorge Luis Guzmán–Mar , Pedro César Quero–Jiménez , Mayra Zyzlila Figueroa–Torres , Roberto Camposeco , Laura Hinojosa–Reyes
The photocatalytic degradation of amoxicillin (AMX) under UV–Vis irradiation employing the HKUST–1(Cu/Fe)–derived CuO–Fe/BiVO4 composite was evaluated in this study. The composites were synthesized by a hydrothermal route with 30, 50, and 70 wt% of HKUST–1(Cu/Fe) incorporated into BiVO4 and subsequently annealed at 400 °C in air. The synthesized materials were characterized using thermogravimetric analysis (TGA), X–ray diffraction (XRD), X–ray photoelectron spectroscopy (XPS), UV–Visible diffuse reflectance spectroscopy (UV–Vis DRS), photoluminescence spectroscopy (PL), Mott–Schottky/EIS techniques, Raman spectroscopy, and nitrogen physisorption. The incorporation of the CuO–Fe derived HKUST–1(Cu/Fe) into BiVO4, with monoclinic crystalline structure, preserved visible light activity (Eg = 2.09 – 2.28 eV) and improved the textural properties by increasing the surface area (from 1.25 to 7.89 m2 g–1) and pore volume (from 0.011 to 0.484 cm3 g–1) in the composites; and also favored the formation of oxygen vacancies, which enhanced the photocatalytic activity compared with that of BiVO4. The photocatalytic degradation of AMX was improved at pH 7 by using the composite with 50 wt% HKUST–1(Cu/Fe) in BiVO4, reaching 92.92 % in 3 h, compared with 75.59 % for BiVO4. The degradation by–products were monitored using GC–MS and ion chromatography (IC), which confirmed the formation of acetic, maleic, and fumaric acids at the end of the process. QSAR (Quantitative Structure–Activity Relationship) analysis indicated that these compounds have low acute and chronic toxicity. The inactivation of Staphylococcus aureus and Escherichia coli with the effluent derived of AMX photocatalytic oxidation by H1(Cu/Fe)50Bi under UV–Vis irradiation (16.4 % for E. coli and 52.2 % for S. aureus) and simulated sunlight exposure (10.9 % E.coli and 42.4 % for S. aureus), indicated the reduction of its antimicrobial activity. Additionally, the photocatalytic material remained stable over three reuse cycles for AMX degradation. The study conducted in the presence of sequestering agents for reactive oxygen species indicated that holes were the primary species responsible for AMX degradation. Thus, HKUST–1(Cu/Fe)–derived CuO–Fe is a promising material to enhance the photocatalytic properties of BiVO4.
研究了HKUST-1 (Cu/Fe)衍生CuO-Fe /BiVO4复合材料在UV-Vis照射下光催化降解阿莫西林(AMX)的性能。BiVO4中分别掺入30%、50%和70% wt%的HKUST-1 (Cu/Fe),通过水热法合成复合材料,然后在400℃空气中退火。采用热重分析(TGA)、x射线衍射(XRD)、x射线光电子能谱(XPS)、紫外-可见漫反射光谱(UV-Vis DRS)、光致发光光谱(PL)、Mott-Schottky /EIS技术、拉曼光谱和氮物理吸附等方法对合成材料进行了表征。CuO-Fe衍生的hkkust - 1(Cu/Fe)掺入BiVO4中,具有单斜晶型结构,保持了复合材料的可见光活性(Eg = 2.09 ~ 2.28 eV),并通过增加复合材料的表面积(从1.25增加到7.89 m2 g-1)和孔隙体积(从0.011增加到0.484 cm3 g-1)改善了复合材料的结构性能;并且有利于氧空位的形成,与BiVO4相比增强了光催化活性。在pH为7时,BiVO4中HKUST-1 (Cu/Fe)的质量分数为50 wt%,在3 h内达到92.92 %,而BiVO4的光催化降解率为75.59 %。采用气相色谱-质谱和离子色谱法(IC)对降解副产物进行了监测,证实了在该过程结束时生成乙酸、马来酸和富马酸。QSAR(定量构效关系)分析表明,这些化合物具有较低的急性和慢性毒性。用H1(Cu/Fe)50Bi对AMX光催化氧化所得出水进行紫外-可见照射(大肠杆菌16.4% %,金黄色葡萄球菌52.2% %)和模拟日光照射(大肠杆菌10.9% %,金黄色葡萄球菌42.4 %)对金黄色葡萄球菌和大肠杆菌的失活实验,表明其抑菌活性降低。此外,光催化材料在三次重复使用循环中对AMX的降解保持稳定。在活性氧截留剂存在的情况下进行的研究表明,孔是导致AMX降解的主要物种。因此,HKUST-1 (Cu/Fe)衍生的CuO-Fe是一种很有希望增强BiVO4光催化性能的材料。
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引用次数: 0
Response of vegetation restoration and soil reconstitution to coupled manure application in alpine mining areas: A comprehensive assessment 高寒矿区植被恢复与土壤重建对施肥耦合响应的综合评价
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-14 DOI: 10.1016/j.jece.2026.121177
Zhongyang Yu , Changhui Li , Mingchun Yang , Guoning Jing , Jianing Li , Jianli Wu
