Experimental investigation of OH* emission spectrum characteristics and transient ignition dynamics in methane and coal dust mixtures explosions

IF 6.9 2区 环境科学与生态学 Q1 ENGINEERING, CHEMICAL Process Safety and Environmental Protection Pub Date : 2024-10-22 DOI:10.1016/j.psep.2024.10.068
Siyu Tian , Botao Qin , Yanwei Zhang , Dong Ma , Jingde Xu
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Abstract

Combustible gases, dusts and their mixtures are widely present in human production and life,and the fire and explosion disasters caused by them pose a serious threat to the field of energy security applications. Studying the ignition process of mixtures is essential for disaster risk assessment and safety protection. In this work, the explosion characteristics and OH* emission spectra of the mixtures were experimentally tested by varying the fuel equivalence ratio ( ER ≈ 0.79 ∼ 1.71), and the evolution of the transient flow field structure during the ignition process was quantitatively analyzed using the schlieren image velocimetry method. The results indicate that the emission spectrum of OH* is closely correlated with the maximum explosion pressure, and the spectral intensity of OH* at 306.4 nm is consistent with the maximum rate of explosion pressure rise. The flow field during the ignition process of the mixtures shows that a small amount of coal dust (concentration≤30 g/m3) can significantly promote flame acceleration and instability as the methane concentration is in lean combustion or stoichiometric ratio. However, when the concentration of coal dust increases (concentration≥40 g/m3), coal dust will suppress flame acceleration and instability. For methane concentration in fuel-rich combustion state, coal dust always suppresses flame acceleration and instability. The experimental results contribute to a further understanding of gas and coal dust mixed explosions and provide a verification database for the construction of chemical kinetic mechanisms.
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甲烷和煤尘混合物爆炸中 OH* 发射光谱特征和瞬态点火动力学实验研究
可燃气体、粉尘及其混合物广泛存在于人类的生产和生活中,其引发的火灾和爆炸灾害对能源安全应用领域构成严重威胁。研究混合物的燃烧过程对于灾害风险评估和安全防护至关重要。本研究通过改变燃料当量比(ER ≈ 0.79 ∼ 1.71),对混合物的爆炸特性和 OH* 发射光谱进行了实验测试,并利用 Schlieren 图像速度测量法定量分析了点火过程中瞬态流场结构的演变。结果表明,OH*的发射光谱与最大爆炸压力密切相关,OH*在306.4 nm处的光谱强度与最大爆炸压力上升速率一致。混合物点火过程中的流场表明,当甲烷浓度处于贫燃或化学计量比时,少量煤粉(浓度≤30 g/m3)可显著促进火焰加速和不稳定。但当煤粉浓度增加时(浓度≥40 g/m3),煤粉会抑制火焰加速和不稳定。对于富燃料燃烧状态下的甲烷浓度,煤粉始终抑制火焰加速和不稳定。实验结果有助于进一步理解瓦斯和煤粉混合爆炸,并为构建化学动力学机制提供了验证数据库。
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来源期刊
Process Safety and Environmental Protection
Process Safety and Environmental Protection 环境科学-工程:化工
CiteScore
11.40
自引率
15.40%
发文量
929
审稿时长
8.0 months
期刊介绍: The Process Safety and Environmental Protection (PSEP) journal is a leading international publication that focuses on the publication of high-quality, original research papers in the field of engineering, specifically those related to the safety of industrial processes and environmental protection. The journal encourages submissions that present new developments in safety and environmental aspects, particularly those that show how research findings can be applied in process engineering design and practice. PSEP is particularly interested in research that brings fresh perspectives to established engineering principles, identifies unsolved problems, or suggests directions for future research. The journal also values contributions that push the boundaries of traditional engineering and welcomes multidisciplinary papers. PSEP's articles are abstracted and indexed by a range of databases and services, which helps to ensure that the journal's research is accessible and recognized in the academic and professional communities. These databases include ANTE, Chemical Abstracts, Chemical Hazards in Industry, Current Contents, Elsevier Engineering Information database, Pascal Francis, Web of Science, Scopus, Engineering Information Database EnCompass LIT (Elsevier), and INSPEC. This wide coverage facilitates the dissemination of the journal's content to a global audience interested in process safety and environmental engineering.
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