Yuliya A. Fadeeva, Liudmila E. Shmukler, Liubov P. Safonova
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引用次数: 0
Abstract
Fuel cells (FC) with proton exchange membranes (PEMs) are seen as an alternative energy source due to their efficiency, power density, low emissions, and reliable energy supply. Proton exchange membranes based on polybenzimidazole have shown potential for operating at high and medium temperatures to enhance FCs performance. New composite membranes made from m-PBI and diethylammonium mesylate [DEAH/MsO] ionic liquid were prepared trough a solution casting method. Silica nanopowder (SiO2) was used as an inorganic filler at varying concentrations (0.5–20 wt%). The ionic liquid content in the membranes ranged from 1 to 2.5 mol per mole of PBI monomer units. Our study is focused on the thermal properties, such as thermal stability and phase transition temperatures, morphology, conductivity, and electrochemical stability of the membranes. The influence of the inorganic filler on these properties was also discussed.
期刊介绍：
This interdisciplinary journal is devoted to the physics, chemistry and materials science of diffusion, mass transport, and reactivity of solids. The major part of each issue is devoted to articles on:
(i) physics and chemistry of defects in solids;
(ii) reactions in and on solids, e.g. intercalation, corrosion, oxidation, sintering;
(iii) ion transport measurements, mechanisms and theory;
(iv) solid state electrochemistry;
(v) ionically-electronically mixed conducting solids.
Related technological applications are also included, provided their characteristics are interpreted in terms of the basic solid state properties.
Review papers and relevant symposium proceedings are welcome.
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