Separation of yttrium from ion-adsorbed-rare-earth deposit leachates using N,N-di(2-ethylhexyl)-diglycolamic acid (HDEHDGA): Preliminary experimental and molecular dynamics simulation studies
{"title":"Separation of yttrium from ion-adsorbed-rare-earth deposit leachates using N,N-di(2-ethylhexyl)-diglycolamic acid (HDEHDGA): Preliminary experimental and molecular dynamics simulation studies","authors":"","doi":"10.1016/j.hydromet.2024.106412","DOIUrl":null,"url":null,"abstract":"<div><div>The separation of yttrium (Y) from heavy rare-earth elements (HREEs) is a major issue for ion-adsorbed rare-earth deposits. This study describes a new extraction system to develop efficient separation of Y from HREEs in a chloride medium using diglycolamic acid as the extractant. The extraction performance of <em>N</em>,<em>N</em>-di(2-ethylhexyl)-diglycolamic acid (HDEHDGA) for mixed REEs of an ion-adsorbed rare-earth deposit was investigated. The extraction order of the REEs in the HDEHDGA system followed a positive sequence, and the extraction behavior of Y resembled that of the middle REEs. Compared with naphthenic acid (NA) and sec-octylphenoxy acetic acid (CA12), HDEHDGA exhibited better separation performance for HREEs (Ho-Lu) and Y. The separation factors of Ho/Y, Er/Y, Tm/Y, Yb/Y, and Lu/Y in the Y-enriched solution were 4.41, 4.29, 3.77, 3.26, and 3.11, respectively. Combined slope analysis and electrospray ionization–high-resolution mass spectroscopy (ESI-HRMS) results identified cation exchange as the extraction mechanism of RE<sup>3+</sup>. Furthermore, the molecular dynamics simulation results provided new insights into the dynamic behaviors of Y<sup>3+</sup> and Yb<sup>3+</sup> extraction and revealed that the interaction of HDEHDGA with Yb<sup>3+</sup> was stronger than that with Y<sup>3+</sup>. In addition, the loading capacity and recyclability of HDEHDGA were evaluated. This study highlights the potential of the HDEHDGA system for the separation of Y from HREEs.</div></div>","PeriodicalId":13193,"journal":{"name":"Hydrometallurgy","volume":null,"pages":null},"PeriodicalIF":4.8000,"publicationDate":"2024-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":null,"platform":"Semanticscholar","paperid":null,"PeriodicalName":"Hydrometallurgy","FirstCategoryId":"88","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0304386X2400152X","RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"METALLURGY & METALLURGICAL ENGINEERING","Score":null,"Total":0}
引用次数: 0
Abstract
The separation of yttrium (Y) from heavy rare-earth elements (HREEs) is a major issue for ion-adsorbed rare-earth deposits. This study describes a new extraction system to develop efficient separation of Y from HREEs in a chloride medium using diglycolamic acid as the extractant. The extraction performance of N,N-di(2-ethylhexyl)-diglycolamic acid (HDEHDGA) for mixed REEs of an ion-adsorbed rare-earth deposit was investigated. The extraction order of the REEs in the HDEHDGA system followed a positive sequence, and the extraction behavior of Y resembled that of the middle REEs. Compared with naphthenic acid (NA) and sec-octylphenoxy acetic acid (CA12), HDEHDGA exhibited better separation performance for HREEs (Ho-Lu) and Y. The separation factors of Ho/Y, Er/Y, Tm/Y, Yb/Y, and Lu/Y in the Y-enriched solution were 4.41, 4.29, 3.77, 3.26, and 3.11, respectively. Combined slope analysis and electrospray ionization–high-resolution mass spectroscopy (ESI-HRMS) results identified cation exchange as the extraction mechanism of RE3+. Furthermore, the molecular dynamics simulation results provided new insights into the dynamic behaviors of Y3+ and Yb3+ extraction and revealed that the interaction of HDEHDGA with Yb3+ was stronger than that with Y3+. In addition, the loading capacity and recyclability of HDEHDGA were evaluated. This study highlights the potential of the HDEHDGA system for the separation of Y from HREEs.
期刊介绍:
Hydrometallurgy aims to compile studies on novel processes, process design, chemistry, modelling, control, economics and interfaces between unit operations, and to provide a forum for discussions on case histories and operational difficulties.
Topics covered include: leaching of metal values by chemical reagents or bacterial action at ambient or elevated pressures and temperatures; separation of solids from leach liquors; removal of impurities and recovery of metal values by precipitation, ion exchange, solvent extraction, gaseous reduction, cementation, electro-winning and electro-refining; pre-treatment of ores by roasting or chemical treatments such as halogenation or reduction; recycling of reagents and treatment of effluents.