Separation of yttrium from ion-adsorbed-rare-earth deposit leachates using N,N-di(2-ethylhexyl)-diglycolamic acid (HDEHDGA): Preliminary experimental and molecular dynamics simulation studies

IF 4.8 2区 材料科学 Q1 METALLURGY & METALLURGICAL ENGINEERING Hydrometallurgy Pub Date : 2024-10-19 DOI:10.1016/j.hydromet.2024.106412
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Abstract

The separation of yttrium (Y) from heavy rare-earth elements (HREEs) is a major issue for ion-adsorbed rare-earth deposits. This study describes a new extraction system to develop efficient separation of Y from HREEs in a chloride medium using diglycolamic acid as the extractant. The extraction performance of N,N-di(2-ethylhexyl)-diglycolamic acid (HDEHDGA) for mixed REEs of an ion-adsorbed rare-earth deposit was investigated. The extraction order of the REEs in the HDEHDGA system followed a positive sequence, and the extraction behavior of Y resembled that of the middle REEs. Compared with naphthenic acid (NA) and sec-octylphenoxy acetic acid (CA12), HDEHDGA exhibited better separation performance for HREEs (Ho-Lu) and Y. The separation factors of Ho/Y, Er/Y, Tm/Y, Yb/Y, and Lu/Y in the Y-enriched solution were 4.41, 4.29, 3.77, 3.26, and 3.11, respectively. Combined slope analysis and electrospray ionization–high-resolution mass spectroscopy (ESI-HRMS) results identified cation exchange as the extraction mechanism of RE3+. Furthermore, the molecular dynamics simulation results provided new insights into the dynamic behaviors of Y3+ and Yb3+ extraction and revealed that the interaction of HDEHDGA with Yb3+ was stronger than that with Y3+. In addition, the loading capacity and recyclability of HDEHDGA were evaluated. This study highlights the potential of the HDEHDGA system for the separation of Y from HREEs.

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使用 N,N-二(2-乙基己基)二甘醇氨基甲酸(HDEHDGA)从离子吸附的稀土矿床浸出液中分离钇:初步实验和分子动力学模拟研究
从重稀土元素(HREEs)中分离钇(Y)是离子吸附稀土矿床的一个主要问题。本研究介绍了一种新的萃取系统,该系统以二甘醇肟酸为萃取剂,在氯化物介质中开发出了从 HREEs 中高效分离 Y 的方法。研究了 N,N-二(2-乙基己基)-二甘醇胺酸(HDEHDGA)对离子吸附稀土矿床中混合 REEs 的萃取性能。在 HDEHDGA 体系中,REEs 的萃取顺序为正序,Y 的萃取行为与中间 REEs 相似。与环烷酸(NA)和仲辛基苯氧乙酸(CA12)相比,HDEHDGA对HREEs(Ho-Lu)和Y具有更好的分离性能。Y富集溶液中Ho/Y、Er/Y、Tm/Y、Yb/Y和Lu/Y的分离因子分别为4.41、4.29、3.77、3.26和3.11。结合斜率分析和电喷雾电离高分辨质谱(ESI-HRMS)结果,确定阳离子交换是 RE3+ 的萃取机制。此外,分子动力学模拟结果为 Y3+ 和 Yb3+ 萃取的动态行为提供了新的见解,并发现 HDEHDGA 与 Yb3+ 的相互作用强于与 Y3+ 的相互作用。此外,还评估了 HDEHDGA 的负载能力和可回收性。这项研究凸显了 HDEHDGA 系统从 HREEs 中分离 Y 的潜力。
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来源期刊
Hydrometallurgy
Hydrometallurgy 工程技术-冶金工程
CiteScore
9.50
自引率
6.40%
发文量
144
审稿时长
3.4 months
期刊介绍: Hydrometallurgy aims to compile studies on novel processes, process design, chemistry, modelling, control, economics and interfaces between unit operations, and to provide a forum for discussions on case histories and operational difficulties. Topics covered include: leaching of metal values by chemical reagents or bacterial action at ambient or elevated pressures and temperatures; separation of solids from leach liquors; removal of impurities and recovery of metal values by precipitation, ion exchange, solvent extraction, gaseous reduction, cementation, electro-winning and electro-refining; pre-treatment of ores by roasting or chemical treatments such as halogenation or reduction; recycling of reagents and treatment of effluents.
期刊最新文献
Technological advancements in rare earth elements recovery from ionic clays: A comprehensive review Lipophilic EDTA-based ligands in different diluents for the extraction of rare earths: Preliminary results with Nd(III), Dy(III) and Pr(III) in chloride and nitrate media Separation of yttrium from ion-adsorbed-rare-earth deposit leachates using N,N-di(2-ethylhexyl)-diglycolamic acid (HDEHDGA): Preliminary experimental and molecular dynamics simulation studies A critical review of hydrothermal treatment of sulfide minerals with Cu(II) solution in H2SO4 media Fundamentals of copper(II) adsorption on phyllosilicate minerals relevant to crud formation in solvent extraction from heap leach liquors
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