Fertilization and grassland reconstruction are vital for restoring alpine mining areas, yet the combined effects of sheep manure and commercial organic fertilizer on plant communities, soil properties, and microbial composition in artificial grasslands remain unclear. This study evaluated six fertilization treatments—CK (no fertilization), S (100 % sheep manure), F (100 % organic fertilizer), M1 (60 % sheep manure + 40 % organic fertilizer), M2 (50 % + 50 %), and M3 (40 % + 60 %)—in an artificial grassland established in 2021 in the Muli mining area, Qinghai Province. Sampling and high-throughput sequencing were conducted in 2024. After four years, fertilization significantly altered plant community structure, soil chemical traits, and microbial composition and function. Above-ground biomass, Shannon-Wiener index, Pielou index, and Simpson index under M1 treatment were significantly higher than other treatments, exceeding the control group by 223.03 %, 4.23 %, 12.20 %, and 15.67 %, respectively. Moreover, M1 significantly enhanced total nitrogen, total phosphorus, available nitrogen, available phosphorus, and organic matter content, with respective increases of 90.70 %, 169.61 %, 504.43 %, 251.24 %, and 391.00 % compared to the control. While M1 treatment led to significant reductions in the bacterial community's Sobs, Ace, and Chao indices, it markedly increased these indices within the fungal community. Structural equation modeling indicated that nutrient supplementation enhances plant productivity by directly improving the soil nutrient environment and indirectly improving microbial community structure. Overall, the fertilization strategy of 60 % sheep manure combined with 40 % commercial organic fertilizer emerges as the most effective approach for vegetation restoration and soil rehabilitation in alpine mining regions.
施肥和草地重建对高寒矿区的恢复至关重要,但羊粪和商业有机肥对人工草地植物群落、土壤性质和微生物组成的综合影响尚不清楚。在青海省木里矿区2021年建立的人工草地上,对ck(不施肥)、S(100 %羊粪)、F(100 %有机肥)、M1(60 %羊粪+ 40 %有机肥)、M2(50 % + 50 %)和M3(40 % + 60 %)6种施肥处理进行了评价。2024年进行取样和高通量测序。4年后,施肥显著改变了植物群落结构、土壤化学性状、微生物组成和功能。M1处理的地上生物量、Shannon-Wiener指数、Pielou指数和Simpson指数均显著高于其他处理,分别比对照组高出223.03 %、4.23 %、12.20 %和15.67 %。此外,M1显著提高了全氮、全磷、速效氮、速效磷和有机质含量,分别比对照提高了90.70 %、169.61 %、504.43 %、251.24 %和391.00 %。虽然M1处理导致细菌群落的Sobs、Ace和Chao指数显著降低,但它显著增加了真菌群落的这些指数。结构方程模型表明,养分补充通过直接改善土壤养分环境和间接改善微生物群落结构来提高植物生产力。综上所述,60% %羊粪配40% %商业有机肥的施肥策略是高寒矿区植被恢复和土壤修复最有效的方法。
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引用次数: 0
Pollution characteristics of Litopenaeus vannamei greenhouse effluents and purification performance of a combined flocculation–ecological floating bed system 凡纳滨对虾温室污水污染特征及絮凝-生态浮床联合系统净化性能
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-12 DOI: 10.1016/j.jece.2026.121198
Shanyuan Xue , Guo Li , Ensheng Zhu , Weizhen Zhang , Jiao Ran , Zhe Li , Yu Zhao , Jingru Hu , Jing Dong , Yingxue Yi , Dan Zhou , Qiang He , Zheng Zheng
With the rapid intensification of aquaculture, greenhouse-based Litopenaeus vannamei farming generates large volumes of high-salinity and nutrient-rich effluents, posing serious threats to the surrounding aquatic environment. This study systematically investigated the pollution characteristics of greenhouse shrimp aquaculture effluents and developed a combined flocculation-ecological floating bed (EFB) system for efficient purification.The flocculation pretreatment employed polyferric sulfate (PFS) and polyacrylamide (PAM) as coagulants, and the process parameters were optimized using a Box–Behnken response surface model. The optimal conditions were PFS = 0.5 g/L, PAM = 0.01 g/L, pH = 8, temperature = 30 °C, and 15 min for both stirring time and sedimentation time. Under these conditions, removal efficiencies for TSS, turbidity, and COD reached 95.80 %, 96.04 %, and 54.08 %, respectively, with model–experiment deviations below 5 %, confirming the model’s reliability. In the subsequent EFB treatment stage, three fillers—suspended balls, multi-faceted hollow spheres, and carbon fiber grass—were compared. The carbon fiber grass system (D_s) exhibited the best purification performance, achieving 78.7 % TN and 83.5 % COD removal. High-throughput sequencing revealed that the D_s system possessed the highest microbial α-diversity, with enrichment of Bacillus and Paracoccus forming stable co-occurrence networks. Functional gene quantification showed significantly increased nirK and nirS abundances, indicating enhanced denitrification potential. Overall, the integrated “Flocculation + EFB” process effectively removed major pollutants from greenhouse aquaculture effluents and achieved a synergistic coupling between pollutant control and ecological purification, providing theoretical and practical guidance for sustainable treatment of high-salinity aquaculture wastewater.
