Hydrogen permeation behavior of X80 pipeline steel under alternating wet-dry environment in the South China Sea

IF 1.3 4区 化学 Q4 ELECTROCHEMISTRY International Journal of Electrochemical Science Pub Date : 2024-10-24 DOI:10.1016/j.ijoes.2024.100848
Hongzhi Jin , Dongxu Sun , Ming Wu , Dongshu Wu
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Abstract

The riser sections of offshore pipelines are subject to cathodic potentials, alternating wet-dry (AWD) cycles and stresses in the service environment. The hydrogen permeation of X80 offshore pipeline with different cathodic potentials, dry/wet ratios, and constant tensile stress in AWD environment were investigated by the self made experimental equipment, which includes the three modules, i.e., the constant stress loading, the two-component cell hydrogen permeation, and AWD environment. Results showed that hydrogen permeation current fluctuates with the AWD, which is different from that in the bulk solution. In one AWD cycle, the permeation increases in the wetting stage and decreases in the dry stage. The smaller the dry/wet ratio, the longer the hydrogen permeation current keeps high level which is caused by the dense corrosion product layer. The hydrogen permeation currents in the elastic stress are greater than those in the plastic deformation, and unstressed conditions is the smallest.
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南海干湿交替环境下 X80 管线钢的氢渗透行为
海上管道的立管部分在使用环境中会受到阴极电位、干湿交替(AWD)循环和应力的影响。通过自制的实验设备,包括恒定应力加载、双组分电池渗氢和 AWD 环境三个模块,研究了不同阴极电位、干湿比和 AWD 环境下恒定拉伸应力下 X80 海洋管道的渗氢情况。结果表明,氢渗透电流随 AWD 的变化而波动,这与体液中的情况不同。在一个 AWD 周期中,渗透电流在润湿阶段增加,在干燥阶段减少。干湿比越小,氢渗透电流保持高水平的时间越长,这是因为腐蚀产物层很致密。弹性应力条件下的氢渗透电流大于塑性变形条件下的氢渗透电流,而无应力条件下的氢渗透电流最小。
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来源期刊
CiteScore
3.00
自引率
20.00%
发文量
714
审稿时长
2.6 months
期刊介绍: International Journal of Electrochemical Science is a peer-reviewed, open access journal that publishes original research articles, short communications as well as review articles in all areas of electrochemistry: Scope - Theoretical and Computational Electrochemistry - Processes on Electrodes - Electroanalytical Chemistry and Sensor Science - Corrosion - Electrochemical Energy Conversion and Storage - Electrochemical Engineering - Coatings - Electrochemical Synthesis - Bioelectrochemistry - Molecular Electrochemistry
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