随着养殖业的快速集约化,温室养殖的凡纳滨对虾产生大量高盐度、富营养化的出水,对周边水生环境构成严重威胁。本研究系统研究了温室养殖对虾废水的污染特性,开发了絮凝-生态浮床联合净化系统。采用聚合硫酸铁(PFS)和聚丙烯酰胺(PAM)作为混凝剂进行絮凝预处理,并采用Box-Behnken响应面模型对工艺参数进行优化。最佳搅拌条件为PFS = 0.5 g/L, PAM = 0.01 g/L, pH = 8,温度= 30℃,搅拌时间和沉淀时间均为15 min。在此条件下,对TSS、浊度和COD的去除率分别达到95.80 %、96.04 %和54.08 %,模型-实验偏差小于5 %,验证了模型的可靠性。在随后的EFB处理阶段,比较了三种填料——悬浮球、多面空心球和碳纤维草。碳纤维草体系(D_s)的净化效果最好,TN去除率为78.7% %,COD去除率为83.5 %。高通量测序结果显示,D_s系统具有最高的微生物α-多样性,富集的芽孢杆菌和副球菌形成稳定的共生网络。功能基因定量显示,nirK和nirS丰度显著增加,表明反硝化潜力增强。总体而言,“絮凝+ EFB”一体化工艺有效去除了温室养殖废水中的主要污染物,实现了污染物控制与生态净化的协同耦合,为高盐度养殖废水的可持续处理提供了理论和实践指导。
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引用次数: 0
Synthesis, characterization, and classification of quantum dot photocatalysts: Applied catalysis for light-driven environmental remediation and energy conversion 量子点光催化剂的合成、表征和分类:在光驱动环境修复和能量转换中的应用
IF 7.2 2区 工程技术 Q1 ENGINEERING, CHEMICAL Pub Date : 2026-04-01 Epub Date: 2026-01-08 DOI: 10.1016/j.jece.2026.121142
Keren Shi , Tuojie Wang , Xiaoyu Li , Wende Yi , Ziyan Wang , Qiaowei Xiao , Yan Liu , Changyi Yang , Huiqin Yao
Quantum dot photocatalysts are a class of nanoscale zero-dimensional semiconductor materials, typically ranging in size from 1 to 20 nanometers. These materials possess numerous unique advantages: tunable bandgaps, multiple exciton effects, quantum confinement effects, upconversion fluorescence effects, broad-spectrum absorption capabilities, and abundant surface active sites. In this paper, we first focus on two key areas—energy conversion and environmental remediation—to provide an overview of the application of quantum dots in photocatalysis. We then summarize their controllable and precise synthesis strategies and key characterization methods. Subsequently, we systematically classify various types of quantum dot photocatalytic materials, focusing on their mechanisms of action and the intrinsic factors that enhance photocatalytic performance. Finally, we delve into the challenges that quantum dot photocatalysts still face in their practical application. This review aims to provide theoretical guidance for the design, synthesis, and reaction mechanism research of high-performance quantum dot photocatalysts, thereby driving performance breakthroughs in the field of solar energy conversion.
量子点光催化剂是一类纳米级零维半导体材料,通常尺寸在1到20纳米之间。这些材料具有许多独特的优点:可调的带隙、多激子效应、量子约束效应、上转换荧光效应、广谱吸收能力和丰富的表面活性位点。本文首先从能量转换和环境修复两个关键领域综述了量子点在光催化中的应用。总结了它们的可控精确合成策略和关键表征方法。随后,我们对各种类型的量子点光催化材料进行了系统的分类,重点研究了它们的作用机制和增强光催化性能的内在因素。最后,我们深入探讨了量子点光催化剂在实际应用中仍然面临的挑战。本文旨在为高性能量子点光催化剂的设计、合成和反应机理研究提供理论指导,从而推动太阳能转换领域的性能突破。
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引用次数: 0
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Journal of Environmental Chemical Engineering
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